Causes Analysis on Micro-Cracks of 6Cr13 Stainless Steel Plate of Cutlery Material after Cold Rolling
摘 要
某6Cr13马氏体不锈钢板经过三道冷轧工序后静置一周出现密集分布的微裂纹,通过对钢板的化学成分、显微组织、表面形貌、硬度、微区成分等进行分析,确定了微裂纹产生的原因。结果表明:由于原材料钢板局部碳化物中的铬含量过高,导致周边出现贫铬区域,从而降低了材料的耐腐蚀性能,当接触到氯离子时,贫铬区出现孔腐蚀;随着腐蚀的发展,孔内氯化物浓缩、水解等使得孔内介质pH下降成为酸性溶液,氢离子通过电化学反应获得电子后成为氢原子并在局部富集产生氢压;在氢压与轧制残余应力的共同作用下钢板沿着轧制方向产生氢致裂纹。最后根据微裂纹产生原因提出了延长退火时间、改善成分等建议。
Abstract
After three times of cold-rolling process and standing for a week, densely distributed micro-cracks appeared in the 6Cr13 martensitic stainless steel plate. The crack forming causes were determined by analyzing the chemical composition, microstructure, surface morphology, hardness and micro-zone compositions of the steel plate. The results show that due to the high chromium content in the local carbides of the raw material, the phenomenon of poor chromium appeared in the carbides periphery, which reduced the corrosion resistance of the material. When the steel plate was exposed to chloride ions, pitting corrosion of the chromium deficient area occurred. With the development of the corrosion, the pH of the pit medium reduced to acidic because of the concentration and hydrolysis of chlorides in the pits. Hydrogen ions obtained electrons and became hydrogen atoms by electrochemical reaction, and then the hydrogen atoms enriched at the local position and produced hydrogen pressure. Under the combined action of hydrogen and rolling residual stress, hydrogen-induced cracking occurred along the rolling direction. Finally, according to the formation causes of micro-cracks of the steel plate, suggestions such as lengthening annealing time and improving compositions were proposed.
中图分类号 TG178 DOI 10.11973/lhjy-wl201712013
所属栏目 质量控制与失效分析
基金项目
收稿日期 2016/11/21
修改稿日期
网络出版日期
作者单位点击查看
联系人作者曹艳彬(40199067@qq.com)
备注申利凤(1980-),女,讲师,硕士,主要从事模具设计、夹具设计及材料热处理研究
引用该论文: SHEN Lifeng,CAO Yanbin. Causes Analysis on Micro-Cracks of 6Cr13 Stainless Steel Plate of Cutlery Material after Cold Rolling[J]. Physical Testing and Chemical Analysis part A:Physical Testing, 2017, 53(12): 904~908
申利凤,曹艳彬. 刀剪材料6Cr13不锈钢板冷轧后出现微裂纹的原因分析[J]. 理化检验-物理分册, 2017, 53(12): 904~908
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【3】姚迪,李晶,李积回. 7Cr17MoV不锈钢刀剪材料塑性变形的组织与性能[J]. 金属热处理,2014,38(2):42-45.
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【5】赵步青,龚真忠,纪正祥,等. 碳化物对高速钢刀具寿命的影响[J]. 热处理技术与装备,2011,32(3):60-64.
【6】GARCI'A DE ANDRÉS C,CARUANA G,ALVAREZ L F. Control of M23C6 carbides in 0.45C-13Cr martensitic stainless steel by means of three representative heat treatment parameters[J].Materials Science and Engineering:A,1998,241(1):211-215.
【7】何燕霖,朱娜琼,吴晓瑜,等. 富Cr碳化物析出行为的热力学与动力学计算[J]. 材料热处理学报,2011,32(1):134-137.
【8】张根元,吴晴飞,覃瑞森,等. 贫铬区演化对奥氏体不锈钢晶间腐蚀影响[J]. 材料热处理学报,2013,34(z2):148-153.
【9】YU X,CHEN S. A simulation of Cr depletion in austenitic stainless steel with cellular automaton[J]. Computational Materials Science,2009,45(4):899-904.
【10】梁成浩,高敏. 化对不锈钢孔蚀性能的影响[J]. 腐蚀科学与防护技术,1996,8(4):25-29.
【11】镇凡,刘静,黄峰,等. 夹杂物对X120管线钢氢致开裂的影响[J]. 中国腐蚀与防护学报,2010,30(2):145-149,154.
【12】丁二喜,吴继权,张居光,等. WP304WX管道泄漏原因分析[J]. 理化检验-物理分册,2013,49(1):68-70.
【13】张彦文,吴立新,王志奋,等. 储气球罐连接阀螺栓断裂分析[J]. 理化检验-物理分册,2013,49(9):628-631.
【14】肖纪美. 不锈钢的金属学问题[M]. 北京:冶金工业出版社,2006.
【15】KIM J K,KIM Y H,UHM S H,et al. Intergranular corrosion of Ti-stabilized 11wt% Cr ferritic stainless steel for automotive exhaust systems[J]. Corrosion Science,2009,51(11):2716-2723.
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【17】徐文亮,唐豪清,孙元宁. 合金元素对2Cr13马氏体不锈钢组织及性能的影响[J]. 宝钢技术,2008(5):39-43.
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