Corrosion Behavior of X65 Steel in Simulated Gathering Pipeline Environment
摘 要
通过腐蚀失重、SEM、XRD等方法,研究了X65钢在模拟集输管道CO2/油/水环境中的腐蚀特性。结果表明:X65钢腐蚀速率随流速和CO2分压升高均呈现先增大后减小的趋势,存在临界流速和临界压力;低于临界值,基体表面上生成的腐蚀产物疏松多孔、不稳定,高于临界值后形成的产物膜致密、附着力较强,具有一定保护作用;流速增大超过1 m/s会使油膜比较均匀地吸附在试样表面,减少了腐蚀反应活性点,一定程度上保护了基体不被腐蚀,腐蚀速率下降;随CO2分压增大,CO2在原油内的溶解度增加使原油黏度下降,流动性变好,与基体接触和吸附的概率增加,对X65钢的缓蚀作用增强,也会使腐蚀速率下降。
Abstract
The corrosion behavior of X65 steel in the CO2/oil/water environment in gathering pipeline was investigated by mass loss method, SEM and XRD. The results show that the corrosion rate of the X65 steel increased at first and then decreased with the increase of flow rate and CO2 pressure, and critical velocity and critical pressure existed, below the critical value, the corrosion products formed on the steel surface were loose, porous and unstable, higher than the critical value, the product films were dense and had strong adhesion with a certain protective effect. When the flow rate increased to more than 1 m/s, the oil film adsorbed on the sample surface more evenly, the active points of corrosion reaction were reduced and the substrate was protected from being corroded, thus the corrosion rate decreased. With the increase of CO2 partial pressure, the solubility of CO2 in crude oil increased, the viscosity of crude oil decreased, the mobility of the crude oil became better and the probability of oil film adsorption increased, these factors led to the reinforcement of corrosion inhibition to X65 steel, and the corrosion rate decreased.
中图分类号 TG172.9 DOI 10.11973/fsyfh-201707006
所属栏目 试验研究
基金项目 国家自然科学基金项目(51301201)
收稿日期 2016/10/12
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联系人作者李自力(cygcx@163.com)
引用该论文: CHENG Yuanpeng,LI Zili,BAI Yu,LIU Jianguo. Corrosion Behavior of X65 Steel in Simulated Gathering Pipeline Environment[J]. Corrosion & Protection, 2017, 38(7): 510
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参考文献
【1】KERMANI M B,MORSHED A. Carbon dioxide corrosion in oil and gas production:a compendium[J]. Corrosion,2003,59(8):659-683.
【2】张学元,邸超,雷良才. 二氧化碳腐蚀与控制[M]. 北京:化学工业出版社,2000:15-27.
【3】ABD EL-LATEEF H M,ABBASOV V M,ALIYEVA LI,et al. Corrosion protection of steel pipelines against CO2 corrosion-a review[J]. Chemistry Journal,2012,2(2):52-63.
【4】NESIC S. Effects of multiphase flow on internal CO2 corrosion of mild steel pipelines[J]. Energy Fuels,2012,26:4098-4111.
【5】姬鄂豫,李爱魁,张银华,等. 原油对碳钢腐蚀行为影响的研究[J]. 材料保护,2004,37(5):42-44.
【6】孙冲,孙建波,王勇,等. 超临界CO2/油/水系统中油气管材钢的腐蚀机制[J]. 金属学报,2014,50(7):811-820.
【7】张忠烨,郭金宝. CO2对油气管材的腐蚀规律及国内外研究进展[J]. 宝钢技术,2000(4):54-58.
【8】JEPSON W P,MENAZES R. The effects of oil viscosity on sweet corrosion in multiphase oil/water/gas horizontal pipelines[J]. Corrosion,1995(3):106-112.
【9】ZHAO G X,LU X H,HAN Y. Effect of flow rate on CO2 corrosion behavior of P110 steel[J]. Journal of Materials Engineering,2008(8):5-8.
【10】YARO A S,ABDUL-KHALIK K R,KHADOM A A. Effect of CO2 corrosion behavior of mild steel in oilfield produced water[J]. Journal of Loss Prevention in the Process Industries,2015,38:24-38.
【11】ZAFAR M N,RIHAN R,Al-HADHRAMI L. Evaluation of the corrosion resistance of SA-543 and X65 steels in emulsions containing H2S and CO2 using a novel emulsion flow loop[J]. Corrosion Science,2015(94):275-287.
