Corrosion Behavior of 2205 Duplex Stainless Steel in Deep Seawater of South China Sea
摘 要
利用腐蚀挂片试验与循环极化测试的方法,结合光学显微镜、扫描电子显微镜(SEM)、能谱仪(EDS)等测试手段研究了2205双相不锈钢在南海水下170 m海水中的腐蚀行为。结果表明:2205双相不锈钢在深海环境中发生了局部腐蚀;浸泡初期,不锈钢表面形成微生物保护膜,在微生物膜的保护下其耐蚀性能提高;随着浸泡时间的延长,微生物死亡、脱落,失去对金属基体的保护作用,导致不锈钢耐蚀性能下降;同时,残留的微生物膜与不锈钢基体间形成缝隙,在溶解氧与Cl-作用下发生缝隙腐蚀,形成局部腐蚀坑。
Abstract
The corrosion behavior of 2205 duplex stainless steel in the seawater under 170 m of South China Sea was studied by coupon corrosion testing and cyclic polarization testing in combination with scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The results show that localized corrosion occurred on the 2205 duplex stainless steel in deep-sea environment. At the initial stage of immersion, a microbial protective film was formed on the surface of the 2205 duplex stainless steel, and the corrosion resistance of the stainless steel improved under the protection of the microbial film. As the immersing time increased, microorganisms died and sloughed off, and then lost the protection for metal substrate, resulting in the decrease of corrosion resistance of the 2205 duplex stainless steel. A gap was formed between the residual microbial film and the stainless steel substrate, and crevice corrosion occurred under the action of dissolved oxygen and Cl- to form localized corrosion pits.
中图分类号 TG172 DOI 10.11973/fsyfh-201912006
所属栏目 试验研究
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收稿日期 2018/3/15
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引用该论文: SONG Jiwen,WANG Maomao,ZHANG Liang,LI Dapeng,CHEN Shengli,WANG Xiuyun,CHANG Wei,ZHANG Lei. Corrosion Behavior of 2205 Duplex Stainless Steel in Deep Seawater of South China Sea[J]. Corrosion & Protection, 2019, 40(12): 898
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参考文献
【1】王健. 2205双相不锈钢的点蚀及再钝化行为[D]. 大连:大连理工大学,2015.
【2】LUCIANO G, LETARDI P, TRAVERSO P, et al. Corrosion behaviour of Al, Cu, and Fe alloys in deep sea environment[J]. Metallurgia Italiana, 2013, 105(1): 21-29.
【3】XU D K, XIA J, ZHOU E Z, et al. Accelerated corrosion of 2205 duplex stainless steel caused by marine aerobic Pseudomonas aeruginosa biofilm[J]. Bioelectrochemistry, 2017, 113: 1-8.
【4】SAWANT S S, WAGH A B. Corrosion behaviour of metals and alloys in the waters of the Arabian sea[J].Corrosion Prevention and Control, 1990, 36: 154-157, 168.
【5】SAWANT S S, VENKAT K, WAGH A B. Corrosion of metals and alloys in the coastal and deep waters of the Arabian sea and the bay of Bengal[J]. Indian Journal of Technology, 1993, 31(12): 862-866.
【6】VENKATESAN R, VENKATASAMY M A, BHASKARAN T A, et al. Corrosion of ferrous alloys in deep sea environments[J]. British Corrosion Journal, 2002, 37(4): 257-266.
【7】TRAVERSO P, CANEPA E. A review of studies on corrosion of metals and alloys in deep-Sea environment[J]. Ocean Engineering, 2014, 87: 10-15.
【8】DEXTER S C, GAO G Y. Effect of seawater biofilms on corrosion potential and oxygen reduction of stainless steel[J]. Corrosion, 1988, 44(10): 717-723.
【9】牛桂华,尹衍升,常雪婷,等.海洋微生物对316不锈钢的电化学腐蚀行为[J].化学研究,2008,19(3):83-86,90.
【10】刘彬.海洋好氧生物膜在不锈钢电极表面的附着与腐蚀行为研究[D].青岛:中国科学院研究生院(海洋研究所),2011.
【2】LUCIANO G, LETARDI P, TRAVERSO P, et al. Corrosion behaviour of Al, Cu, and Fe alloys in deep sea environment[J]. Metallurgia Italiana, 2013, 105(1): 21-29.
【3】XU D K, XIA J, ZHOU E Z, et al. Accelerated corrosion of 2205 duplex stainless steel caused by marine aerobic Pseudomonas aeruginosa biofilm[J]. Bioelectrochemistry, 2017, 113: 1-8.
【4】SAWANT S S, WAGH A B. Corrosion behaviour of metals and alloys in the waters of the Arabian sea[J].Corrosion Prevention and Control, 1990, 36: 154-157, 168.
【5】SAWANT S S, VENKAT K, WAGH A B. Corrosion of metals and alloys in the coastal and deep waters of the Arabian sea and the bay of Bengal[J]. Indian Journal of Technology, 1993, 31(12): 862-866.
【6】VENKATESAN R, VENKATASAMY M A, BHASKARAN T A, et al. Corrosion of ferrous alloys in deep sea environments[J]. British Corrosion Journal, 2002, 37(4): 257-266.
【7】TRAVERSO P, CANEPA E. A review of studies on corrosion of metals and alloys in deep-Sea environment[J]. Ocean Engineering, 2014, 87: 10-15.
【8】DEXTER S C, GAO G Y. Effect of seawater biofilms on corrosion potential and oxygen reduction of stainless steel[J]. Corrosion, 1988, 44(10): 717-723.
【9】牛桂华,尹衍升,常雪婷,等.海洋微生物对316不锈钢的电化学腐蚀行为[J].化学研究,2008,19(3):83-86,90.
【10】刘彬.海洋好氧生物膜在不锈钢电极表面的附着与腐蚀行为研究[D].青岛:中国科学院研究生院(海洋研究所),2011.
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