Microstructure and Properties of Al-Ti-TiB2 Laser-Cladding Layer on Surface of AZ31 Magnesium Alloy
摘 要
采用不同功率(2.5,3.0 kW)的高能激光将质量比为1.0:3.0:0.5的铝、钛和TiB2混合粉熔覆在AZ31镁合金表面,研究了该熔覆层的显微组织、物相组成、硬度和耐腐蚀性能。结果表明:在激光熔覆过程中,铝与钛反应生成了Al3Ti相,与镁在激光功率2.5 kW下反应生成Al0.56Mg0.44相,在激光功率3.0 kW下生成Al12Mg17相,TiB2仍保持原来的晶体结构;与激光功率2.5 kW下的相比,激光功率3.0 kW下熔覆层中的Al3Ti相更细小,且熔覆层与镁合金基体之间形成了共晶层,呈现出更好的冶金结合;激光功率对熔覆层的硬度影响较小,熔覆层硬度均随距表面距离的增大先增后降;激光熔覆可以有效提高镁合金基体的耐腐蚀性能,在激光功率3.0 kW下熔覆层的耐腐蚀性能优于激光功率2.5 kW下的。
Abstract
Mixed powders of aluminum, titanium, TiB2 with mass ratio of 1.0:3.0:0.5 were cladded on surface of AZ31 magnesium alloy by using a high energy laser with different powers (2.5, 3.0 kW). The microstructure, phase composition, hardness and corrosion resistance of the cladding layer were studied. The results show that during the laser cladding, the aluminum reacted with the titanium to form Al3Ti phase. Meanwhile, the aluminum reacted with the magnesium to form Al0.56Mg0.44 phase and Al12Mg17 phase at the laser powers of 2.5 kW and 3.0 kW, respectively. The TiB2 retained the original crystal structure. The cladding layer had a finer Al3Ti phase at the laser power of 3.0 kW than at the laser power of 2.5 kW, and showed a better metallurgical bonding by the formation of a eutectic structure layer between the cladding layer and the magnesium alloy substrate. The laser power had little influence on the hardness of the cladding layer; the hardness increased and then decreased with the distance to the surface increasing. The laser cladding can effectively improve the corrosion resistance of AZ31 magnesium alloy. The corrosion resistance of the cladding layer at the laser power of 3.0 kW was better than that at the laser power of 2.5 kW.
中图分类号 TG146 DOI 10.11973/jxgccl201810005
所属栏目 新材料 新工艺
基金项目 上海工程技术大学研究生创新项目(16KY0505)
收稿日期 2017/10/9
修改稿日期 2018/9/11
网络出版日期
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备注刘德坤(1996-),男,安徽淮北人,硕士研究生
引用该论文: LIU Dekun,ZHANG Kemin,LIU Yingrui. Microstructure and Properties of Al-Ti-TiB2 Laser-Cladding Layer on Surface of AZ31 Magnesium Alloy[J]. Materials for mechancial engineering, 2018, 42(10): 24~28
刘德坤,张可敏,刘应瑞. AZ31镁合金表面Al-Ti-TiB2激光熔覆层的组织和性能[J]. 机械工程材料, 2018, 42(10): 24~28
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参考文献
【1】曾荣昌, 柯伟, 徐永波, 等. Mg合金的最新发展及应用前景[J]. 金属学报, 2001, 37(7):673-685.
【2】曾小勤, 王渠东, 吕宜振, 等. 镁合金应用新进展[J]. 铸造, 1998(11):39-43.
【3】GRAY J E, LUAN B. Protective coatings on magnesium and its alloys:A critical review[J]. Journal of Alloys and Compounds, 2002, 336(1/2):88-113.
【4】PAITAL S R, BHATTACHARYA A, MONCAYO M, et al. Improved corrosion and wear resistance of Mg alloys via laser surface modification of Al on AZ31B[J]. Surface and Coatings Technology, 2012, 206(8):2308-2315.
【5】QIAN M, LI D, LIU S B, et al. Corrosion performance of laser-remelted Al-Si coating on magnesium alloy AZ91D[J]. Corrosion Science, 2010, 52(10):3554-3560.
【6】JUN Y, SUN G P, WANG H Y, et al. Laser (Nd:YAG) cladding of AZ91D magnesium alloys with Al+Si+Al2O3[J]. Journal of Alloys and Compounds, 2006, 407(1):201-207.
【7】惠林海, 耿浩然, 王守仁, 等. Al3Ti金属间化合物的研究进展[J]. 机械工程材料, 2007, 31(9):1-3.
【8】杨悦, 庄宇, 由晓军. AZ91D镁合金表面激光熔覆Al-Ti-C涂层的显微组织和性能[J]. 吉林大学学报(工学版), 2010, 40(6):1567-1571.
【9】王继娜, 徐开东. 镁合金表面激光熔覆Al/TiB2复合强化层及其性能[J]. 机械工程材料, 2013, 37(8):45-49.
【10】PENG L M, WANG J H, LI H, et al. Synthesis and microstructural characterization of Ti-Al3Ti metal-intermetallic laminate (MIL) composites[J]. Scripta Materialia, 2005, 52(3):243-248.
【11】WANG X, JHA A, BRYDSON R. In situ fabrication of Al3Ti particle reinforced aluminium alloy metal-matrix composites[J]. Materials Science and Engineering:A, 2004, 364(1/2):339-345.
【2】曾小勤, 王渠东, 吕宜振, 等. 镁合金应用新进展[J]. 铸造, 1998(11):39-43.
【3】GRAY J E, LUAN B. Protective coatings on magnesium and its alloys:A critical review[J]. Journal of Alloys and Compounds, 2002, 336(1/2):88-113.
【4】PAITAL S R, BHATTACHARYA A, MONCAYO M, et al. Improved corrosion and wear resistance of Mg alloys via laser surface modification of Al on AZ31B[J]. Surface and Coatings Technology, 2012, 206(8):2308-2315.
【5】QIAN M, LI D, LIU S B, et al. Corrosion performance of laser-remelted Al-Si coating on magnesium alloy AZ91D[J]. Corrosion Science, 2010, 52(10):3554-3560.
【6】JUN Y, SUN G P, WANG H Y, et al. Laser (Nd:YAG) cladding of AZ91D magnesium alloys with Al+Si+Al2O3[J]. Journal of Alloys and Compounds, 2006, 407(1):201-207.
【7】惠林海, 耿浩然, 王守仁, 等. Al3Ti金属间化合物的研究进展[J]. 机械工程材料, 2007, 31(9):1-3.
【8】杨悦, 庄宇, 由晓军. AZ91D镁合金表面激光熔覆Al-Ti-C涂层的显微组织和性能[J]. 吉林大学学报(工学版), 2010, 40(6):1567-1571.
【9】王继娜, 徐开东. 镁合金表面激光熔覆Al/TiB2复合强化层及其性能[J]. 机械工程材料, 2013, 37(8):45-49.
【10】PENG L M, WANG J H, LI H, et al. Synthesis and microstructural characterization of Ti-Al3Ti metal-intermetallic laminate (MIL) composites[J]. Scripta Materialia, 2005, 52(3):243-248.
【11】WANG X, JHA A, BRYDSON R. In situ fabrication of Al3Ti particle reinforced aluminium alloy metal-matrix composites[J]. Materials Science and Engineering:A, 2004, 364(1/2):339-345.
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