Corrosion Behavior of Q235 Steel in Three Typical Soil Environments
摘 要
选择取自武汉的近中性黄棕壤、取自天津的碱性盐碱土和取自南昌的酸性红壤作为腐蚀介质,对Q235钢进行室内模拟加速腐蚀试验,对比研究了试验钢的腐蚀速率、腐蚀形貌和腐蚀产物组成,分析了其腐蚀机理。结果表明:在3种土壤中试验钢均发生了不均匀的全面腐蚀和局部点蚀。腐蚀产物外层结构疏松,主要由Fe2O3、FeOOH组成;内层结构致密,主要由Fe3O4组成。在碱性盐碱土中,试验钢表面形成了结构完整的腐蚀产物层,抑制了阴极的耗氧反应,腐蚀速率最低;酸性红壤中较高浓度的H+促进了阴极析氢反应的进行以及裂纹的产生,试验钢腐蚀速率最高;在腐蚀后期,试验钢表面形成了致密的Fe3O4内锈层,因此腐蚀15 d时的腐蚀速率大于腐蚀30 d时的。
Abstract
The near-neutral yellow brown soil from Wuhan, the alkaline saline-alkali soil from Tianjin and the acid red soil from Nanchang were selected as corrosive media. The indoor simulated accelerated corrosion test of Q235 steel was carried out. The corrosion rate, corrosion morphology and corrosion product composition of the test steel were compared, and the corrosion mechanism was analyzed. The results show that the test steel in all the three soils had uneven comprehensive corrosion and local pitting. The outer layer structure of the corrosion products was loose, mainly composed of Fe2O3 and FeOOH. The inner layer structure was dense and mainly composed of Fe3O4. In the alkaline saline-alkali soil, a structurally complete corrosion product layer was formed on the surface of the test steel, which inhibited the oxygen-consuming reaction of the cathode; the corrosion rate was the lowest. The higher concentration of H+ in acid red soil promoted the process of the cathodic hydrogen evolution reaction and the generation of cracks; the corrosion rate of the test steel was the highest. In the later stage of corrosion, the dense inner rust layer of Fe3O4 was formed on the surface of the test steel; the corrosion rate of the test steel during 15 d was higher than that during 30 d.
中图分类号 TG172 DOI 10.11973/jxgccl201910004
所属栏目 试验研究
基金项目 国家自然科学基金资助项目(51961028);国家电网公司科技项目(52182017000Y)
收稿日期 2018/9/28
修改稿日期 2019/9/3
网络出版日期
作者单位点击查看
备注朱亦晨(1996-),男,江西萍乡人,硕士研究生
引用该论文: ZHU Yichen,LIU Guangming,LIU Xin,PEI Feng,TIAN Xu,GAN Hongyu. Corrosion Behavior of Q235 Steel in Three Typical Soil Environments[J]. Materials for mechancial engineering, 2019, 43(10): 15~19
朱亦晨,刘光明,刘欣,裴锋,田旭,甘鸿禹. Q235钢在3种典型土壤环境中的腐蚀行为[J]. 机械工程材料, 2019, 43(10): 15~19
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【3】李风雷, 刘勇, 刘建秋. 接地网腐蚀与防护研究进展[J]. 工业建筑, 2012, 42(增刊1):783-785.
【4】ZOU Y, WANG J, ZHENG Y Y. Electrochemical techniques for determining corrosion rate of rusted steel in seawater[J]. Corrosion Science, 2011, 53(1):208-216.
【5】裴锋, 刘光明, 刘欣, 等. 不同湿度的酸性红壤中Q235钢-紫铜电偶腐蚀行为研究[J]. 表面技术, 2017, 46(8):240-245.
【6】聂向晖, 李晓刚, 李云龙, 等. 碳钢的土壤腐蚀模拟加速实验[J]. 材料工程, 2012, 40(1):59-65.
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【8】李海玲, 万红霞, 杜翠薇. 镀锌钢在多种典型土壤环境中的腐蚀行为[J]. 腐蚀与防护, 2018, 39(5):387-390.
【9】裴锋, 田野, 刘平,等. Q235碳钢在红壤中的腐蚀行为[J]. 腐蚀与防护, 2016, 37(9):715-719.
【10】李健, 苏航, 柴锋, 等. Q235钢在实际土壤与模拟溶液中的腐蚀行为[J]. 钢铁研究学报, 2014, 26(12):36-41.
【11】王帅星, 杜楠, 刘道新, 等. 模拟酸雨作用下红壤含水量对X80钢腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2018, 38(2):147-157.
【12】LIU G M, GUO S Q, LI D S, et al. Effects of moisture content on soil corrosion behavior of Q235 steel[C]//Materials Engineering and Environmental Science:Proceedings of the 2015 International Conference on Materials Engineering and Environmental Science (MEES2015). Singapore:World Scientific Publishing Company, 2016.
【13】王彬彬, 王军, 卢志伟, 等. 红壤模拟溶液中Cl-对X80管线钢腐蚀行为的影响[J]. 全面腐蚀控制, 2016, 30(11):54-58.
【14】董超芳, 李晓刚, 武俊伟, 等. 土壤腐蚀的实验研究与数据处理[J]. 腐蚀科学与防护技术, 2003, 15(3):154-160.
【15】LIU Z Y, WANG L W, DU C W, et al. Short-term corrosion behavior of Q235 steel and X70 pipeline steel in gray desert soil in North America[J]. Journal of University of Science & Technology Beijing, 2013, 35(8):1021-1026.
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