离子交换型可控释放智能缓蚀剂的研究进展
Research Progress of Ion-Exchange Type Controlled-Release Smart Corrosion Inhibitors
摘 要
介绍了近十年来离子交换型可控释放智能缓蚀剂的研究进展，根据缓蚀剂和刺激离子的电负性可将该类缓蚀剂分为阳离子型和阴离子型，对两类缓蚀剂的原理、发展和制备进行了探讨，并对未来离子交换型智能缓蚀剂的研究方向和关注热点提出了展望。
离子交换
可控释放
smart corrosion inhibitor
ion-exchange
controlled-release
Abstract
The research progress of ion-exchange type controlled-release intelligent corrosion inhibitors in the past ten years is introduced. The corrosion inhibitors can be classified into a cationic type and an anionic type, depending on the electronegativity of the corrosion inhibitors and stimulating ions. The principle, development and preparation of these two types of corrosion inhibitors are discussed, and the future research directions and hotspots of ion exchange intelligent corrosion inhibitors are proposed.
中图分类号 TG174.4 DOI 10.11973/fsyfh-201907008
所属栏目 专论
基金项目
收稿日期 2017/12/22
修改稿日期
网络出版日期
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引用该论文: TIAN Yuwan,WEN Cheng,DONG Chaofang,WANG Gui,LI Xiaogang. Research Progress of Ion-Exchange Type Controlled-Release Smart Corrosion Inhibitors[J]. Corrosion & Protection, 2019, 40(7): 507
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参考文献
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【4】杨玉霞, 杨怀玉. pH敏感型智能材料的研究进展及其在缓蚀剂中的应用. 腐蚀与防护, 2010, 31(增刊1):221-224.
【5】程伟, 周扬, 古华山, 等. 环境友好型缓蚀剂的研究进展. 石油化工腐蚀与防护, 2015, 32(3):9-11.
【6】Products:synthetic silicas,Shieldex® anti-corrosion pigments. Grace website; https://grace.com/coatings-and-inks/en-us/anti-corrosion-pigments.
【7】GRANIZO N, VEGA J M, DÍAZ I, et al. Paint systems formulated with ion-exchange pigments applied on carbon steel:Effect of surface preparation. Progress in Organic Coatings, 2011, 70(4):394-400.
【8】LI J C, BUCHHEIT R. Development of zinc ferrocyanide ion exchange compounds for corrosion-inhibiting and sensing pigments. Progress in Organic Coatings, 2017, 104:210-216.
【9】BOUALI I, ROCCA E, VEYS-RENAUX D, et al. Ca2+-exchange in layered zirconium orthophosphate, α-ZrP:chemical study and potential application for zinc corrosion inhibition. Applied Surface Science, 2017, 422:778-786.
【10】WILLIAMS G, GEARY S, MCMURRAY H N. Smart release corrosion inhibitor pigments based on organic ion-exchange resins. Corrosion Science, 2012, 57:139-147.
【11】WILLIAMS G, MCMURRAY H N, LOVERIDGE M J. Inhibition of corrosion-driven organic coating disbondment on galvanised steel by smart release group Ⅱ and Zn(Ⅱ)-exchanged bentonite pigments. Electrochimica Acta, 2010, 55(5):1740-1748.
【12】WILLIAMS G, MCMURRAY H N. Inhibition of filiform corrosion on organic-coated AA2024-T3 by smart-release cation and anion-exchange pigments. Electrochimica Acta, 2012, 69:287-294.
【13】MOTTE C, POELMAN M, ROOBROECK A, et al. Improvement of corrosion protection offered to galvanized steel by incorporation of lanthanide modified nanoclays in silane layer. Progress in Organic Coatings, 2012, 74(2):326-333.
【14】DIAS S A S, LAMAKA S V, NOGUEIRA C A, et al. Sol-gel coatings modified with zeolite fillers for active corrosion protection of AA2024. Corrosion Science, 2012, 62:153-162.
