Effects of Sintering Temperature on Properties of AlCoCrFeNi2.1 High-Entropy Alloy by Spark Plasma Sintering
摘 要
采用放电等离子烧结(SPS)技术在不同烧结温度(850,950,1 050,1 150℃)保温5 min条件下制备AlCoCrFeNi2.1高熵合金,研究了烧结温度对合金的烧结性能、物相组成、微观形貌和力学性能的影响。结果表明:随着烧结温度升高,合金表面气孔数量逐渐减少,合金相对密度增大;当烧结温度升至1 150℃时,合金颗粒间形成了良好的冶金结合;随着烧结温度升高,烧结合金的显微硬度和屈服强度均先增后降,当烧结温度为1 050℃时,烧结合金的显微硬度和屈服强度最大;烧结合金的断裂机制为沿晶断裂和穿晶断裂。
Abstract
AlCoCrFeNi2.1 high-entropy alloy was prepared by spark plasma sintering (SPS) at different sintering temperatures (850,950,1 050,1 150℃) for 5 min. The effects of sintering temperature on sintering properties, phase composition, micromorphology, mechanical properties of the alloy were studied. The results show that with sintering temperature increasing, the amount of pores on the surface of the alloy decreased and the relative density of the alloy increased. When the sintering temperature rose to 1 150℃, good metallurgic bonding was formed between the alloy particles. With the increase of sintering temperature, the microhardness and yield strength of the sintered alloy increased first and then decreased. When the sintering temperature was 1 050℃,the microhardness and yield strength of the sintered alloy were the highest. The fracture mechanism of the sintered alloy was intergranular fracture and transgranular fracture.
中图分类号 TG146 DOI 10.11973/jxgccl201907007
所属栏目 材料性能及应用
基金项目
收稿日期 2018/7/6
修改稿日期 2019/5/23
网络出版日期
作者单位点击查看
备注姚瑞敏(1982-),女,山西长治人,讲师,硕士
引用该论文: YAO Ruimin,ZHENG Liuwei. Effects of Sintering Temperature on Properties of AlCoCrFeNi2.1 High-Entropy Alloy by Spark Plasma Sintering[J]. Materials for mechancial engineering, 2019, 43(7): 28~32
姚瑞敏,郑留伟. 烧结温度对放电等离子烧结AlCoCrFeNi2.1高熵合金性能的影响[J]. 机械工程材料, 2019, 43(7): 28~32
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】饶湖常, 戴品强, 陈鼎宁, 等. 碳含量对FeCoCrNiMnCx高熵合金显微组织与性能的影响[J]. 机械工程材料, 2016, 40(8):76-80.
【2】JIN G, CAI Z B, GUAN Y J, et al. High temperature wear performance of laser-cladded FeNiCoAlCu high-entropy alloy coating[J]. Applied Surface Science, 2018, 445:113-122.
【3】HE J Y, WANG H, HUANG H L, et al. A precipitation-hardened high-entropy alloy with outstanding tensile properties[J]. Acta Materialia, 2016, 102:187-196.
【4】陈永星, 朱胜, 王晓明, 等. 高熵合金制备及研究进展[J]. 材料工程, 2017, 45(11):129-138.
【5】刘丘林, 刘允中, 王艳群, 等. 高熵合金的研究现状和应用前景[J]. 粉末冶金工业, 2017, 27(6):64-69.
【6】LUO W Y, LIU Y Z, LUO Y, et al. Fabrication and characterization of WC-AlCoCrCuFeNi high-entropy alloy composites by spark plasma sintering[J]. Journal of Alloys and Compounds, 2018, 754:163-170.
【7】KUMAR D, MAULIK O, KUMAR S, et al. Phase and thermal study of equiatomic AlCuCrFeMnW high entropy alloy processed via spark plasma sintering[J]. Materials Chemistry and Physics, 2018, 210:71-77.
【8】刘灯宪, 彭琼, 吴波, 等.AlCoCrFe1.5Ni高熵合金的显微组织与性能[J].机械工程材料,2016,40(10):55-59.
【9】ZHANG Z H, LIU Z F, LU J F, et al. The sintering mechanism in spark plasma sintering:Proof of the occurrence of spark discharge[J].Scripta Materialia,2014,81(11):56-59.
