热镀锌层无铬复合钝化处理研究的进展
Advancement in Chromium-free Composite Conversion Coating on Hot-dip Zinc Coating
摘 要
为了科学地引导热镀锌层无铬复合钝化技术的快速发展，综述了国内外无铬复合钝化处理的发展历程和研究现状，阐述了复合钝化膜防护的特点，分析了钝化膜耐蚀性的影响因素并评价了其研究方法。
钝化膜
耐蚀性
交流阻抗
自修复
hot-dip galvanizing
conversion coating
corrosion resistance
AC impedance
self-healing
Abstract
To guide the development of composite chromium-free conversion coating technology in hot-dip galvanzing, the development path and research status of the domestic and foreign composite chromium-free conversion coating on hot-dip zinc coating are summaried, the protective characteristics of composite chromium-free conversion coating are described, the affecting factors of corrosion resistance are analysed, and the research methods are evaluated.
中图分类号 TG174 DOI 10.11973/fsyfh-201711003
所属栏目 专论
基金项目 北京市科技计划课题（D151100003515001）
收稿日期 2016/4/22
修改稿日期
网络出版日期
作者单位点击查看
引用该论文: GAO Zhiqiang,JIANG Sheming,ZHANG Qifu,LI Xiaogang. Advancement in Chromium-free Composite Conversion Coating on Hot-dip Zinc Coating[J]. Corrosion & Protection, 2017, 38(11): 834
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参考文献
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【2】朱久发. 新日铁家电板表面处理技术[J]. 武钢技术,2008,46(2):43-45,58.
【3】张启富,刘邦津,黄建中. 现代钢带连续热镀锌[M]. 北京:冶金工业出版社,2007.
【4】朱文英. 日本开发无铬表面处理钢板的进展[J]. 上海金属,2005,27(4):50-53,60.
【5】郭太雄,马建权. 薄有机涂层钢板的应用与开发[J]. 轧钢,2008,25(4):30-34.
【6】周渝生. 无铬钝化技术研究的进展[J]. 钢铁,2003,38(4):68-71.
【7】廖建. NKK开发出涂敷有机树脂薄膜的表面处理钢板[J]. 上海钢研,2003(2):54-55.
【8】MASAAKI Y,TAKAFUMI Y,AKIRA M,et al. NKK galvalume steel sheet:genius coat[J]. NKK Technical Review,2000,83:37-41.
【9】UNKNOWN A. Advanced coated steel sheets with excellent functions to satisfy ecological requirements[J]. NKK Technical Review,2003,88:58-72.
【10】YOSHIHARU B,ATSUO C,MASANORI,et al. Chemical conversion treatment solution and chemically converted steel sheet:WO2015/072154 A1[P]. 2015-05-21.
【11】马建权,田冰,程兴德. 镀锌钢板有机无铬钝化技术研究的进展[J]. 轧钢,2007,24(1):36-38.
【12】蔡千华. 家电用无铬化学覆膜处理钢板的现状和动向[J]. 国外金属热处理,2004,25(4):8-11,16.
【13】黄建中. 中国汽车腐蚀与其防护对策[J]. 汽车工艺与材料,1995(4):4-6.
【14】潘肇. 有机涂层湿附着力的研究[J]. 材料保护,1994,27(2):9-12,47.
【15】张万益,刘抗利. 用辊涂机生产薄膜彩涂钢板[J]. 钢铁研究,1990(4):110-111,29.
【16】ICHIRO T,TAKAO I. Apparatus for controlling tickness of coated film on web-like member by roll coater:5435848[P]. 1995-07-25.
【17】LUO J L,LIN C J,YANG Q,et al. Cathodic disbonding of a thick polyurethane coating from steel in sodium chloride solution[J]. Progress in Organic Coatings,1997,31(4):289-295.
【18】胡吉明,张鉴清,谢德明,等. 水在有机涂层中的传输Ⅰ Fick扩散过程[J]. 中国腐蚀与防护学报,2002,22(5):311-315.
【19】胡吉明,张鉴清,谢德明,等. 水在有机涂层中的传输——Ⅱ复杂的实际传输过程[J]. 中国腐蚀与防护学报,2002,22(6):371-374.
【20】DE R L,MONETTA T,BELLUCCI F. Moisture uptake in organic coatings monitored with EIS[J]. Materials Science Forum,1998,289:315-326.
【21】黎完模,宋玉苏,邓淑珍. 涂装金属的腐蚀[M]. 长沙:国防科技大学出版社,2003.
【22】MIRABEDINI S M,THOMPSON G E,MORADIAN S,et al. Corrosion performance of powder coated aluminium using EIS[J]. Progress in Organic Coatings,2003,46(2):112-120.
【23】王燕华,张涛,王佳,等. Kelvin探头参比电极技术在大气腐蚀研究中的应用[J]. 中国腐蚀与防护学报,2004,24(1):59-64.
【24】赵增元,王佳. 有机涂层阴极剥离作用研究进展[J]. 中国腐蚀与防护学报,2008,28(2):116-120.
【25】LENG A,STRECKEL H,STRATMANN M. The delamination of polymeric coatings from steel. Part 1:calibration of the Kelvinprobe and basic delamination mechanism[J]. Corrosion Science,1998,41(3):547-578.
【26】FVRBETH W,STRATMANN M. The delamination of polymeric coatings from electrogalvanized steel-a mechanistic approach[J]. Corrosion Science,2001,43(2):243-254.
【27】DEFLORIAN F,FEDRIZZI L. Adhesion characterization of protective organic coatings by electrochemical impedance spectroscopy[J]. Journal of Adhesion Science and Technology,1999,13(5):629-645.
【28】HIRAYAMA R,HARUYAMA S. Electrochemical impedance for degraded coated steel having pores[J]. Corrosion,1991,47(12):952-958.
【29】MANSFELD F,TSAI C H. Determination of coating deterioration with EIS:I. basic relationships[J]. Corrosion,1991,47(12):958-963.
【30】JORCIN J B,ARAGON E,MERLATTI C,et al. Delaminated areas beneath organic coating:a local electrochemical impedance approach[J]. Corrosion Science,2006,48(7):1779-1790.
【31】梁永煌,满瑞林,吴文彪,等. 镀锌钢板表面有机/无机协同钝化研究进展[J]. 涂料工业,2009,39(6):48-50,55.
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