【15】ROSELLI S, BELLOTTI N, DEYÁ C, et al. Lanthanum-exchanged zeolite and clay as anticorrosive pigments for galvanized steel. Journal of Rare Earths, 2014, 32(4):352-359.
【16】AGHZZAF A A, RHOUTA B, ROCCA E, et al. Corrosion inhibition of zinc by calcium exchanged beidellite clay mineral:a new smart corrosion inhibitor. Corrosion Science, 2014, 80:46-52.
【17】FERRER E L, ROLLON A P, MENDOZA H D, et al. Double-doped zeolites for corrosion protection of aluminium alloys. Microporous and Mesoporous Materials, 2014, 188:8-15.
【18】GHAZI A, GHASEMI E, MAHDAVIAN M, et al. The application of benzimidazole and zinc cations intercalated sodium montmorillonite as smart ion exchange inhibiting pigments in the epoxy ester coating. Corrosion Science, 2015, 94:207-217.
【19】SERDECHNOVA M, SALAK A N, BARBOSA F S, et al. Interlayer intercalation and arrangement of 2-mercaptobenzothiazolate and 1, 2, 3-benzotriazolate anions in layered double hydroxides:in situ X-ray diffraction study. Journal of Solid State Chemistry, 2016, 233:158-165.
【20】YUAN Y, ZHANG X L, LEI Y, et al. Nitrogen removal by modified zeolites coated with Zn-layered double hydroxides (Zn-LDHs) prepared at different molar ratios. Journal of the Taiwan Institute of Chemical Engineers, 2018, 87:73-82.
【21】WILLIAMS G, MCMURRAY H N. Inhibition of filiform corrosion on polymer coated AA2024-T3 by hydrotalcite-like pigments incorporating organic anions. Electrochemical and Solid-State Letters, 2004, 7(5):B13.
【22】TEDIM J, KUZNETSOVA A, SALAK A N, et al. Zn-Al layered double hydroxides as chloride nanotraps in active protective coatings. Corrosion Science, 2012, 55:1-4.
【23】于湘, 牛显春, 俞志东. 缓蚀剂钼酸盐插层水滑石对Cl-吸附行为的研究. 表面技术, 2012, 41(6):26-29.
【24】于湘, 俞志东, 程丽华,等. LDH型MoO2-4缓蚀剂的合成及防腐性能. 精细化工, 2013, 30(1):7-11.
【25】LI D D, WANG F Y, YU X, et al. Anticorrosion organic coating with layered double hydroxide loaded with corrosion inhibitor of tungstate. Progress in Organic Coatings, 2011, 71(3):302-309.
【26】CAO Y H, DONG S G, ZHENG D J, et al. Multifunctional inhibition based on layered double hydroxides to comprehensively control corrosion of carbon steel in concrete. Corrosion Science, 2017, 126:166-179.
【27】ZHANG Y, LI Y D, REN Y S, et al. Double-doped LDH films on aluminum alloys for active protection. Materials Letters, 2017, 192:33-35.
【28】TEDIM J, BASTOS A C, KALLIP S, et al. Corrosion protection of AA2024-T3 by LDH conversion films. Analysis of SVET results. Electrochimica Acta, 2016, 210:215-224.
【29】GHAZI A, GHASEMI E, MAHDAVIAN M, et al. The application of benzimidazole and zinc cations intercalated sodium montmorillonite as smart ion exchange inhibiting pigments in the epoxy ester coating. Corrosion Science, 2015, 94:207-217.
【30】XU Y D, SUTHAR J, EGBU R, et al. Reverse microemulsion synthesis of layered gadolinium hydroxide nanoparticles. Journal of Solid State Chemistry, 2018, 258:320-327.
【31】SMALENSKAITE A, SALAK A N, FERREIRA M G S, et al. Sol-gel synthesis and characterization of hybrid inorganic-organic Tb(Ⅲ)-terephthalate containing layered double hydroxides. Optical Materials, 2018, 80:186-196.
