金属基合金表面超疏水膜的构筑及其耐蚀性的研究进展
Research Progress on Construction and Corrosion Performance of Superhydrophobic Film on Surface of Metal Based Alloys
摘 要
超疏水技术是一项新型的腐蚀防护技术，在金属基合金表面构筑超疏水膜能有效地抑制金属和合金材料发生腐蚀。介绍了金属基合金表面超疏水膜的构筑方法，重点分析了超疏水膜对金属合金基体耐蚀性能的影响，最后总结了超疏水技术近年来的发展，及其存在的技术障碍。
超疏水膜
构筑
耐蚀性
进展
metal based alloy
superhydrophobic film
construction
corrosion resistance
progress
Abstract
As a new kind of technique for corrosion protection, superhydrophobic film on the surface of metal based alloys can inhibit the corrosion of metal and alloy effectively. The construction methods of superhydrophobic film on the surface of metal based alloys are summarized. Then the effects of superhydrophobic film on corrosion resistance of metal based alloys are analyzed emphatically. At last, the development of superhydrophobic technique in recent years and the existed technical barriers are concluded.
中图分类号 TG174.42 DOI 10.11973/fsyfh-201612009
所属栏目 专论
基金项目 国家自然科学基金（21553001）; 上海市教委科技创新重点项目（14ZZ152）
收稿日期 2015/5/2
修改稿日期
网络出版日期
作者单位点击查看
备注徐群杰(1969-)，教授，博士，从事电厂化学和腐蚀电化学的研究
引用该论文: HAN Jie,LIU Wei,MIN Yu-lin,XU Qun-jie. Research Progress on Construction and Corrosion Performance of Superhydrophobic Film on Surface of Metal Based Alloys[J]. Corrosion & Protection, 2016, 37(12): 988
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参考文献
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【22】李杰,张会臣. MB8镁合金超疏水表面的制备和润湿性[J]. 材料研究学报,2012,26(3):240-245.
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【28】万勇,王中乾,刘义芳. 金属锌表面超疏水薄膜的制备及其摩擦学性能[J]. 无机材料学报,2012,27(4):390-394.
【29】吴勃,周明,李保家,等. 飞秒激光结合水热法制备不锈钢高粘附超疏水表面[J]. 功能材料,2013,24(44):3568-6662.
【30】BASU B J,HARIPRAKASH V,ARUNA S T,et al. Effect of microstructure and surface roughness on the wettability of superhydrophobic sol-gel nanocomposite coatings[J]. Journal of Sol-gel Science and Technology,2010,56(3):278-286.
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【32】WANG J,LI D,LIU Q,et al. Fabrication of hydrophobic surface with hierarchical structure on Mg alloy and its corrosion resistance[J]. Electrochimica Acta,2010,55(22):6897-6906.
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【35】WANG P,QIU R,ZHANG D,et al. Fabricated super-hydrophobic film with potentiostatic electrolysis method on copper for corrosion protection[J]. Electrochimica Acta,2010,56(1):517-522.
【36】LU Z,WANG P,ZHANG D. Super-hydrophobic film fabricated on aluminium surface as a barrier to atmospheric corrosion in a marine environment[J]. Corrosion Science,2015,91:287-296.
【37】LIU Y,LIU J,LI S,et al. Fabrication of biomimetic super-hydrophobic surface on aluminum alloy[J]. Journal of Material Science,2014,49(4):1624-1629.
【38】PENG S,TIAN D,YANG X,et al. Highly efficient and large-scale fabrication of superhydrophobic alumina surface with strong stability based on self-congregated alumina nanowires[J]. Applied Materials & Interfaces,2014,6(7):4831-4841.
【39】LI X,ZHANG Q,GUO Z,et al. Fabrication of superhydrophobic surface with improved corrosion inhibition on 6061 aluminum alloy substrate[J]. Applied Surface Science,2015,342(1):76-83.
【40】侯文婷,康志新. Mg-Li合金表面浅绿色超疏水复合膜层的制备及耐蚀性能研究[J]. 中国腐蚀与防护学报,2012,32(4):306-310.
【41】赖晓明,康志新,李元元. AZ31镁合金微弧氧化与有机镀膜复合表面改性及功能特性[J]. 中国有色金属学报,2011,21(6):1299-1307.
【42】徐喆,连峰,张会臣. 基于激光加工和自组装技术改性处理铝镁合金的表面润湿性[J]. 中国有色金属学报,2012,22(7):1855-1862.
【43】ZHAO L,LIU Q,GAO R,et al. One-step method for the fabrication of superhydrophobic surface on magnesium alloy and its corrosion protection,antifouling performance[J]. Corrosion Science,2014,80:177-183.
