搜索热:失效分析 陶瓷
扫一扫 加微信
首页 > 期刊论文 > 论文摘要
硅酸钠添加量对多孔硅藻土陶瓷性能的影响
          
Effect of Sodium Silicate Addition Amount on Properties of Porous Diatomite Ceramics

摘    要
以工业硅藻土细粉为原料,以硅酸钠为烧结助剂,采用发泡注凝法在1 000℃保温2 h制备多孔硅藻土陶瓷,研究了硅酸钠添加量(0~5%,质量分数)对陶瓷物相组成、显微结构、气孔孔径和耐压强度的影响。结果表明:随硅酸钠添加量的增加,多孔硅藻土陶瓷中的方石英含量减少,鳞石英含量增加,烧结致密程度增大,气孔孔径呈现减小的趋势,耐压强度增大;当硅酸钠的质量分数为3%时制备得到具有多级孔结构的硅藻土陶瓷,该陶瓷的耐压强度为(1.13±0.08)MPa,比未添加硅酸钠的提高了约113%,其200℃时的热导率仅为(0.098±0.002)W·m-1·K-1
标    签 硅酸钠   硅藻土   多级孔陶瓷   耐压强度   sodium silicate   diatomite   hierarchically pore-structured ceramics   compressive strength  
 
Abstract
Porous diatomite ceramics were prepared by foam-gelcasting method after holding at 1 000℃ for 2 h with industrial diatomite fine powder as raw material and sodium silicate as sintering aid. The addition amount (0-5wt%) of sodium silicate on the phase composition, microstructure, pore size and compressive strength of the ceramics were investigated. The results show that with increasing addition amount of sodium silicate, the cristobalite content decreased while the tridymite content increased in the porous diatomite ceramics, the sintering densification increased, the pore size showed a decreasing trend, and the compressive strength was improved. When the addition amount of sodium silicate was 3wt%, the diatomite ceramics with a hierarchically pore-structure were obtained; the compressive strength was (1.13±0.08) MPa, which increased by about 113% comparing with that without sodium silicate, and the thermal conductivity at 200℃ was (0.098±0.002) W·m-1·K-1.

中图分类号 TQ174.7   DOI 10.11973/jxgccl201804016

 
  中国光学期刊网论文下载说明


所属栏目 材料性能及应用

基金项目 国家自然科学基金面上项目(51672194);湖北省教育厅高等学校优秀中青年科技创新团队计划项目(T201602);湖北省自然科学基金创新群体项目(2017CFA004)

收稿日期 2017/8/2

修改稿日期 2018/3/12

网络出版日期

作者单位点击查看

备注韩磊(1987-),男,河南驻马店人,博士研究生

引用该论文: HAN Lei,WANG Junkai,DENG Xiangong,GE Shengtao,ZHANG Haijun. Effect of Sodium Silicate Addition Amount on Properties of Porous Diatomite Ceramics[J]. Materials for mechancial engineering, 2018, 42(4): 73~77
韩磊,王军凯,邓先功,葛胜涛,张海军. 硅酸钠添加量对多孔硅藻土陶瓷性能的影响[J]. 机械工程材料, 2018, 42(4): 73~77


论文评价
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
分享论文
分享到新浪微博 分享到腾讯微博 分享到人人网 分享到 Google Reader 分享到百度搜藏分享到Twitter

参考文献
【1】DA J, DU Y H, LI M D, et al. The preparation and performance study of thermal insulating materials with diatomite[J]. Advanced Materials Research, 2014, 941/942/943/944:1562-1565.
 
【2】郑水林, 高如琴, 王健东,等. TiO2/硅藻土基多孔陶瓷复合材料的制备及降解甲醛性能[J]. 硅酸盐学报, 2008, 36(11):1633-1637.
 
【3】LIN K L, LAN J Y, LUO K W, et al. Effects of sintering temperature on water retention characteristics of sewage sludge ash-diatomite based porous ceramics[C]//4th International Conference on Future Environment and Energy. Singapore:LACSIT Press, 2014.
 
【4】HAN M, YIN X, KONG L, et al. Graphene-wrapped ZnO hollow spheres with enhanced electromagnetic wave absorption properties[J]. Journal of Materials Chemistry A, 2014, 2(39):16403-16409.
 
【5】DENG X G, WANG J K, ZHANG H J, et al. Effects of firing temperature on the microstructures and properties of porous mullite ceramics prepared by foam-gelcasting[J]. Advances in Applied Ceramics, 2016, 115(4):204-209.
 
【6】DENG X G, WANG J K, LIU J H, et al. Low cost foam-gelcasting preparation and characterization of porous magnesium aluminate spinel (MgAl2O4) ceramics[J]. Ceramics International, 2016, 42(16):18215-18222.
 
【7】HAN Y, LI C, BIAN C, et al. Porous anorthite ceramics with ultra-low thermal conductivity[J]. Journal of the European Ceramic Society, 2013, 33(13/14):2573-2578.
 
