Effect of Al on Corrosion Resistance of Bridge Steel in Humid and Warm Industrial-Marine Atmosphere
摘 要
通过周期浸润加速腐蚀试验、腐蚀失重试验、扫描电镜(SEM)、X射线衍射(XRD)、电化学测试等方法, 研究了湿热工业-海洋大气环境中, 铝对桥梁钢耐蚀性的影响。结果表明: 试验钢的腐蚀过程遵循幂函数分布规律, 锈层以向内生长为主; 铝具有强化铁素体组织、抑制腐蚀产物结晶和促进具有保护作用的细晶氧化物膜生成等优势, 有利于提高试验钢的耐蚀性, 但铝氧化物容易与含硫酸发生反应, 使锈层中形成较多的锈巢和裂纹; 随腐蚀时间的延长, 裂纹增多, 锈巢增大, 锈层结构不断被破坏, 到腐蚀后期, 生成垂直裂纹, 加速了腐蚀性粒子的入侵, 最终导致腐蚀速率上升, 钢基体腐蚀恶化。
Abstract
The effect of Al on the corrosion resistance of bridge steel in simulated industrial-marine atmosphere was investigated by wet/dry alternate immersion corrosion testing, mass loss testing, X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical testing. The results indicate that the corrosion process of the experimental steel shows a good agreement with the power function, and the growth trend of the rust layer is mainly inward. Al has the advantages in strengthening ferrite microstructure, inhibiting the crystallization of corrosion products, and promoting the formation of a dense protective film made of fine-grained oxide, which can help to improve the weather resistance of the steel. However, in the humid and warm industry-marine atmosphere, acids could be generated by the reaction between SO2 and H2O, leading to the corrosion of the rust layer and steel substrate. Besides, compared with iron oxides, the Al-containing oxides are easier to react with acids and result in more rust nests and cracks forming in the rust layer. With the increase of corrosion time, the number of cracks increases, and the volume of rust nests becomes bigger, the structure of the rust layer is thus continuously being damaged. By the late stage of corrosion, the infiltration of corrosive particles is accelerated by the formation of the cracks perpendicular to the steel substrate, leading to the increase of corrosion rate and the decline of corrosion resistance of the steel.
中图分类号 TG174 DOI 10.11973/fsyfh-201610001
所属栏目 海工材料腐蚀与防护
基金项目 国家自然科学基金项目(51304040); 教育部基本科研业务费项目(N150204008)
收稿日期 2016/3/1
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备注朱苗勇(1965-), 教授, 博士, 从事先进冶炼与连铸工艺及装备技术的研究工作,
引用该论文: LI Dong-liang,FU Gui-qin,ZHU Miao-yong. Effect of Al on Corrosion Resistance of Bridge Steel in Humid and Warm Industrial-Marine Atmosphere[J]. Corrosion & Protection, 2016, 37(10): 781
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参考文献
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【3】王克武. 碳钢表面热浸镀铝[J]. 表面技术,1995,24(4): 21-25.
【4】陈建阳,肖跃文,李雄晖,等. 电弧喷铝涂层的保护极限及钢箱梁桥大面积长效防腐[J]. 桥梁建设,2001(1): 32-34.
【5】EVANS U R. The mechanism of rusting[J]. Quarterly Reviews-Chemical Society,London,1967,21(1): 29-43.
【6】CHEN X H,DONG J H,HAN E H,et al. The synergistic effect of aluminium and silicon on corrosion resistance of chlorine ion for low alloy steel[C]//Proceedings of the 3rd International Conference on Advanced Structural Steels.[S.l.]: [s.n.],2006: 635-639.
【7】CHEN X H,DONG J H,HAN E H,et al. Effect of Al alloying on corrosion performance of steel[J]. Corrosion Engineering,Science and Technology,2007,42(3): 224-231.
【8】董俊华,韩恩厚,柯伟,等. 一种Al-Si型经济耐候钢: CN101033520[P]. 2007-09-12.
【9】陈新华. 合金元素对经济耐候钢大气腐蚀协同抑制作用[D]. 沈阳: 中国科学院金属研究所,2007.
【10】NISHIMURA T. Corrosion resistance of Si and Al-bearing ultrafine grained weathering steel[J]. Materials Science Forum,2005,475/479: 55-60.
【11】NISHIMURA T. Rust formation and corrosion performance of Si- and Al-bearing ultrafine grained weathering steel[J]. Corrosion Science,2008,50(5): 1306-1312.
【12】NISHIMURA T. Corrosion resistance of Si-Al-bearing ultrafine-grained weathering steel[J]. Science and Technology of Advanced Materials,2008,9(1): 1-7.
【13】NISHIMURA T. Electrochemical behavior and structure of rust formed on Si- and Al-bearing steel after atmospheric exposure[J]. Corrosion Science,2010,52(11): 3609-3614.
【14】许红梅,张宇,王银柏,等. 一种低成本硅铝耐候钢的研制[J]. 钢铁,2013,48(8): 70-74.
【15】邹德辉,郭爱民. 我国铁路桥梁用钢的现状与发展[J]. 钢结构,2009,24(9): 1-5.
【16】崔忠圻,覃耀春. 金属学与热处理[M]. 北京: 机械工业出版社,2009: 228.
【17】孙珍宝,朱谱藩. 合金钢手册[M]. 北京: 冶金工业出版社,1982: 59-78.
【18】BURGER E,FENART M,PERRIN S,et al. Use of the gold markers method to predict the mechanisms of iron atmospheric corrosion[J]. Corrosion Science,2011,53(6): 2122-2130.
【19】林翠,赵晴,刘月娥,等. 含SO2大气中20碳钢腐蚀产物的演变[J]. 金属学报,2010,46(3): 358-365.
【20】HAO L,ZHANG S X,DONG J H,et al. Rusting evolution of MnCuP weathering steel submitted to simulated industrial atmospheric corrosion[J]. Metallurgical and Materials Transactions: A,2012,43(5): 1724-1730.
【21】董杰,董俊华,韩恩厚,等. 低碳钢带锈电极的腐蚀行为[J]. 腐蚀科学与防护技术,2006,18(6): 414-417.
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