【44】NICOLA F D,CASTRUCCI P,SCARSELLI M,et al. Super-hydrophobic multi-walled carbon nanotube coatings for stainless steel[J]. Nanotechnology,2015,26(14):145701.
【45】王帅波,尹衍升,刘涛,等. 超疏水膜改性Fe3Al在海水中的腐蚀行为[J]. 中国腐蚀与防护学报,2009,29(2):137-140.
【2】冯琳,江雷. 仿生智能纳米界面材料[M]. 北京:化学工业出版社,2007.
【3】余存烨． 滨海石化厂钛铜共用海水冷却器牺牲阳极保护探讨[J]. 腐蚀与防护,2004,25(2):61-64．
【4】王宏智,陈君，周建奇，等. 紫铜海水管焊接部位在人工海水中的腐蚀行为[J]. 化工学报,2006,57(11):153-157.
【5】林泽泉,刘爽,孙志强,等. 核电厂反冲洗海水管道内壁防腐蚀处理技术的应用[J]. 腐蚀与防护,2014,35(12):1263-1265.
【6】徐群杰,朱律均,曹为民,等. 绿色缓蚀剂聚天冬氨酸对铜的缓蚀性能与吸附行为[J]. 物理化学学报,2008,24(9):1724-1728.
【7】李美明,徐群杰,韩杰,等. 绿色铜缓蚀剂的研究进展[J]. 腐蚀与防护,2014,35(12):1243-1247.
【8】徐群杰,池国镇,时士峰,等. 聚环氧琥珀酸对白铜在3% NaCl溶液中的缓蚀作用[J]. 材料保护,2011,44(7):71-73.
【9】季献武,时士峰,肖嵘,等. 硅烷处理对涂层/金属体系耐蚀性能的影响[J]. 腐蚀与防护,2012,33(12):1081-1086.
【10】WENZEl R N. Resistance of solid surface to wetting by water[J]. Ind Eng Chem,1936,28(8):988-994.
【11】CASSIE A B D,BAXTER S. Wettability of porous surfaces[J]. Trans Faraday Soc,1944,36(4):546-561.
【12】XU X,ZHU L,LI W,et al. A variable hydrophobic surface improves corrosion resistance of electroplating copper coating[J]. Applied Surface Science,2011,257(13):5524-5528.
【13】XU X，ZHANG Z，YANG J． Fabrication of biomimetic superhydrophobic surface on engineering materials by a simple electroless galvanic deposition method[J]. Langmuir,2010,26(5):3654-3658.
【14】邓先钦,徐群杰,云虹,等. 具有超疏水表面的铜及铜合金电化学行为研究进展[J]. 腐蚀与防护,2012,33(1):741-748.
【15】ISHIZAKI T,KUDO R,OMI T,et al. Corrosion resistance of multilayered magnesium phosphate/magnesium hydroxide film formed on magnesium alloy using steam-curing assisted chemical conversion method[J]. Electrochemica Acta,2012,62(1):19-29.
【16】PENG S,TIAN D,MIAO X R,et al. Designing robust alumina nanowires-on-nanopores structures:superhydrophobic surfaces with slippery or sticky water adhesion[J]. Journal of Colloid and Interface Science,2013,409(11):18-24.
【17】SHAIK U P,KSHIRSAGAR S,KRISHNA M G,et al. Growth of superhydrophobic zinc oxide nanowire thin films[J]. Materials Letters,2012,75(1):51-53.
【18】于思荣,刘家安,刁伟. X52管线钢仿生超疏水表面的制备[J]. 科学通报,2014,59(3):273-278.
【19】马福明,郝全勇,张燕,等. 氧化还原法刻蚀制备铜基超疏水表面[J]. 材料技术与工业,2013,14(13):1671-1815.
【20】SU F H,YAO K. Facile fabrication of superhydrophobic surface with excellent mechanical abrasion and corrosion resistance on copper substrate by a novel method[J]. ACS Applied Materials & Interfaces,2014,6(11):8762-8770.
【21】LIANG J,GUO Z,FANG J,et al. Fabrication of superhydrophobic surface on magnesium alloy[J]. Chemistry Letters,2007,36(3):416-417.
【22】李杰,张会臣. MB8镁合金超疏水表面的制备和润湿性[J]. 材料研究学报,2012,26(3):240-245.
【23】ISHIZAKI T,SAITO N. Rapid formation of a superhydrphobic surface on a magnesium alloy coated with a cerium oxide film by a simple immersion process at room temperature and its chemical stability[J]. Langmuir,2010,26(12):9749-9755.
