Effects of Environmental Factors on Pitting Behaviors of Two Stainless Steels in Simulated Seawater
摘 要
采用动电位极化、恒电位下临界点蚀温度(CPT)测量和腐蚀形貌观察方法对比研究了环境因素对Z2CND18-12N奥氏体不锈钢和S32760双相不锈钢在模拟海水环境中的点蚀行为。结果表明:每种材料在30℃人造海水和3.5% NaCl溶液中的极化行为相似,S32760的点蚀电位Eb均在+1 100 mV(相对于饱和甘汞电极SCE,下同)左右;Z2CND18-12N在两种溶液中均表现为较大的亚稳态波动后点蚀击穿,Eb在+500 mV附近。S32760表现出优秀的点蚀抗力,但在60℃时出现较明显的亚稳态波动;Z2CND18-12N在低温3℃下表现出与S32760接近的点蚀抗力,但是温度升高至30℃和60℃时,点蚀抗力显著下降,出现明显的点蚀坑,点蚀抗力不及S32760的。S32760在3.5% NaCl和10% NaCl中的CPT分别为86℃和79℃,Z2CND18-12N的则为23℃和20℃。
Abstract
The effects of environmental factors on the pitting behaviors of Z2CND18-12N austenitic stainless steel and S32760 duplex stainless steel in simulated seawater environment were investigated by means of potentiodynamic polarization, critical pitting temperature (CPT) measurement and corrosion morphology observation. The results showed that the polarization behaviors of each materials in artificial seawater and 3.5% NaCl solution at 30℃ were similar. The pitting potential Eb of S32760 was about + 1 100 mV (relative to saturated calomel electrode SCE, the same below). Z2CND18-12N in the two solutions showed apparent metastable fluctuation before the pitting breakdown, with Eb around +500 mV. S32760 showed excellent pitting resistance, but apparent metastable fluctuation occurred at 60℃. Pitting resistance of Z2CND18-12N was close to that of S32760 at low temperature of 3℃, but decreased significantly when the temperature increased to 30℃ and 60℃. The pitting corrosion resistance of Z2CND18-12N was weaker than that of S32760 duplex stainless steel. CPT of S32760 in the 3.5% NaCl and 10% NaCl were 86℃ and 79℃, with the corresponding values of 23℃ and 20℃ for Z2CND18-12N.
中图分类号 TG174 DOI 10.11973/fsyfh-201809003
所属栏目 试验研究
基金项目 上海市科委项目(15DZ1203300;15DZ2260302)
收稿日期 2017/5/10
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引用该论文: JIN Yuting,JI Kaiqiang,HU Jun,LI Run,LI Guangfu. Effects of Environmental Factors on Pitting Behaviors of Two Stainless Steels in Simulated Seawater[J]. Corrosion & Protection, 2018, 39(9): 663
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【3】邓博,蒋益民,龚佳,等. 双相不锈钢临界点蚀温度和再钝化温度[J]. 中国有色金属学报,2007(10):47-53
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