Structure and Remnant Life of HP40Nb Steel Furnace Tube after Long-Term High-Temperature Service
摘 要
利用光学显微镜、扫描电镜、能谱仪、拉伸及冲击试验机等对服役15 a的制氢转化炉中HP40Nb钢炉管的显微组织和力学性能进行了研究,依据高温持久试验结果估算了炉管剩余寿命。结果表明:长期高温服役后,炉管钢组织中晶界粗化并有G相析出,晶内二次碳化物析出明显,近内壁、近外壁和基体中均出现蠕变孔洞,近内壁和近外壁发生氧化和贫铬,外壁形成脱碳层;与原始铸态炉管相比,长期高温服役后炉管的室温抗拉强度降幅超30%,高温抗拉强度降幅约18%,室温冲击功下降明显,剩余寿命不足1 a。
Abstract
The microstructure and mechanical properties of HP40Nb steel furnace tube in a hydrogen reformer after 15-year service were studied by optical microscope, scanning electron microscope, energy dispersive spectrometer, tensile and impact testers. Based on the high-temperature creep rupture testing results, the remnant life of the furnace tube was evaluated. The results show that after the long-term high-temperature service, in the microstructure of furnace tube steel, the grain boundaries coarsened with the G phase precipitation; secondary carbides precipitated in grains obviously; creep voids were observed near inner and outer wall and in matrix; oxidation and chromium depletion were observed near inner and outer wall; decarburization layer was formed on the outer wall. Compared with the as-cast steel furnace tube, the tensile strength of the furnace tube after the long-term high-temperature service reduced by 30% and 18% at room and high temperature, respectively, the impact energy at room temperature decreased significantly, and the remnant life was less than 1 a.
中图分类号 TG142.73 TE963 TQ052.6 DOI 10.11973/jxgccl201706012
所属栏目 材料性能及应用
基金项目 CAP1400核电站运行和维护技术研究(2015ZX06002005)
收稿日期 2016/4/6
修改稿日期 2017/4/30
网络出版日期
作者单位点击查看
备注樊钊(1984-),男,山东临朐人,工程师,硕士
引用该论文: FAN Zhao,XU Wei,CHEN Weimin,WANG Guanghui. Structure and Remnant Life of HP40Nb Steel Furnace Tube after Long-Term High-Temperature Service[J]. Materials for mechancial engineering, 2017, 41(6): 49~54
樊钊,徐伟,陈伟民,王光辉. 长期高温服役后HP40Nb钢炉管的组织及剩余寿命[J]. 机械工程材料, 2017, 41(6): 49~54
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参考文献
【1】杜中强. 新型制氢转化炉的应用[J]. 石油化工设备技术, 2005,26(2):40-41.
【2】WANG W Z, XUAN F Z, WANG Z D,et al. Effect of overheating temperature on the microstructure and creep behavior of HP40Nb alloy[J]. Materials and Design, 2011,32(7):4010-4016.
【3】孙长海, 郭林海, 马海涛, 等. 石油企业HP40Nb钢制氢转化炉炉管破裂分析[J]. 化工学报, 2013,64(S1):159-164.
【4】湛小琳, 刘智勇, 杜翠薇, 等. HP40Nb钢制氢转化炉炉管失效分析[J].腐蚀科学与防护技术, 2012,24(6):498-502.
【5】张文书, 林旭, 吕永超, 等. HP40Nb 炉管爆管失效分析[J].铸造技术, 2014,35(2):314-316.
【6】刘建杰,巩建鸣,姜勇, 等. 采用修正θ投影法预测Cr25Ni35Nb炉管钢的蠕变性能[J].机械工程材料, 2011,35(1):89-92.
【7】杨晓靖, 侯聚现. 制氢转化炉炉管状态分析与寿命评估[J]. 石油与化工设备, 2010,13(1):34-37.
【8】王友华,魏安安, 纪熙, 等. 制氢转化炉炉管剩余寿命评估[J].腐蚀与防护, 2012, 33(4):335-337.
【9】LIU C J, CHEN Y. Variations of the microstructure and mechanical properties of HP40Nb hydrogen reformer tube with time at elevated temperature[J]. Materials and Design, 2011,32(4):2507-2512
【10】MERTINGER V, BENKE M, KISS G, et al. Degradation of a corrosion and heat resistant steel pipe[J]. Engineering Failure Analysis, 2013,29:38-44.
【11】CHEN Q Z, THOMAS C W, KNOWLES D M.Characterisation of 20Cr32Ni1Nb alloys in as-cast and ex-service conditions by SEM, TEM and EDX[J]. Materials Science and Engineering A, 2004, 374(1/2):398-408.
【12】VOICUA R, ANDRIEUA E, POQUILLONA D, et al. Microstructure evolution of HP40-Nb alloys during aging under air at 1 000℃[J]. Materials Characterization, 2009, 60(9):1020-1027.
【13】ALVINO A, LEGA D, GIACOBBE F,et al. Damage characterization in two reformer heater tubes after nearly 10 years of service at different operative and maintenance conditions[J]. Engineering Failure Analysis, 2010,17(7):1526-1541.
【14】KENIK E A, MAZIASZ P J, SWINDEMAN R W,et al. Structure and phase stability in a cast modified-HP austenite after long term ageing[J]. Scripta Materialia, 2003, 49(2):117-122.
