Automatic Potentiometric Titration of Water Soluble Chlorides in Iron Ores
摘 要
应用自动电位滴定法,在pH>2的微酸性乙醇-水(4+1)溶液中,用0.002 mol·L-1硝酸银标准溶液为滴定剂,测定了铁矿石样品中水溶性氯化物.试样用水在95 ℃温度条件下浸取使其水溶性氯化物溶出,共存的硫化物的干扰采用在微碱性条件下加入过氧化氢并煮沸至无小气泡产生可予以消除,对试样的预处理方法,以及各项影响测定的参数(如溶液介质,被滴定液的酸度及温度,滴定速度及搅拌速度等)做了试验并予以优化.方法的检出限(S/N=3)为2.0 μg,用标准加入法做了回收率试验,结果在99.9%~100.4%之间.
Abstract
Water soluble chlorides in iron ores were determined by automatic potentiometric titration in weakly acidic solution of pH>2 and containing ethanol and water in the ratio of 4 to 1,using 0.002 mol·L-1 AgNO3 standard solution as titrant.Soluble chlorides in the sample were extracted with water at 95 ℃.Interference of sulfides was eliminated by boiling the slightly alkalified sample solution with H2O2 until ceasing of gaseous bubbles.Methods of pretreatment of sample,and various parameters affecting the titration (i.e.titration medium,acidity and temperature of the titrate,as well as the rate of stirring and titration) were tested and optimized.Detection limit of the method was found to be 2.0 μg.Recovery test was performed by standard addition method,and the results obtained were in the range of 99.9%-100.4%.
中图分类号 O657.31
所属栏目 工作简报
基金项目 国家质检总局资助重点项目(2006B090)
收稿日期 2007/3/15
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备注卢振国(1963-),男,广东人,高级工程师,主要研究方向为化学检测技术.
引用该论文: LU Zhen-guo,HUANG Wen-xian,PENG Su-biao,ZHAI Cui-ping,ZHENG Jian-guo,LIU Jian-bing,ZHONG Zhi-guang. Automatic Potentiometric Titration of Water Soluble Chlorides in Iron Ores[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2007, 43(9): 732~734
卢振国,黄文娴,彭速标,翟翠萍,郑建国,刘健斌,钟志光. 自动电位滴定法测定铁矿中水溶性氯化物[J]. 理化检验-化学分册, 2007, 43(9): 732~734
被引情况:
【1】宋晓红,高姗,杨杰,马东伟, "自动电位滴定法测定脱硫系统中氯化物",理化检验-化学分册 47, 684-686(2011)
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参考文献
【1】张道礼,王贤爱.电位滴定法测定磷矿石中的氯[J].磷肥与复肥,1996,11(4):52-54,30.
【2】ISO 9517:1989(E)铁矿石-水溶性氯化物含量的测定-离子选择电极法[S].
【3】申献辰,刘玲花,赵炳成,等.天然水化学[M].北京:中国环境科学出版社,1994:8-10.
【4】陈建华.电位滴定法测定铜精矿中氯[J].理化检验-化学分册,1977,33(10):450-451.
【5】GB 3097-1997海水水质标准[S].
【6】HJ/T 84-2001水质 无机阴离子的测定 离子色谱法[S].
【7】王新,袁长详,於剑波,等.进出口商品检验鉴定人员培训教材(下册)[M].北京:中国标准出版社,2004:46.
【2】ISO 9517:1989(E)铁矿石-水溶性氯化物含量的测定-离子选择电极法[S].
【3】申献辰,刘玲花,赵炳成,等.天然水化学[M].北京:中国环境科学出版社,1994:8-10.
【4】陈建华.电位滴定法测定铜精矿中氯[J].理化检验-化学分册,1977,33(10):450-451.
【5】GB 3097-1997海水水质标准[S].
【6】HJ/T 84-2001水质 无机阴离子的测定 离子色谱法[S].
【7】王新,袁长详,於剑波,等.进出口商品检验鉴定人员培训教材(下册)[M].北京:中国标准出版社,2004:46.
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