Microstructure and Wear Properties of High Velocity Oxygen Fuel Sprayed Cr3C2-NiCr Coating
摘 要
采用超音速火焰喷涂技术在H13钢基体上制备Cr3C2-NiCr涂层,研究了涂层的显微组织、物相组成及摩擦磨损性能,并探讨了磨损机理。结果表明:Cr3C2-NiCr涂层与H13钢基体结合紧密,厚度约为340 μm;涂层由Cr3C2硬质相、NiCr黏结相及少量Cr7C3相组成,组织致密,孔隙率为0.63%;Cr3C2-NiCr涂层与H13钢的稳定摩擦因数分别为0.90,0.75,涂层磨痕深度及磨损率仅为H13钢的1/2, 涂层耐磨性能较好;Cr3C2-NiCr涂层的磨损机理主要为磨粒磨损和疲劳磨损。
Abstract
The Cr3C2-NiCr coating was prepared on H13 steel substrate by high velocity oxygen fuel spraying technique. The microstructure,phase composition and friction and wear properties of the coating were studied, and the wear mechanism was discussed. The results show that the Cr3C2-NiCr coating with a thickness of about 340 μm was closely combined with the H13 steel substrate. The coating was composed of Cr3C2 hard phase, NiCr bonding phase and a small amount of Cr7C3, and the structure was dense with a porosity of 0.63%. The stable friction coefficients of the Cr3C2-NiCr coating and H13 steel were 0.90 and 0.75, respectively, and the wear track depth and wear rate of the coating were only half that of H13 steel, showing that the coating had relatively good wear resistance. The main wear mechanism of the Cr3C2-NiCr coating was abrasive wear and fatigue wear.
中图分类号 TG174.2 DOI 10.11973/jxgccl202004007
所属栏目 试验研究
基金项目
收稿日期 2019/9/23
修改稿日期 2020/3/3
网络出版日期
作者单位点击查看
备注师玮(1995-),女,河南安阳人,硕士研究生
引用该论文: SHI Wei,YANG Weihua,WU Yuping. Microstructure and Wear Properties of High Velocity Oxygen Fuel Sprayed Cr3C2-NiCr Coating[J]. Materials for mechancial engineering, 2020, 44(4): 35~39
师玮,杨伟华,吴玉萍. 超音速火焰喷涂Cr3C2-NiCr涂层的显微组织与磨损性能[J]. 机械工程材料, 2020, 44(4): 35~39
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】林林, 张小岩, 钱楚楚, 等. 中国压铸模具发展的现状与展望[J]. 特种铸造及有色合金, 2019, 39(1):45-48.
【2】RODRÍGUEZ-BARACALDOR R, BENITO J A, PUCHI-CABRERA E S,et al.High temperature wear resistance of (TiAl)N PVD coating on untreated and gas nitrided AISI H13 steel with different heat treatments[J]. Wear, 2007, 262(3/4):380-389.
【3】杨伟华, 吴玉萍, 洪晟, 等. 超音速火焰喷涂WC-10Co-4Cr涂层的微观组织与摩擦磨损性能[J]. 材料工程, 2018,46(5):120-125.
【4】JI G C,LI C J,WANG Y Y,et al.Microstructural characterization and abrasive wear performance of HVOF sprayed Cr3C2-NiCr coating[J].Surface and Coatings Technology, 2006, 200(24):6749-6757.
【5】AHMED R,VOURLIAS G,ALGOBURI A,et al.Comparative study of corrosion performance of HVOF-sprayed coatings produced using conventional and suspension WC-Co feedstock[J]. Journal of Thermal Spray Technology, 2018, 27(8):1579-1593.
【6】CHENG J B, WANG Z H, XU B S. Wear and corrosion behaviors of FeCrBSiNbW amorphous/nanocrystalline coating prepared by arc spraying process[J]. Journal of Thermal Spray Technology, 2012, 21(5):1025-1031.
【7】DINH V C, NGUYEN T P, DOAN T H, et al. Optimizating spray parameters of high velocity oxy fuel (HVOF) for Cr3C2-NiCr coating[J]. Applied Mechanics and Materials, 2019, 889:168-176.
【8】门向东, 陶凤和, 甘霖, 等. 超音速火焰喷涂Cr3C2-NiCr与WC-Co涂层高温结合性能研究[J]. 人工晶体学报, 2015, 44(7):2005-2010.
【9】师玮, 吴玉萍, 孙昊, 等. 超音速火焰喷涂CoCrAlYTa-10%Al2O3涂层的组织与性能[J]. 理化检验(物理分册), 2016, 52(8):562-566.
【10】陈淼. 超音速火焰喷涂NiCr-Cr3C2涂层的组织结构与摩擦学性能[J]. 材料保护, 2016, 49(9):23-26.
【11】WU N C,CHEN K,SUN W H,et al.Correlation between particle size and porosity of Fe-based amorphous coating[J].Surface Engineering, 2019,35(1):37-45.
【12】ZHOU W X,ZHOU K S,LI Y X, et al. High temperature wear performance of HVOF-sprayed Cr3C2-WC-NiCoCrMo and Cr3C2-NiCr hardmetal coatings[J]. Applied Surface Science, 2017, 416:33-44.
【13】GENG Z,LI S,DUAN D L,et al.Wear behaviour of WC-Co HVOF coatings at different temperatures in air and argon[J].Wear, 2015,330/331:348-353.
