Composition Optimization and High Temperature Sagging Resistance of Aluminum Alloy Core Material in Composite Aluminum Foil
摘 要
以3003M铝合金的化学成分为基础,通过正交试验研究了锰、硅、锌、铜,以及富铈混合稀土含量对铝合金室温力学性能和高温抗下垂性能的影响,优化了复合铝箔芯材铝合金的化学成分,并分析了铝合金在钎焊过程中的抗下垂机制。结果表明:铜元素对试验铝合金抗拉强度的影响最大,硅、锰、铜元素对高温抗下垂性能的影响较显著;性能最优铝合金中铜、锌、硅、锰,以及富铈混合稀土的质量分数分别为0.5%,2.5%,0.8%,1.2%,0,最优铝合金的抗拉强度比3003M铝合金的高约40 MPa,伸长率高约2个百分点,下垂距离缩短一半;在610℃钎焊过程中,优化铝合金出现二次再结晶现象,组织由弥散分布的析出相、一次再结晶晶粒和尺寸约1 mm的粗大长条晶粒组成。
Abstract
The effects of content of Mn, Si, Zn, Cu and Ce-rich mixed rare earth on the room-temperature mechanical properties and high temperature sagging resistance of the aluminum alloy on the basis of chemical composition of 3003M aluminum alloy were studied by orthogonal test. The chemical composition of aluminum alloy core material for composite aluminum foil was optimized and the sagging resistance mechanism of the aluminum alloy during brazing was analyzed. The results show that Cu element had the greatest effect on the tensile strength of the tested aluminum alloy, while Si, Mn and Cu elements had significant effects on the sagging resistance. The mass fractions of Mn, Si, Zn, Cu and Ce-rich mixed rare earth of the aluminum alloy with the best properties were 0.5%, 2.5%, 0.8%, 1.2%, 0, respectively. The tensile strength of the optimal aluminum alloy was about 40 MPa higher than that of 3003M aluminum alloy, the elongation increased by about 2 percentage points, and sagging distance was shortened by half. During brazing at 610℃, the secondary recrystallization occurred in the optimal aluminum alloy, and the microstructure was composed of dispersed precipitated phase, primary recrystallization grains and coarse long grains with size of about 1 mm.
中图分类号 TG1 DOI 10.11973/jxgccl201808003
所属栏目 试验研究
基金项目 钢铁联合基金资助项目(U1360104)
收稿日期 2017/4/28
修改稿日期 2018/6/4
网络出版日期
作者单位点击查看
备注高旭东(1991-),男,河北石家庄人,硕士研究生
引用该论文: GAO Xudong,ZHAO Yuanyuan,JIN Li,WANG Fenghua,DONG Jie. Composition Optimization and High Temperature Sagging Resistance of Aluminum Alloy Core Material in Composite Aluminum Foil[J]. Materials for mechancial engineering, 2018, 42(8): 11~17
高旭东,赵媛媛,靳丽,王锋华,董杰. 复合铝箔中铝合金芯材的成分优化及高温抗下垂性能[J]. 机械工程材料, 2018, 42(8): 11~17
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参考文献
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【3】陈一龙. 汽车轻量化技术发展状况及展望[J]. 汽车工艺与材料, 2012(1):1-4.
【4】孙兴隆, 凌亚标. 复合钎焊铝箔抗下垂性能的研究进展[J]. 轻合金加工技术, 2015, 43(2):8-15.
【5】TANGEN S, SJΦLSTAD K, FURU T, et al. Effect of concurrent precipitation on recrystallization and evolution of the P-texture component in a commercial Al-Mn alloy[J]. Metallurgical and Materials Transactions A, 2010, 41(11):2970-2983.
【6】康绍海,丁冬雁,张俊超,等.锌元素对钎焊态3003铝合金显微组织与性能的影响[J].有色金属材料与工程,2012,33(1):1-6.
【7】徐进, 毛卫民, 冯惠平,等. Cu对高压电解电容器阳极铝箔再结晶织构的影响[J]. 工程科学学报, 2002, 24(2):133-136.
【8】李浩. Cu、RE对Al-Cu-Mn铸造铝合金微观组织及力学性能的影响[D]. 郑州:郑州大学, 2014.
【9】陈仁宗, 黄元伟, 唐定骧,等. 不同含量的稀土和钛对3003铝合金热传输材料性能影响[C]//中国长三角铝业高峰论坛暨上海铝业行业协会年会. 上海:上海铝业行业协会,2013.
【10】YOON J S, LEE S H, KIM M S. Fabrication and brazeability of a three-layer 4343/3003/4343 aluminum clad sheet by rolling[J]. Journal of Materials Processing Technology, 2001, 111(1):85-89.
【11】RYU J S, KIM M S, JUNG D. Brazeability of cold rolled three layer Al-7.5Si/Al-1.2Mn-2Zn-(0.04-1.0)Si/Al-7.5Si (wt.%) clad sheets[J]. Journal of Materials Processing Technology, 2002, 130(4):240-244.
【12】LEE S H, YOON J S, KIM M S, et al. Effects of cold rolling parameters on sagging behavior for three layer Al-Si/Al-Mn(Zn)/Al-Si brazing sheets[J]. Metals and Materials International, 2002, 8(3):227-232.
【13】QIN J, KANG S B, CHO J H. Sagging mechanisms in the brazing of aluminum heat exchangers[J]. Scripta Materialia, 2013, 68(12):941-944.
【14】KANG S B, KIM D B, JUNG S S, et al. Thermomechanical treatment of aluminum alloy fin stock for heat exchanger produced by twin roll strip casting process[C]//Materials Science Forum.[S.l.]:[s.n.],2010:241-246.
【15】TU Y, QIAN H, ZHOU X, et al. Effect of scandium on the interaction of concurrent precipitation and recrystallization in commercial AA3003 aluminum alloy[J]. Metallurgical and Materials Transactions A, 2014, 45(4):1883-1891.
【16】SHIN J, KIM K, KO S. Effects of Ti addition into core alloy on forming and brazing characteristics of 4343/3003/4343 aluminum alloy clad sheets[J]. Materials Transactions, 2013, 54(11):2131-2138.
【17】ZHAO Y Y, ZHANG Z Y, JIN L, et al. Effects of annealing process on sagging resistance of cold-rolled three-layer Al alloy clad sheets[J]. Transactions of Nonferrous Metals Society of China, 2016, 26(10):2542-2551.
【18】左秀荣, 李立祥, 孙海斌, 等. 稀土对铝合金微观组织的影响[J]. 铸造技术, 2007, 28(11):1473-1476.
【19】吴文祥, 张新明, 唐建国,等. 3003铝合金箔制备过程中的组织演变[J]. 金属热处理, 2006, 31(3):36-39.
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