【32】ZHELUDKEVICH M L, POZNYAK S K, RODRIGUES L M, et al. Active protection coatings with layered double hydroxide nanocontainers of corrosion inhibitor. Corrosion Science, 2010, 52(2):602-611.
【33】HU J L, GAN M Y, MA L, et al. Preparation and enhanced properties of polyaniline/grafted intercalated ZnAl-LDH nanocomposites. Applied Surface Science, 2015, 328:325-334.
【34】WANG Y, ZHANG D. Synthesis, characterization, and controlled release anticorrosion behavior of benzoate intercalated Zn-Al layered double hydroxides. Materials Research Bulletin, 2011, 46(11):1963-1968.
【35】HANG T T X, TRUC T A, DUONG N T, et al. Preparation and characterization of nanocontainers of corrosion inhibitor based on layered double hydroxides. Applied Clay Science, 2012, 67/68:18-25.
【36】STIMPFLING T, LEROUX F, HINTZE-BRUENING H. Unraveling EDTA corrosion inhibition when interleaved into layered double hydroxide epoxy filler system coated onto aluminum AA 2024. Applied Clay Science, 2013, 83/84:32-41.
【37】STIMPFLING T, LEROUX F, HINTZE-BRUENING H. Organo-modified layered double hydroxide in coating formulation to protect AA2024 from corrosion. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2014, 458:147-154.
【38】POZNYAK S K, TEDIM J, RODRIGUES L M, et al. Novel inorganic host layered double hydroxides intercalated with guest organic inhibitors for anticorrosion applications. ACS Applied Materials & Interfaces, 2009, 1(10):2353-2362.
【39】LI Y D, LI S M, ZHANG Y, et al. Fabrication of superhydrophobic layered double hydroxides films with different metal cations on anodized aluminum 2198 alloy. Materials Letters, 2015, 142:137-140.
【40】LI Y D, LI S M, ZHANG Y, et al. Enhanced protective Zn-Al layered double hydroxide film fabricated on anodized 2198 aluminum alloy. Journal of Alloys and Compounds, 2015, 630:29-36.
【41】MOHEDANO M, SERDECHNOVA M, STARYKEVICH M, et al. Active protective PEO coatings on AA2024:Role of voltage on in-situ LDH growth. Materials & Design, 2017, 120:36-46.
【42】TEDIM J, ZHELUDKEVICH M L, BASTOS A C, et al. Influence of preparation conditions of Layered Double Hydroxide conversion films on corrosion protection. Electrochimica Acta, 2014, 117:164-171.
【2】HOU B R, LI X G, MA X M, et al. The cost of corrosion in China. Npj Materials Degradation, 2017(1):4-6.
【3】陈振宇, 郭兴蓬. 缓蚀剂研究进展简述. 腐蚀与防护, 2014, 35(增刊2):1-7.
【4】杨玉霞, 杨怀玉. pH敏感型智能材料的研究进展及其在缓蚀剂中的应用. 腐蚀与防护, 2010, 31(增刊1):221-224.
【5】程伟, 周扬, 古华山, 等. 环境友好型缓蚀剂的研究进展. 石油化工腐蚀与防护, 2015, 32(3):9-11.
【6】Products:synthetic silicas,Shieldex® anti-corrosion pigments. Grace website; https://grace.com/coatings-and-inks/en-us/anti-corrosion-pigments.
【7】GRANIZO N, VEGA J M, DÍAZ I, et al. Paint systems formulated with ion-exchange pigments applied on carbon steel:Effect of surface preparation. Progress in Organic Coatings, 2011, 70(4):394-400.
【8】LI J C, BUCHHEIT R. Development of zinc ferrocyanide ion exchange compounds for corrosion-inhibiting and sensing pigments. Progress in Organic Coatings, 2017, 104:210-216.
