Effects of Holding Time on Microstructure and Mechanical Properties of Diffusion Bonded Joint of AZ31B Magnesium Alloy/Al/Cu
摘 要
为实现镁合金AZ31B与铜的可靠连接, 采用铝作为中间层, 在450 ℃保温30~120 min的条件下进行扩散钎焊试验, 研究了保温时间对接头组织、显微硬度和剪切强度的影响。结果表明:保温时间为30 min时, 接头无法实现过渡液相扩散连接; 当保温时间为60 min时, 铝中间层完全溶解, 接头中形成了宽约150 μm的扩散区, 从镁合金侧到铜侧, 扩散区的组织依次为镁基固溶体、共晶组织和Cu3Al2Mg2金属间化合物; 保温不同时间后, 从扩散区的镁合金侧到铜侧, 显微硬度均呈阶梯式升高; 随着保温时间延长, 铜侧过渡层的显微硬度显著增加, 接头的剪切强度先增大后降低, 并在保温90 min后达到最高, 为68.2 MPa; 断裂发生在靠近铜侧的扩散区。
Abstract
To achieve reliable bonding between AZ31B magnesium alloy and copper, diffusion bonding tests for AZ31B magesium alloy and Cu with Al interlayer were carried out at 450 ℃ for 30-120 min, and the effects of holding time on microstructure, microhardness and shear strength of the joint were studied. The results show that the transient liquid phase bonding for the joint could not be achieved when holding time was 30 min. When holding time was 60 min, Al interlayer completely dissolved, and a diffusion zone with width about 150 μm formed in the joint, the microstructures of diffusion zone were magnesium-based solid solution, eutectic structure and Cu3Al2Mg2 intermetallic compound, in turn, from magnesium alloy side to Cu side. After holding for different times, microhardness increased in a stepped form from magnesium alloy side to Cu side in diffussion zone. With the increase of holding time, microhardness of Cu side in fussion zone increased remarkably, shear strength of the joint increased firstly and then decreased, and up to the maximun value of 68.2 MPa when holding time was 90 min. Fracture occurred at diffusion zone near Cu side.
中图分类号 TG115.28 DOI 10.11973/jxgccl201602016
所属栏目 新材料 新工艺
基金项目 陕西省科学与研究发展计划项目(2013K09-22)
收稿日期 2014/12/26
修改稿日期 2015/11/10
网络出版日期
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引用该论文: LAN Tian,DU Shuang-ming,HU Jie. Effects of Holding Time on Microstructure and Mechanical Properties of Diffusion Bonded Joint of AZ31B Magnesium Alloy/Al/Cu[J]. Materials for mechancial engineering, 2016, 40(2): 66~70
兰天,杜双明,胡结. 保温时间对AZ31B镁合金/铝/铜扩散钎焊接头组织与力学性能的影响[J]. 机械工程材料, 2016, 40(2): 66~70
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【6】LIU Li-ming, WANG Sheng-xi, ZHAO Li-min. Study on the dissimilar magnesium alloy and copper lap joint by TIG welding[J].Materials Science and Engineering:A, 2008, 476(12):206-209.
【7】LIU Li-ming, WANG Sheng-xi, ZHAO Li-min.Study on TIG welding of dissimilar Mg alloy and Cu with Fe as interlayer[J].Science and Technology of Welding and Joining, 2006, 11(5):523-525.
【8】李会,林飞,郭继祥,等.挤压态镁合金真空扩散焊试验研究[J].焊接技术, 2011, 40(5):20-23.
【9】董占贵,钱乙余,石素琴,等.合金接触反应钎焊接头力学响应及中间层厚度的确定[J].焊接学报, 2002, 23(1):34-36.
【10】杜双明,赵维涛,刘刚,等.AZ31B镁合金钎焊界面区域的组织结构及性能[J].热加工工艺, 2012, 41(1):140-144.
【11】WU Ming-fang, SI Nai-chao, CHEN Jian. Contact reactivebrazing of Al alloy/Cu/stainless steel joints and dissolution behaviors of interlayer[J]. Transactions of Nonferrous Metals Society of China, 2011, 5(21):1035-1039.
【12】董占贵, 钱乙余, 石素琴.Al/Cu/Al接触反应液相行为及其连接[J].焊接学报, 2001, 22(6):45-47.
【13】熊江涛,张赋升,李京龙.镁合金与钛合金的瞬间液相扩散焊[J].稀有金属材料工程, 2006, 35(10):77-80.
【14】杜双明,刘刚,王明静.异种金属过渡液相扩散焊接头的显微组织及性能[J].中国有色金属学报, 2013, 23(5):55-61.
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【16】陈定华,钱乙余,黄继华.Al/Cu接触反应钎焊中反应铺展现象和氧化膜行为[J].金属学报, 1989, 25(1):42-47.
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