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0.1HoMnO3-0.9BiFeO3柔性铁电薄膜的制备及电学性能
          
Preparation and Electric Property of 0.1HoMnO3-0.9BiFeO3 Flexible Ferroelectric Thin Film

摘    要
采用脉冲激光沉积技术在云母柔性衬底上沉积0.1HoMnO3-0.9BiFeO3薄膜,研究了薄膜的晶体结构、表面形貌、弯曲服役特性、铁电和介电性能以及输运特性。结果表明:BiFeO3沿(012)和(104)晶面取向生长,结晶良好;薄膜表面光滑,均方根表面粗糙度为6.7 nm,连续弯曲平整10 000次后表面无细微裂纹;薄膜具有良好的微观压电性,且呈现出一定的向上自发极化特性;薄膜的饱和极化强度和剩余极化强度分别为68,61 μC·cm-2,弯曲至曲率半径为2.2 mm时的极化强度变化不大,连续弯曲平整10 000次后则有所降低,平整状态和弯曲状态下的介电性能相差较小;薄膜的激活能为0.42 eV,低于纯BiFeO3薄膜的,其载流子输运能力有所增强。
标    签 柔性薄膜   BiFeO3   HoMnO3   介电性能   压电性   铁电性   flexible thin film   BiFeO3   HoMnO3   dielectric property   piezoelectricity   ferroelectricity  
 
Abstract
Thin film of 0.1HoMnO3-0.9BiFeO3 was deposited on flexible mica substrate by pulsed laser deposition. The crystal structure, surface appearance, bending service characteristic, ferroelectric and dielectric properties and carriage property of the film were studied. The results show that BiFeO3 grew along the (012) and (104) crystal planes and had good crystallization. The film presented a smooth surface with root mean square surface roughness of 6.7 nm. After continuously bending and flatting for 10 000 times, the film surface showed no microcracks. The film illustrated a good micro piezoelectricity and a certain upward spontaneous polarization. The saturated and remanent polarization of the film were 68, 61 μC·cm-2, respectively. The polarization changed little after bending to curvature radius of 2.2 mm, whereas decreased slightly after continuously bending and flatting for 10 000 times; the dielectric properties in flatting and bending states had little difference. The activation energy of the film was 0.42 eV, which was lower than that of pure BiFeO3 film, indicating an increased carrier transport capacity.

中图分类号 TM282   DOI 10.11973/jxgccl201902005

 
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所属栏目 试验研究

基金项目 国家自然科学基金资助项目(11274174);江苏高校优势学科建设工程项目

收稿日期 2017/12/16

修改稿日期 2019/1/4

网络出版日期

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备注王建业(1991-),男,江苏淮安人,硕士研究生

引用该论文: WANG Jianye,WANG Yiping,YANG Ying,SHENG Yun. Preparation and Electric Property of 0.1HoMnO3-0.9BiFeO3 Flexible Ferroelectric Thin Film[J]. Materials for mechancial engineering, 2019, 43(2): 23~27
王建业,王一平,杨颖,盛云. 0.1HoMnO3-0.9BiFeO3柔性铁电薄膜的制备及电学性能[J]. 机械工程材料, 2019, 43(2): 23~27


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