【24】LIU Y,YIN X M,ZHANG J J,et al. A electro-deposition process for fabrication of biomimetic super-hydrophobic surface and its corrosion resistance on magnesium alloy[J]. Electrochimica Acta,2014,125(10):395-403.
【25】WANG H,DAI D,WU X. Fabrication of superhydrophobic surfaces on aluminum[J]. Applied Surface Science,2008,254(17):5599-5601.
【26】RUAN M,LI W,WANG B,et al. Optimal conditions for the preparation of superhydrophobic surfaces on al substrates using a simple etching approach[J]. Applied Surface Science,2012,258(18):7031-7035.
【27】ZUO Z,LIAO R,GUO C,et al. Fabrication and anti-icing property of coral-like superhydrophobic aluminum surface[J]. Applied Surface Science,2015,331(15):132-139.
【28】万勇,王中乾,刘义芳. 金属锌表面超疏水薄膜的制备及其摩擦学性能[J]. 无机材料学报,2012,27(4):390-394.
【29】吴勃,周明,李保家,等. 飞秒激光结合水热法制备不锈钢高粘附超疏水表面[J]. 功能材料,2013,24(44):3568-6662.
【30】BASU B J,HARIPRAKASH V,ARUNA S T,et al. Effect of microstructure and surface roughness on the wettability of superhydrophobic sol-gel nanocomposite coatings[J]. Journal of Sol-gel Science and Technology,2010,56(3):278-286.
【31】杨武,裴奔,郭昊,等. 十二羟基硬脂酸的醇溶液浸泡金属片引发的超疏水性[J]. 西北师范大学学报,2011,47(3):54-59.
【32】WANG J,LI D,LIU Q,et al. Fabrication of hydrophobic surface with hierarchical structure on Mg alloy and its corrosion resistance[J]. Electrochimica Acta,2010,55(22):6897-6906.
【33】HUANG Y,SARKAR D K,GALLANT D,et al. Corrosion resistance properties of superhydrophobic copper surfaces fabricated by one-step electrochemical modification process[J]. Applied Surface Science,2013,282(1):689-694.
【34】RAO A V,LATTHE S S,MAHADIK S A,et al. Mechanically stable and corrosion resistant superhydrophobic sol-gel coatings on copper substrate[J]. Applied Surface Science,2011,257(13):5722-5776.
【35】WANG P,QIU R,ZHANG D,et al. Fabricated super-hydrophobic film with potentiostatic electrolysis method on copper for corrosion protection[J]. Electrochimica Acta,2010,56(1):517-522.
【36】LU Z,WANG P,ZHANG D. Super-hydrophobic film fabricated on aluminium surface as a barrier to atmospheric corrosion in a marine environment[J]. Corrosion Science,2015,91:287-296.
【37】LIU Y,LIU J,LI S,et al. Fabrication of biomimetic super-hydrophobic surface on aluminum alloy[J]. Journal of Material Science,2014,49(4):1624-1629.
【38】PENG S,TIAN D,YANG X,et al. Highly efficient and large-scale fabrication of superhydrophobic alumina surface with strong stability based on self-congregated alumina nanowires[J]. Applied Materials & Interfaces,2014,6(7):4831-4841.
【39】LI X,ZHANG Q,GUO Z,et al. Fabrication of superhydrophobic surface with improved corrosion inhibition on 6061 aluminum alloy substrate[J]. Applied Surface Science,2015,342(1):76-83.
【40】侯文婷,康志新. Mg-Li合金表面浅绿色超疏水复合膜层的制备及耐蚀性能研究[J]. 中国腐蚀与防护学报,2012,32(4):306-310.
【41】赖晓明,康志新,李元元. AZ31镁合金微弧氧化与有机镀膜复合表面改性及功能特性[J]. 中国有色金属学报,2011,21(6):1299-1307.
【42】徐喆,连峰,张会臣. 基于激光加工和自组装技术改性处理铝镁合金的表面润湿性[J]. 中国有色金属学报,2012,22(7):1855-1862.
【43】ZHAO L,LIU Q,GAO R,et al. One-step method for the fabrication of superhydrophobic surface on magnesium alloy and its corrosion protection,antifouling performance[J]. Corrosion Science,2014,80:177-183.
【44】NICOLA F D,CASTRUCCI P,SCARSELLI M,et al. Super-hydrophobic multi-walled carbon nanotube coatings for stainless steel[J]. Nanotechnology,2015,26(14):145701.
【45】王帅波,尹衍升,刘涛,等. 超疏水膜改性Fe3Al在海水中的腐蚀行为[J]. 中国腐蚀与防护学报,2009,29(2):137-140.
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