Preperation and Corrosion Resistance of a Coating on the Surface of Aluminum Alloy for Aircraft Structure
摘 要
针对飞机结构用铝合金在使用过程中容易发生腐蚀的缺点,采用化学镀工艺在2024航空铝合金表面制备了Ni-P合金、Ni-W-P合金和Ni-P-MWCNTs复合镀层3种镀层,研究多臂碳纳米管(MWCNTs)与Na2WO4添加量对镀层沉积速率的影响,并对三种镀层的表面微观形貌、结合力、疏水性能、耐蚀性等进行观察与分析。结果表明:Ni-P-MWCNTs复合镀层的沉积速率随着WMCNTs量的增加呈现先增后减,当WMCNTs加入量为0.3 g/L时,其沉积速率达到最大值10.03 mg/(cm2·h)。Ni-W-P合金镀层的沉积速率随着Na2WO4加入量的增大而增大并逐渐趋于稳定,当Na2WO4加入量为18 g/L时,沉积速率达到15.21 mg/(cm2·h)。几种试样的综合性能由强到弱依次为Ni-W-P镀层 > Ni-P-MWCNTs镀层 > Ni-P镀层 > 基体试样。
Abstract
Aiming at the shortcomings of aluminum alloys for aircraft structures that were prone to corrosion during use, three types of cladding such as Ni-P alloy cladding, Ni-WP alloy cladding, and Ni-P-MWCNTs composite cladding were prepared on the surface of 2024 aviation aluminum alloy by chemical plating process. The effects of MWCNTs and Na2WO4 additions on the deposition rate of the claddings were studied, and surface micromorphology, adhesion, hydrophobic properties, corrosion resistance of the three coatings were observed and analyzed. The results show that the deposition rate of Ni-P-MWCNTs composite cladding increased first and then decreased with the increase of the amount of WMCNTs. When 0.3 g/L WMCNTs was added, the deposition rate reached a maximum of 10.03 mg/(cm2·h). The deposition rate of Ni-W-P alloy cladding gradually increased with the increase of the amount of Na2WO4 and gradually stabilized. When 18 g/L Na2WO4 was added, the deposition rate reached 15.21 mg/(cm2·h). The comprehensive performance of several samples in order from strong to weak was as follow:Ni-W-P coating > Ni-P-MWCNTs coating > Ni-P coating > matrix sample.
中图分类号 TG174.4 DOI 10.11973/fsyfh-202003008
所属栏目 试验研究
基金项目 民航教育项目(J170)
收稿日期 2018/6/15
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联系人作者秦文峰(qwfgrh@126.com)
引用该论文: QIN Wenfeng,FAN Yuhang,HAN Xiaoqiang,YOU Wentao,XU Yuheng. Preperation and Corrosion Resistance of a Coating on the Surface of Aluminum Alloy for Aircraft Structure[J]. Corrosion & Protection, 2020, 41(3): 43
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【5】DUQUESNAY D. Fatigue crack growth from corrosion damage in 7075-T6511 aluminium alloy under aircraft loading[J]. International Journal of Fatigue,2003,25(5):371-377.
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【12】鲁香粉,吴玉程,朱邦同,等. Ni-P-TiO2纳米复合镀层的制备及性能研究[J]. 功能材料,2008(3):482-484.
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