Corrosion Properties of Rapidly Solidified CuSn Alloys
摘 要
利用铜模铸造法分别制备了两种不同成分的快凝铜锡合金, 利用XRD分析了该快凝合金的物相结构, 用四探针法测量了两种快凝铜锡合金的电阻率, 并通过动电位极化曲线和电化学阻抗谱研究了两种快凝合金在NaOH溶液中的电化学耐腐蚀性能。结果表明, Cu75Sn25快凝合金具有Cu3Sn相, 而Cu65Sn35快凝合金主要具有Cu6Sn5相及部分Cu3Sn相, 由于两种快凝合金均形成了金属间化合物, 其电阻率没有明显区别; 在NaOH溶液中, Cu65Sn35快凝合金的耐蚀性明显优于Cu75Sn25快凝合金的。
Abstract
Two rapidly solidified CuSn alloys were prepared by copper mold casting. The phase composition and electronic resistivity of the two alloys were analyzed by XRD and four-probe method. And the corrosion behaviors of the alloys in NaOH solution were also studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results show that the phase of the rapidly solidified Cu75Sn25 alloy was Cu3Sn while the rapidly solidified Cu65Sn35 consisted of Cu6Sn5 and Cu3Sn. Due to the formation of intermetallic compounds, the electronic resistances were nearly the same for the two alloys. The rapidly solidified alloy Cu65Sn35 had more excellent corrosion resistance than rapidly solidified alloy Cu75Sn25 in 0.1 mol/L NaOH solution.
中图分类号 TG174.2 TG174.3 DOI 10.11973/fsyfh-201512003
所属栏目 试验研究
基金项目 江苏省自然科学基金(BK20130304; BK20140334); 国家自然科学基金(51204115; 51401139); 江苏省高校自然科学基金(14KJB460024); 中国博士后基金(2013M541719; 2014M561707)
收稿日期 2015/6/30
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备注盛敏奇(1983-)博士,从事金属材料的制备及电化学等性能方面的研究,
引用该论文: HOU Ji-xin,ZHOU Wei,ZHANG Shun-hu,SHENG Min-qi,XIAO Zheng-dong,WU Qiong. Corrosion Properties of Rapidly Solidified CuSn Alloys[J]. Corrosion & Protection, 2015, 36(12): 1129
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参考文献
【1】AL-GANAINY G S, FAWZY A, ADB EL-SALAM F. Transient and steady-state creep characteristics of Cu-2wt% Sn alloy in the solid solution region[J]. Physica B,2004,344(1/4):443-450.
【2】SONG J Y, YU J, LEE T Y. Effects of reactive diffusion on stress evolution in Cu-Sn films[J]. Scripta Materialia,2004,51(2):167-170.
【3】DEBIEMME-CHOUVY C, AMMELOOT F, SUTTER E M M. X-ray photoemission investigation of the corrosion film formed on a polished Cu-13Sn alloy in aerated NaCl solution[J]. Applied Surface Science,2001,174(1/2):55-61.
【4】MA X, QIAN Y Y, YOSHIDA F. Effect of La on the Cu-Sn intermetallic compound (IMC) growth and solder joint reliability[J]. J Alloys and Compound,2002,334(1/2):224-227.
【5】AMMELOOT F, FIAUD C, SUTTER E M M. Characterization of the oxide layers on a Cu-13Sn alloy in a NaCl aqueous solution without and with 0.1 M benzotriazole Electrochemical and photoelectrochemical contributions[J]. Electrochimica Acta,1999,44(15):2549-2558.
【6】MULLER J,LAK B,GUILLOT I. A-CuSn bronzes in sulphate medium:Influence of the tin content on corrosion processes[J]. Corrosion Science,2013,77:46-51.
【7】杨扬. 快速凝固Cu-Sn亚包晶合金的微观结构与性能[D]. 西安: 西安理工大学,2007.
【8】翟秋亚,杨扬,徐锦峰,等. 快速凝固CuSn亚包晶合金的电阻率及力学性能[J]. 物理学报,2007,56(10):6118-6123.
【9】LASHIN A R,MOSSA M,EL-BEDIWI A,et al. Study of some physical properties of the rapidly solidified Sn-Sb-Cu-Zn alloys[J]. Materials & Design,2013,43:322-326.
【10】LIU Zhe,CHU Zhen-hua,DONG Yan-chun,et al. The effect of metallic bonding layer on the corrosion behavior of plasma sprayed Al2O3 ceramic coatings in simulated seawater[J]. Vacuum,2014,101:6-9.
【11】LI Rui-feng,LI Zhu-guo,HUANG Jian,et al. Effect of Ni-to-Fe ratio on structure and properties of Ni-Fe-B-Si-Nb coatings fabricated by laser processing[J]. Applied Surface Science,2011,257(8):3554-3557.
【12】梁秋颖,孙洪津,孙玥, 等. 不同晶粒尺寸Cu-Ag合金在Na2SO4介质中腐蚀电化学行为研究[J]. 沈阳师范大学学报(自然科学版),2011,29(2):245-248.
【2】SONG J Y, YU J, LEE T Y. Effects of reactive diffusion on stress evolution in Cu-Sn films[J]. Scripta Materialia,2004,51(2):167-170.
【3】DEBIEMME-CHOUVY C, AMMELOOT F, SUTTER E M M. X-ray photoemission investigation of the corrosion film formed on a polished Cu-13Sn alloy in aerated NaCl solution[J]. Applied Surface Science,2001,174(1/2):55-61.
【4】MA X, QIAN Y Y, YOSHIDA F. Effect of La on the Cu-Sn intermetallic compound (IMC) growth and solder joint reliability[J]. J Alloys and Compound,2002,334(1/2):224-227.
【5】AMMELOOT F, FIAUD C, SUTTER E M M. Characterization of the oxide layers on a Cu-13Sn alloy in a NaCl aqueous solution without and with 0.1 M benzotriazole Electrochemical and photoelectrochemical contributions[J]. Electrochimica Acta,1999,44(15):2549-2558.
【6】MULLER J,LAK B,GUILLOT I. A-CuSn bronzes in sulphate medium:Influence of the tin content on corrosion processes[J]. Corrosion Science,2013,77:46-51.
【7】杨扬. 快速凝固Cu-Sn亚包晶合金的微观结构与性能[D]. 西安: 西安理工大学,2007.
【8】翟秋亚,杨扬,徐锦峰,等. 快速凝固CuSn亚包晶合金的电阻率及力学性能[J]. 物理学报,2007,56(10):6118-6123.
【9】LASHIN A R,MOSSA M,EL-BEDIWI A,et al. Study of some physical properties of the rapidly solidified Sn-Sb-Cu-Zn alloys[J]. Materials & Design,2013,43:322-326.
【10】LIU Zhe,CHU Zhen-hua,DONG Yan-chun,et al. The effect of metallic bonding layer on the corrosion behavior of plasma sprayed Al2O3 ceramic coatings in simulated seawater[J]. Vacuum,2014,101:6-9.
【11】LI Rui-feng,LI Zhu-guo,HUANG Jian,et al. Effect of Ni-to-Fe ratio on structure and properties of Ni-Fe-B-Si-Nb coatings fabricated by laser processing[J]. Applied Surface Science,2011,257(8):3554-3557.
【12】梁秋颖,孙洪津,孙玥, 等. 不同晶粒尺寸Cu-Ag合金在Na2SO4介质中腐蚀电化学行为研究[J]. 沈阳师范大学学报(自然科学版),2011,29(2):245-248.
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