【9】BOUALI I, ROCCA E, VEYS-RENAUX D, et al. Ca2+-exchange in layered zirconium orthophosphate, α-ZrP:chemical study and potential application for zinc corrosion inhibition. Applied Surface Science, 2017, 422:778-786.
【10】WILLIAMS G, GEARY S, MCMURRAY H N. Smart release corrosion inhibitor pigments based on organic ion-exchange resins. Corrosion Science, 2012, 57:139-147.
【11】WILLIAMS G, MCMURRAY H N, LOVERIDGE M J. Inhibition of corrosion-driven organic coating disbondment on galvanised steel by smart release group Ⅱ and Zn(Ⅱ)-exchanged bentonite pigments. Electrochimica Acta, 2010, 55(5):1740-1748.
【12】WILLIAMS G, MCMURRAY H N. Inhibition of filiform corrosion on organic-coated AA2024-T3 by smart-release cation and anion-exchange pigments. Electrochimica Acta, 2012, 69:287-294.
【13】MOTTE C, POELMAN M, ROOBROECK A, et al. Improvement of corrosion protection offered to galvanized steel by incorporation of lanthanide modified nanoclays in silane layer. Progress in Organic Coatings, 2012, 74(2):326-333.
【14】DIAS S A S, LAMAKA S V, NOGUEIRA C A, et al. Sol-gel coatings modified with zeolite fillers for active corrosion protection of AA2024. Corrosion Science, 2012, 62:153-162.
【15】ROSELLI S, BELLOTTI N, DEYÁ C, et al. Lanthanum-exchanged zeolite and clay as anticorrosive pigments for galvanized steel. Journal of Rare Earths, 2014, 32(4):352-359.
【16】AGHZZAF A A, RHOUTA B, ROCCA E, et al. Corrosion inhibition of zinc by calcium exchanged beidellite clay mineral:a new smart corrosion inhibitor. Corrosion Science, 2014, 80:46-52.
【17】FERRER E L, ROLLON A P, MENDOZA H D, et al. Double-doped zeolites for corrosion protection of aluminium alloys. Microporous and Mesoporous Materials, 2014, 188:8-15.
【18】GHAZI A, GHASEMI E, MAHDAVIAN M, et al. The application of benzimidazole and zinc cations intercalated sodium montmorillonite as smart ion exchange inhibiting pigments in the epoxy ester coating. Corrosion Science, 2015, 94:207-217.
【19】SERDECHNOVA M, SALAK A N, BARBOSA F S, et al. Interlayer intercalation and arrangement of 2-mercaptobenzothiazolate and 1, 2, 3-benzotriazolate anions in layered double hydroxides:in situ X-ray diffraction study. Journal of Solid State Chemistry, 2016, 233:158-165.
【20】YUAN Y, ZHANG X L, LEI Y, et al. Nitrogen removal by modified zeolites coated with Zn-layered double hydroxides (Zn-LDHs) prepared at different molar ratios. Journal of the Taiwan Institute of Chemical Engineers, 2018, 87:73-82.
【21】WILLIAMS G, MCMURRAY H N. Inhibition of filiform corrosion on polymer coated AA2024-T3 by hydrotalcite-like pigments incorporating organic anions. Electrochemical and Solid-State Letters, 2004, 7(5):B13.
【22】TEDIM J, KUZNETSOVA A, SALAK A N, et al. Zn-Al layered double hydroxides as chloride nanotraps in active protective coatings. Corrosion Science, 2012, 55:1-4.
【23】于湘, 牛显春, 俞志东. 缓蚀剂钼酸盐插层水滑石对Cl-吸附行为的研究. 表面技术, 2012, 41(6):26-29.
【24】于湘, 俞志东, 程丽华,等. LDH型MoO2-4缓蚀剂的合成及防腐性能. 精细化工, 2013, 30(1):7-11.
【25】LI D D, WANG F Y, YU X, et al. Anticorrosion organic coating with layered double hydroxide loaded with corrosion inhibitor of tungstate. Progress in Organic Coatings, 2011, 71(3):302-309.
