Microstructure Evolution of As-welded and Heat-treated Nuclear Grade 316L Stainless Steel Weld during Thermal Aging
摘 要
采用国产核级E316L焊条对20 mm厚奥氏体不锈钢板进行多层多道填充焊接,之后对焊缝进行610℃×16 h热处理和400℃下不同时间(400,2 000,3 500 h)的加速热老化处理,研究了在热老化过程中焊态和热处理态焊缝中铁素体及析出相的演变。结果表明:焊态和热处理态焊缝的组织均由奥氏体、铁素体和析出相组成;随着热老化时间的延长,焊缝中铁素体的数量呈先增多后减少的趋势,铁素体形貌由断续网状变为较连续网状,再变为断续网状;焊态焊缝中铁素体的含量高于热处理态的;在热老化过程中,焊缝中的析出相主要为Cr23C6相和σ相,热处理态焊缝比焊态的更容易形成析出相;随着热老化时间的延长,Cr23C6相和σ相优先在晶界处析出并聚集,随后铁素体晶内也有Cr23C6和σ相的析出和聚集。
Abstract
Multi-layer and multi-pass filling welding was carried out on austenitic stainless steel plates with thickness of 20 mm with domestic nuclear grade E316L electrode. Then the welds were heat treated at 610℃ for 16 h and accelerated thermal aged at 400℃ for different times (400,2 000,3 500 h), and the evolution of ferrite and precipitated phases in the as-welded and heat-treated weld during thermal aging was studied. The results show that the microstructure of as-welded weld and heat-treated weld both consisted of austenite, ferrite and precipitated phases. With the increase of thermal aging time, the amount of ferrite in the weld increased first and then decreased, and the morphology of ferrite changed from discontinuous mesh to relatively continuous mesh and then to discontinuous mesh. The content of ferrite in the as-welded weld was higher than that in the heat-treated weld. During thermal aging, the precipitated phases in the weld were mainly composed of Cr23C6 phase and σ phase, and the precipitated phases in heat-treated weld was formed more easily than those in the as-welded weld. With the prolongation of thermal aging time, Cr23C6 phase and σ phase preferentially precipitated and aggregated at the grain boundaries, and then in ferrite crystals.
中图分类号 TG142.71 DOI 10.11973/jxgccl201811002
所属栏目 试验研究
基金项目
收稿日期 2017/8/17
修改稿日期 2018/9/11
网络出版日期
作者单位点击查看
备注赵宏刚(1991-),男,陕西西安人,硕士研究生
引用该论文: ZHAO Honggang,NIU Ruifeng,ZHANG Junhua,YANG Lun,ZHU Ping,ZHANG Ruchan. Microstructure Evolution of As-welded and Heat-treated Nuclear Grade 316L Stainless Steel Weld during Thermal Aging[J]. Materials for mechancial engineering, 2018, 42(11): 6~10
赵宏刚,牛锐锋,张俊华,杨伦,朱平,张汝潺. 热老化过程中焊态和热处理态核级316L不锈钢焊缝的组织演变[J]. 机械工程材料, 2018, 42(11): 6~10
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参考文献
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【6】贺立华. 焊接快速成形316L不锈钢的组织和性能研究[D]. 南昌:南昌航空大学, 2015.
【7】庄育智,蒋宁寿. 18/8型不锈钢中δ-铁素体恒温分解初期的电子显微镜观察[J]. 金属学报,1957,2(3):301-304.
【8】丁秀平,刘雄,何燕霖,等.316L奥氏体不锈钢中时效条件下析出相演变行为的研究[J].材料研究学报,2009,23(3):269-274.
【9】SVOBODA M, KROUPA A, VŘU EŠUŤU ÁL J, et al. Phase changes in super austenitic steels after long-term annealing[J]. Zeitschrift Für Metallkunde, 2013, 95(11):1025-1030.
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【13】LAI H H, HSIEH C C, LIN C M, et al. Lattice relations and solidification of the complex regular eutectic (Cr,Fe)-(Cr,Fe)23C6[J]. Metals & Materials International, 2017, 23(3):1-5.
【14】刘鹏虎,张而耕,关凯书,等.Cr-Ni奥氏体不锈耐热钢中碳化物、σ相变热力学和转变动力学探讨[J].化工机械,2002, 29(2):82-84.
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