【10】DELAIZIR G, BERNARD-GRANGER G, MONNIER J, et al. A comparative study of spark plasma sintering (SPS), hot isostatic pressing (HIP) and microwaves sintering techniques on p-type Bi2Te3 thermoelectric properties[J]. Materials Research Bulletin, 2012, 47(8):1954-1960.
【11】MOHANTY S, MAITY T N, MUKHOPADHYAY S, et al. Powder metallurgical processing of equiatomic AlCoCrFeNi high entropy alloy:Microstructure and mechanical properties[J].Materials Science and Engineering, 2017,679:299-313.
【12】GAO X Z, LU Y P, ZHANG B, et al. Microstructural origins of high strength and high ductility in an AlCoCrFeNi2.1 eutectic high-entropy alloy[J].Acta Materialia, 2017, 141:59-66.
【13】GAO X Z, LU Y P, ZHANG B, et al. Microstructural origins of high strength and high ductility in an AlCoCrFeNi2.1 eutectic high-entropy alloy[J]. Acta Materialia, 2017, 141:59-66.
【14】RANGANATHAN S. Alloyed pleasures:Multimetallic cocktails[J]. Current Science, 2003, 85(10):1404-1406.
【2】JIN G, CAI Z B, GUAN Y J, et al. High temperature wear performance of laser-cladded FeNiCoAlCu high-entropy alloy coating[J]. Applied Surface Science, 2018, 445:113-122.
【3】HE J Y, WANG H, HUANG H L, et al. A precipitation-hardened high-entropy alloy with outstanding tensile properties[J]. Acta Materialia, 2016, 102:187-196.
【4】陈永星, 朱胜, 王晓明, 等. 高熵合金制备及研究进展[J]. 材料工程, 2017, 45(11):129-138.
【5】刘丘林, 刘允中, 王艳群, 等. 高熵合金的研究现状和应用前景[J]. 粉末冶金工业, 2017, 27(6):64-69.
【6】LUO W Y, LIU Y Z, LUO Y, et al. Fabrication and characterization of WC-AlCoCrCuFeNi high-entropy alloy composites by spark plasma sintering[J]. Journal of Alloys and Compounds, 2018, 754:163-170.
【7】KUMAR D, MAULIK O, KUMAR S, et al. Phase and thermal study of equiatomic AlCuCrFeMnW high entropy alloy processed via spark plasma sintering[J]. Materials Chemistry and Physics, 2018, 210:71-77.
【8】刘灯宪, 彭琼, 吴波, 等.AlCoCrFe1.5Ni高熵合金的显微组织与性能[J].机械工程材料,2016,40(10):55-59.
【9】ZHANG Z H, LIU Z F, LU J F, et al. The sintering mechanism in spark plasma sintering:Proof of the occurrence of spark discharge[J].Scripta Materialia,2014,81(11):56-59.
【10】DELAIZIR G, BERNARD-GRANGER G, MONNIER J, et al. A comparative study of spark plasma sintering (SPS), hot isostatic pressing (HIP) and microwaves sintering techniques on p-type Bi2Te3 thermoelectric properties[J]. Materials Research Bulletin, 2012, 47(8):1954-1960.
【11】MOHANTY S, MAITY T N, MUKHOPADHYAY S, et al. Powder metallurgical processing of equiatomic AlCoCrFeNi high entropy alloy:Microstructure and mechanical properties[J].Materials Science and Engineering, 2017,679:299-313.
【12】GAO X Z, LU Y P, ZHANG B, et al. Microstructural origins of high strength and high ductility in an AlCoCrFeNi2.1 eutectic high-entropy alloy[J].Acta Materialia, 2017, 141:59-66.
【13】GAO X Z, LU Y P, ZHANG B, et al. Microstructural origins of high strength and high ductility in an AlCoCrFeNi2.1 eutectic high-entropy alloy[J]. Acta Materialia, 2017, 141:59-66.
【14】RANGANATHAN S. Alloyed pleasures:Multimetallic cocktails[J]. Current Science, 2003, 85(10):1404-1406.
相关信息