【8】DENG X G, WANG J K, LIU J H, et al. Preparation and characterization of porous mullite ceramics via foam-gelcasting[J]. Ceramics International, 2015, 41(7):9009-9017.
 
【9】FANG B, KIM J H, KIM M S, et al. Hierarchical nanostructured carbons with meso-macroporosity:Design, characterization, and applications[J]. Accounts of Chemical Research, 2013, 46(7):1397-1406.
 
【10】MILLE C, CORKERY R W. A structural and thermal conductivity study of highly porous, hierarchical polyhedral nanofoam shells made by condensing silica in microemulsion films on the surface of emulsified oil drops[J]. Journal of Materials Chemistry A, 2013, 1(5):1849-1859.
 
【11】KOCJAN A, SHEN Z. Colloidal processing and partial sintering of high-performance porous zirconia nanoceramics with hierarchical heterogeneities[J]. Journal of the European Ceramic Society, 2013, 33(15/16):3165-3176.
 
【12】XU B, LI Z. Paraffin/diatomite composite phase change material incorporated cement-based composite for thermal energy storage[J]. Applied Energy, 2013, 105(2):229-237.
 
【13】ROTTMAN J, PLATT L C, SIERRA-ALVAREZ R, et al. Removal of TiO2 nanoparticles by porous media:Effect of filtration media and water chemistry[J]. Chemical Engineering Journal, 2013, 217:212-220.
 
【14】LIN K L, LEE T C, CHANG J C, et al. Water absorption and retention of porous ceramics cosintered from waste diatomite and catalyst[J]. Environmental Progress & Sustainable Energy, 2013, 32(3):640-648.
 
【15】LIN K L, CHANG J C, SHIE J L, et al. Characteristics of porous ceramics produced from waste diatomite and water purification sludge[J]. Environmental Engineering Science, 2012, 29(6):436-446.
 
【16】LIU C Y, TUAN W H, CHEN S C. Preparation of porous SiC ceramics for thermal dissipation purposes[J]. Ceramics International, 2015, 41(3):4564-4568.
 
【17】LIU J, LI Y, LI Y, et al. Effects of pore structure on thermal conductivity and strength of alumina porous ceramics using carbon black as pore-forming agent[J]. Ceramics International, 2016, 42(7):8221-8228.
 
【18】李景华. 焦炉炭化室热补料的制备与性能研究[D]. 济南:济南大学, 2016.
 
【19】LI C, BIAN C, HAN Y, et al. Mullite whisker reinforced porous anorthite ceramics with low thermal conductivity and high strength[J]. Journal of the European Ceramic Society, 2016, 36(3):761-765.
 
相关信息
   标题 相关频次
 SiC含量对ZrB2-SiC/MgO-C低碳复合耐火材料性能的影响
 8
 ZrB2-SiC复合粉体添加量对低碳镁碳耐火材料性能的影响
 6
 Cr2O3催化氮化制备Si3N4/SiC耐火材料及其性能
 4
 催化热解三聚氰胺合成竹节状氮掺杂碳纳米管
 4
 微波熔盐辅助硼热/碳热还原法制备ZrB2-SiC复合粉
 4
 通过硝酸镍催化热解酚醛树脂制备碳纳米管
 3
 12 Mt/a常减压装置的典型腐蚀及防护
 2
 常减压装置塔顶低温腐蚀评估中的相关计算
 2
 储罐外底板阴极保护用锌参比电极可行性探讨
 2
 单组份硅酸钠耐酸胶泥的研究
 2
 电化学噪声数据处理方法概述
 2
 基于SPH方法的电场下液滴动力学数值模拟
 2
 几种钢材在NH4Cl环境中的腐蚀行为
 2
 炼油生产中有机氯的检测与控制
 2
 熔盐氮化法制备六方氮化硼纳米片
 2
 熔盐法制备石墨化碳纳米片
 2
 以聚(3-己基噻吩)-石墨烯-Nafion修饰的玻碳电极为工作电极示差脉冲伏安法测定细颗粒物PM2.5中铅的含量
 2
 增压消解-电感耦合等离子体质谱法测定硅藻土中26种微量元素
 2
 Ca-α/β-Sialon结合刚玉复合材料的力学性能
 1
 不同孔隙率碳纤维增强环氧树脂复合材料板的压缩强度及其预测模型
 1
 不同温度下多层结构TiCN/TiC/TiN镀层的摩擦学行为
 1
 采用双层辉光等离子技术在420不锈钢表面制备ZrO2改性层
 1
 低密度碳/碳复合材料的制备与性能
 1
 端面处理对钻芯法检测混凝土强度的影响
 1
 分层缺陷深度对复合材料层合板力学性能的影响
 1
 钢蜂窝夹芯板面内压缩性能
 1
 钢蜂窝夹芯结构的准静态压缩吸能特性
 1
 铬颗粒尺寸对镍-铬复合镀层900℃抗空气氧化和耐Na2SO4熔盐腐蚀性能的影响
 1
 灌浆节点灌浆料强度的现场检测
 1
 灌浆料抗压强度的表面硬度法检测
 1