【12】RIHAN R,ZAFAR M N,Al-HADHRAMI L. A novel emulsion flow loop for investigating the corrosion of X65 steel in Emulsions with H2S/CO2[J]. Journal of Materials Engineering and Performance,2016,25:3065-3073.
【13】ZAFAR M N,RIHAN R,Al-HADHRAMI L. Effect of H2S and CO2 in oil/water emulsions on the corrosion resistance of SA-543 steel[J]. Journal of Materials Engineering and Performance,2015,24:683-693.
【14】魏爱军,霍富永,王茜,等. CO2驱油地面集输管道的腐蚀电化学行为[J]. 腐蚀与防护,2009,30(6):383.
【15】ZHU S D,FU A Q,MIAO J,et al. Corrosion of N80 carbon steel in oil field formation water containing CO2 in the absence and presence of acetic acid[J]. Corrosion Science,2011,53:3156-3165.
【16】QIU Z C,XIONG C M,CHANG Z L,et al. Major corrosion factors in the CO2 and H2S coexistent environment and the relative anti-corrosion method:Taking Tazhong I gas field,Tarim Basin,as an example[J]. Petroleum Exploration and Development,2012,39(2):256-260.
【2】张学元,邸超,雷良才. 二氧化碳腐蚀与控制[M]. 北京:化学工业出版社,2000:15-27.
【3】ABD EL-LATEEF H M,ABBASOV V M,ALIYEVA LI,et al. Corrosion protection of steel pipelines against CO2 corrosion-a review[J]. Chemistry Journal,2012,2(2):52-63.
【4】NESIC S. Effects of multiphase flow on internal CO2 corrosion of mild steel pipelines[J]. Energy Fuels,2012,26:4098-4111.
【5】姬鄂豫,李爱魁,张银华,等. 原油对碳钢腐蚀行为影响的研究[J]. 材料保护,2004,37(5):42-44.
【6】孙冲,孙建波,王勇,等. 超临界CO2/油/水系统中油气管材钢的腐蚀机制[J]. 金属学报,2014,50(7):811-820.
【7】张忠烨,郭金宝. CO2对油气管材的腐蚀规律及国内外研究进展[J]. 宝钢技术,2000(4):54-58.
【8】JEPSON W P,MENAZES R. The effects of oil viscosity on sweet corrosion in multiphase oil/water/gas horizontal pipelines[J]. Corrosion,1995(3):106-112.
【9】ZHAO G X,LU X H,HAN Y. Effect of flow rate on CO2 corrosion behavior of P110 steel[J]. Journal of Materials Engineering,2008(8):5-8.
【10】YARO A S,ABDUL-KHALIK K R,KHADOM A A. Effect of CO2 corrosion behavior of mild steel in oilfield produced water[J]. Journal of Loss Prevention in the Process Industries,2015,38:24-38.
【11】ZAFAR M N,RIHAN R,Al-HADHRAMI L. Evaluation of the corrosion resistance of SA-543 and X65 steels in emulsions containing H2S and CO2 using a novel emulsion flow loop[J]. Corrosion Science,2015(94):275-287.
【12】RIHAN R,ZAFAR M N,Al-HADHRAMI L. A novel emulsion flow loop for investigating the corrosion of X65 steel in Emulsions with H2S/CO2[J]. Journal of Materials Engineering and Performance,2016,25:3065-3073.
【13】ZAFAR M N,RIHAN R,Al-HADHRAMI L. Effect of H2S and CO2 in oil/water emulsions on the corrosion resistance of SA-543 steel[J]. Journal of Materials Engineering and Performance,2015,24:683-693.
【14】魏爱军,霍富永,王茜,等. CO2驱油地面集输管道的腐蚀电化学行为[J]. 腐蚀与防护,2009,30(6):383.
【15】ZHU S D,FU A Q,MIAO J,et al. Corrosion of N80 carbon steel in oil field formation water containing CO2 in the absence and presence of acetic acid[J]. Corrosion Science,2011,53:3156-3165.
【16】QIU Z C,XIONG C M,CHANG Z L,et al. Major corrosion factors in the CO2 and H2S coexistent environment and the relative anti-corrosion method:Taking Tazhong I gas field,Tarim Basin,as an example[J]. Petroleum Exploration and Development,2012,39(2):256-260.
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