【26】CAO Y H, DONG S G, ZHENG D J, et al. Multifunctional inhibition based on layered double hydroxides to comprehensively control corrosion of carbon steel in concrete. Corrosion Science, 2017, 126:166-179.
【27】ZHANG Y, LI Y D, REN Y S, et al. Double-doped LDH films on aluminum alloys for active protection. Materials Letters, 2017, 192:33-35.
【28】TEDIM J, BASTOS A C, KALLIP S, et al. Corrosion protection of AA2024-T3 by LDH conversion films. Analysis of SVET results. Electrochimica Acta, 2016, 210:215-224.
【29】GHAZI A, GHASEMI E, MAHDAVIAN M, et al. The application of benzimidazole and zinc cations intercalated sodium montmorillonite as smart ion exchange inhibiting pigments in the epoxy ester coating. Corrosion Science, 2015, 94:207-217.
【30】XU Y D, SUTHAR J, EGBU R, et al. Reverse microemulsion synthesis of layered gadolinium hydroxide nanoparticles. Journal of Solid State Chemistry, 2018, 258:320-327.
【31】SMALENSKAITE A, SALAK A N, FERREIRA M G S, et al. Sol-gel synthesis and characterization of hybrid inorganic-organic Tb(Ⅲ)-terephthalate containing layered double hydroxides. Optical Materials, 2018, 80:186-196.
【32】ZHELUDKEVICH M L, POZNYAK S K, RODRIGUES L M, et al. Active protection coatings with layered double hydroxide nanocontainers of corrosion inhibitor. Corrosion Science, 2010, 52(2):602-611.
【33】HU J L, GAN M Y, MA L, et al. Preparation and enhanced properties of polyaniline/grafted intercalated ZnAl-LDH nanocomposites. Applied Surface Science, 2015, 328:325-334.
【34】WANG Y, ZHANG D. Synthesis, characterization, and controlled release anticorrosion behavior of benzoate intercalated Zn-Al layered double hydroxides. Materials Research Bulletin, 2011, 46(11):1963-1968.
【35】HANG T T X, TRUC T A, DUONG N T, et al. Preparation and characterization of nanocontainers of corrosion inhibitor based on layered double hydroxides. Applied Clay Science, 2012, 67/68:18-25.
【36】STIMPFLING T, LEROUX F, HINTZE-BRUENING H. Unraveling EDTA corrosion inhibition when interleaved into layered double hydroxide epoxy filler system coated onto aluminum AA 2024. Applied Clay Science, 2013, 83/84:32-41.
【37】STIMPFLING T, LEROUX F, HINTZE-BRUENING H. Organo-modified layered double hydroxide in coating formulation to protect AA2024 from corrosion. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2014, 458:147-154.
【38】POZNYAK S K, TEDIM J, RODRIGUES L M, et al. Novel inorganic host layered double hydroxides intercalated with guest organic inhibitors for anticorrosion applications. ACS Applied Materials & Interfaces, 2009, 1(10):2353-2362.
【39】LI Y D, LI S M, ZHANG Y, et al. Fabrication of superhydrophobic layered double hydroxides films with different metal cations on anodized aluminum 2198 alloy. Materials Letters, 2015, 142:137-140.
【40】LI Y D, LI S M, ZHANG Y, et al. Enhanced protective Zn-Al layered double hydroxide film fabricated on anodized 2198 aluminum alloy. Journal of Alloys and Compounds, 2015, 630:29-36.
【41】MOHEDANO M, SERDECHNOVA M, STARYKEVICH M, et al. Active protective PEO coatings on AA2024:Role of voltage on in-situ LDH growth. Materials & Design, 2017, 120:36-46.
【42】TEDIM J, ZHELUDKEVICH M L, BASTOS A C, et al. Influence of preparation conditions of Layered Double Hydroxide conversion films on corrosion protection. Electrochimica Acta, 2014, 117:164-171.
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