【15】SWAMINATHAN J, GUGULOTH K, GUNJAN M,et al. Failure analysis and remaining life assessment of service exposed primary reformer heater tubes[J]. Engineering Failure Analysis, 2008, 15(4):311-331.
【16】RAY A K, KUMAR S, KRISHNA G,et al. Microstructural studies and remnant life assessment of eleven years service exposed reformer tube[J]. Materials Science and Engineering A, 2011,529:102-112.
【17】徐宏, 夏翔鸣, 王印培,等. 改质炉高温炉管运行损伤及剩余寿命分析[J]. 华东理工大学学报(自然科学版), 2001,27(4):399-402.
【18】丁毅, 沈复中, 吕勇. 不同服役期的HK-40炉管显微组织分析[J]. 机械工程材料, 2002,26(7):7-9.
【19】RODRIGUEZ J, HARO S, VELASCO A, et al. A metallographic study of aging in a cast heat-resisting alloy[J]. Materials Characterization, 2000,45 (1):25-32.
【20】ALMEIDA L H, RIBEIRO A F, MAY I L. Microstructural characterization of modified 25Cr-35Ni centrifugally cast steel furnace tubes[J]. Materials Characterization, 2003,49(3):219-229.
【21】任颂赞, 叶俭, 陈德华.金相分析原理及技术[M].上海:上海科学技术文献出版社, 2012:577,642.
【2】WANG W Z, XUAN F Z, WANG Z D,et al. Effect of overheating temperature on the microstructure and creep behavior of HP40Nb alloy[J]. Materials and Design, 2011,32(7):4010-4016.
【3】孙长海, 郭林海, 马海涛, 等. 石油企业HP40Nb钢制氢转化炉炉管破裂分析[J]. 化工学报, 2013,64(S1):159-164.
【4】湛小琳, 刘智勇, 杜翠薇, 等. HP40Nb钢制氢转化炉炉管失效分析[J].腐蚀科学与防护技术, 2012,24(6):498-502.
【5】张文书, 林旭, 吕永超, 等. HP40Nb 炉管爆管失效分析[J].铸造技术, 2014,35(2):314-316.
【6】刘建杰,巩建鸣,姜勇, 等. 采用修正θ投影法预测Cr25Ni35Nb炉管钢的蠕变性能[J].机械工程材料, 2011,35(1):89-92.
【7】杨晓靖, 侯聚现. 制氢转化炉炉管状态分析与寿命评估[J]. 石油与化工设备, 2010,13(1):34-37.
【8】王友华,魏安安, 纪熙, 等. 制氢转化炉炉管剩余寿命评估[J].腐蚀与防护, 2012, 33(4):335-337.
【9】LIU C J, CHEN Y. Variations of the microstructure and mechanical properties of HP40Nb hydrogen reformer tube with time at elevated temperature[J]. Materials and Design, 2011,32(4):2507-2512
【10】MERTINGER V, BENKE M, KISS G, et al. Degradation of a corrosion and heat resistant steel pipe[J]. Engineering Failure Analysis, 2013,29:38-44.
【11】CHEN Q Z, THOMAS C W, KNOWLES D M.Characterisation of 20Cr32Ni1Nb alloys in as-cast and ex-service conditions by SEM, TEM and EDX[J]. Materials Science and Engineering A, 2004, 374(1/2):398-408.
【12】VOICUA R, ANDRIEUA E, POQUILLONA D, et al. Microstructure evolution of HP40-Nb alloys during aging under air at 1 000℃[J]. Materials Characterization, 2009, 60(9):1020-1027.
【13】ALVINO A, LEGA D, GIACOBBE F,et al. Damage characterization in two reformer heater tubes after nearly 10 years of service at different operative and maintenance conditions[J]. Engineering Failure Analysis, 2010,17(7):1526-1541.
【14】KENIK E A, MAZIASZ P J, SWINDEMAN R W,et al. Structure and phase stability in a cast modified-HP austenite after long term ageing[J]. Scripta Materialia, 2003, 49(2):117-122.
【15】SWAMINATHAN J, GUGULOTH K, GUNJAN M,et al. Failure analysis and remaining life assessment of service exposed primary reformer heater tubes[J]. Engineering Failure Analysis, 2008, 15(4):311-331.
【16】RAY A K, KUMAR S, KRISHNA G,et al. Microstructural studies and remnant life assessment of eleven years service exposed reformer tube[J]. Materials Science and Engineering A, 2011,529:102-112.
【17】徐宏, 夏翔鸣, 王印培,等. 改质炉高温炉管运行损伤及剩余寿命分析[J]. 华东理工大学学报(自然科学版), 2001,27(4):399-402.
【18】丁毅, 沈复中, 吕勇. 不同服役期的HK-40炉管显微组织分析[J]. 机械工程材料, 2002,26(7):7-9.
【19】RODRIGUEZ J, HARO S, VELASCO A, et al. A metallographic study of aging in a cast heat-resisting alloy[J]. Materials Characterization, 2000,45 (1):25-32.
【20】ALMEIDA L H, RIBEIRO A F, MAY I L. Microstructural characterization of modified 25Cr-35Ni centrifugally cast steel furnace tubes[J]. Materials Characterization, 2003,49(3):219-229.
【21】任颂赞, 叶俭, 陈德华.金相分析原理及技术[M].上海:上海科学技术文献出版社, 2012:577,642.
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