Research Progress on B4C/TiB2 Composite Ceramics
摘 要
综述了B4C/TiB2复相陶瓷的烧结工艺, 以及原料粉体粒径和第三组元对复相陶瓷性能的研究进展。对比了热压烧结、放电等离子烧结和无压反应烧结B4C/TiB2复相陶瓷相对密度和力学性能的差别, 比较了三种烧结工艺的优缺点; 总结了多种金属单质、金属氧化物、碳、过渡金属碳化物等第三组元, 以及粉体粒径对复相陶瓷烧结工艺性等性能的影响规律; 展望了B4C/TiB2复相陶瓷制备技术的发展趋势。
Abstract
Sintering processes for B4C/TiB2 composite ceramics, and effects of particle size and third elements on properties of the ceramics were summarized. Difference for relative density and mechanical properties among B4C/TiB2 composite ceramics prepared by hot pressed sintering, spark plasma sintering and reaction sintering, meanwhile, advantages and disadvantages of three kinds sintering progresses were compared. The effect law of the third additives and particles size on sintering usability and properties of the composite ceramics were summarized, and the additives included metals, metal oxides, carbon and transition metal carbides. Outlook about development tendency of B4C/TiB2 composite ceramics was completed.
中图分类号 TB332 DOI 10.11973/jxgccl201611001
所属栏目 综 述
基金项目 上海市教委重点项目(13ZZ133); 上海工程技术大学研究生科研创新资助项目(15KY0506)
收稿日期 2015/10/20
修改稿日期 2016/8/25
网络出版日期
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备注吴晓(1987-), 男, 浙江平湖人, 硕士研究生。
引用该论文: WU Xiao,YANG Ya-yun,LIN Wen-song. Research Progress on B4C/TiB2 Composite Ceramics[J]. Materials for mechancial engineering, 2016, 40(11): 1~4
吴 晓,杨亚云,林文松. B4C/TiB2复相陶瓷材料的研究进展[J]. 机械工程材料, 2016, 40(11): 1~4
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参考文献
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【2】ZORZI J E, PEROTTONI C A, JORNADA J A H. Hardness and wear resistance of B4C ceramics prepared with several additives[J]. Mater Lett, 2005, 59: 2932-2935.
【3】JUNG J, KANG S. Advances in manufacturing boron carbide-aluminum composites[J]. J Am Ceram Soc, 2004, 87(1): 47-54.
【4】DENG J. Microstructure and mechanical properties of hot pressed B4C/(W,Ti)C ceramic composites[J]. Ceram Int, 2002, 28: 425-430.
【5】HEYDARI M S, BAHARVANDI H R. Comparing the effects of different sintering methods for ceramics on the physical and mechanical properties of B4C-TiB2 nanocomposites[J]. Int J Refrac Met & Hard Mater, 2015, 51: 224-232.
【6】WANG Y, PENG H, YE F, et al. Effect of TiB2 content on microstructure and mechanical properties of in-situ fabricated TiB2/B4C composites[J]. Trans Nonferrous Metals Soc China, 2011, 21: 369-373.
【7】MALEK O. Electrical discharge machining of B4C-TiB2 composites[J]. J Eur Ceram Soc, 2011, 31(11): 2023-2030.
【8】唐军, 谭寿洪, 陈忠明, 等. B4C-TiB2复相陶瓷的强韧化研究[J]. 无机材料学报, 1997, 12(2): 169-174.
【9】SKOROKHOD V V. High strength-high toughness B4C-TiB2 composites[J]. J Mater Sci Lett, 2000,19 (3): 237-239.
【10】DELGADO Y P, STAIA M H, MALEK O, et al. Friction and wear response of pulsed electric current sintered TiB2-B4C ceramic composite[J]. Wear, 2014, 317(1/2): 104-110.
【11】HUANG S G, VANMEENSEL K, MALEK O J A, et al. Microstructure and mechanical properties of pulsed electric current sintered B4C/TiB2 composites[J]. Mater Sci Eng A, 2011, 528(2): 1302-1309.
【12】DUDINA D, HULBERT D, JIANG D, et al. In situ boron carbide-titanium diboride composites prepared by mechanical milling and subsequent spark prima sintering[J]. J Mater Sci, 2008, 43(10): 3569-3576.
【13】HEYDARI M S, BAHARVANDI H R, DOLATKHAH K. Effect of TiO2 nanoparticles on the pressureless sintering of B4C-TiB2 nanocomposites[J]. Int J Refrac Met & Hard Mater, 2015, 51: 6-13.
【14】SKOROKHOD V. Pressureless sintering of B4C-TiB2 ceramic composites[J]. Mater Sci Forum,1998, 282: 219-224.
【15】喻亮, 茹红强, 蔡继东. 热压C-SiC-B4C-TiB2复合材料的组织与力学性能[J]. 中国有色金属学报, 2008,18(2): 271-277.
【16】GOLDSTEIN A, YESHURUN Y, GOLDENBERG A. B4C/metal boride composites derived from B4C/metal oxide mixtures[J]. J Eur Ceram Soc, 2007, 27(2/3): 695-700.
【17】LEVIN L, FRAGE N M P. A novel approach for the preparation of B4C-based cermets[J]. Int J Refract Met & Hard Mater, 2000, 18: 131-135.
【18】YUE X, ZHAO S, LU P,et al. Synthesis and properties of hot pressed B4C-TiB2 ceramic composite[J]. Mater Sci Eng A, 2010,527(27/28): 7215-7219.
【19】LU P, YUE X, YU L, et al. Effect of in situ synthesized TiB2 on the reaction between B4C and Al in a vacuum infiltrated B4C-TiB2-Al composite[J]. J Mater Sci, 2009, 44: 3483-3487.
【20】MASHHADI M, TAHERI-NASSAJ E, MASHHADI M, et al. Pressureless sintering of B4C-TiB2 composites with Al additions[J]. Ceram Int, 2011, 37: 3229-3235.
【21】DANIEL B S S, MURTHY V S R, MURTY G S. Metal-ceramic composites via in-situ methods[J]. Journal of Materials Processing Technology, 1997, 68(2): 132-155.
【22】GUO F W, JIHONG Z, CHUNPING Z. Densification and mechanical properties of B4C based composites sintered by reaction hot-pressing[J]. Key Eng Mater, 2010, 434/435: 24-27.
【23】SIGL L S, KLEEBE H J. Microcracking in B4C-TiB2 composites[J]. J Am Ceram Soc, 1995, 78: 2374-2380.
【24】MCCUISTON R, LASALVIA J, MOSER B. Effect of carbon additions and B4C particle size on the microstructure and properties of B4C-TiB2 composites[M]// Mechanical Properties and Performance of Engineering Ceramics and Composites III.[s.l.]: [s.n.], 2007: 257-268.
【25】HEYDARI M S, BAHARVANDI H R. Effect of different additives on the sintering ability and the properties of B4C-TiB2 composites[J]. Int J Refract Met & Hard Mater, 2015, 51: 61-69.
【26】SIGL L S. Processing and mechanical properties of boron carbide sintered with TiC[J]. J Eur Ceram Soc, 1998, 18: 1521-1529.
【27】LI D, ZHOU Y, GUO Y. Processing and characteristics of TiB2 toughened B-Ti-C composites[J]. Trans Nonferrous Metals Soc, 2003, 13: 314-320.
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