【14】CHENG J B,LIANG X B,WANG Z H,et al.Dry sliding friction and wear properties of metallic glass coating and martensite stainless coating[J].Tribology International, 2013,60:140-146.
【15】AMIRIYAN M,ALAMDARI H D,BLAIS C,et al. Dry sliding wear behavior of Fe3Al and Fe3Al/TiC coatings prepared by HVOF[J]. Wear, 2015, 342/343:154-162.
【16】JIN Y F,KONG W C,SHENG T Y,et al.Effect of load on friction-wear behavior of HVOF-sprayed WC-12Co coatings[J].Journal of Materials Engineering and Performance, 2017,26(7):3465-3473.
【17】WANG H B,WANG X Z,SONG X Y,et al. Sliding wear behavior of nanostructured WC-Co-Cr coatings[J]. Applied Surface Science, 2015, 355:453-460.
【18】兰箭, 张冰. H13钢表面超音速火焰喷涂制备耐磨涂层的研究[J]. 热加工工艺, 2010, 39(20):128-131.
【19】郭永明, 李绪强, 王海军, 等. 超音速等离子喷涂NiCr-Cr3C2/Mo复合涂层的高温摩擦磨损性能[J]. 中国表面工程, 2012,25(5):31-36.
【20】王东生, 田宗军, 王松林, 等. 激光重熔等离子喷涂WC颗粒增强镍基涂层组织及高温磨损性能[J]. 焊接学报, 2012, 33(11):13-16.
【21】CAI F,HUANG X,YANG Q.Mechanical properties,sliding wear and solid particle erosion behaviors of plasma enhanced magnetron sputtering CrSiCN coating systems[J].Wear, 2015,324/325:27-35.
【22】ARCHARD J F. Contact and rubbing of flat surfaces[J]. Journal of Applied Physics, 1953, 24(8):981-988.
【23】梁秀兵, 王慧, 商俊超, 等. FeCrBSiNb非晶涂层的制备及其性能[J]. 中国表面工程, 2017, 30(1):101-106.
【24】刘建金, 崔照雯, 贾成厂, 等. 超音速火焰喷涂WC-12Co涂层的滑动磨损特性[J]. 工程科学学报, 2015, 37(12): 1617-1623.
【25】ZHANG J F,LIU M,ZHOU K S,et al. Tribological behavior of HVOF cermet coatings as alternative to Cr-plating in artificial salt-fog atmosphere[J]. Rare Metal Materials and Engineering, 2016, 45(10): 2492-2497.
【2】RODRÍGUEZ-BARACALDOR R, BENITO J A, PUCHI-CABRERA E S,et al.High temperature wear resistance of (TiAl)N PVD coating on untreated and gas nitrided AISI H13 steel with different heat treatments[J]. Wear, 2007, 262(3/4):380-389.
【3】杨伟华, 吴玉萍, 洪晟, 等. 超音速火焰喷涂WC-10Co-4Cr涂层的微观组织与摩擦磨损性能[J]. 材料工程, 2018,46(5):120-125.
【4】JI G C,LI C J,WANG Y Y,et al.Microstructural characterization and abrasive wear performance of HVOF sprayed Cr3C2-NiCr coating[J].Surface and Coatings Technology, 2006, 200(24):6749-6757.
【5】AHMED R,VOURLIAS G,ALGOBURI A,et al.Comparative study of corrosion performance of HVOF-sprayed coatings produced using conventional and suspension WC-Co feedstock[J]. Journal of Thermal Spray Technology, 2018, 27(8):1579-1593.
【6】CHENG J B, WANG Z H, XU B S. Wear and corrosion behaviors of FeCrBSiNbW amorphous/nanocrystalline coating prepared by arc spraying process[J]. Journal of Thermal Spray Technology, 2012, 21(5):1025-1031.
【7】DINH V C, NGUYEN T P, DOAN T H, et al. Optimizating spray parameters of high velocity oxy fuel (HVOF) for Cr3C2-NiCr coating[J]. Applied Mechanics and Materials, 2019, 889:168-176.
【8】门向东, 陶凤和, 甘霖, 等. 超音速火焰喷涂Cr3C2-NiCr与WC-Co涂层高温结合性能研究[J]. 人工晶体学报, 2015, 44(7):2005-2010.
【9】师玮, 吴玉萍, 孙昊, 等. 超音速火焰喷涂CoCrAlYTa-10%Al2O3涂层的组织与性能[J]. 理化检验(物理分册), 2016, 52(8):562-566.
【10】陈淼. 超音速火焰喷涂NiCr-Cr3C2涂层的组织结构与摩擦学性能[J]. 材料保护, 2016, 49(9):23-26.
【11】WU N C,CHEN K,SUN W H,et al.Correlation between particle size and porosity of Fe-based amorphous coating[J].Surface Engineering, 2019,35(1):37-45.
【12】ZHOU W X,ZHOU K S,LI Y X, et al. High temperature wear performance of HVOF-sprayed Cr3C2-WC-NiCoCrMo and Cr3C2-NiCr hardmetal coatings[J]. Applied Surface Science, 2017, 416:33-44.
【13】GENG Z,LI S,DUAN D L,et al.Wear behaviour of WC-Co HVOF coatings at different temperatures in air and argon[J].Wear, 2015,330/331:348-353.
【14】CHENG J B,LIANG X B,WANG Z H,et al.Dry sliding friction and wear properties of metallic glass coating and martensite stainless coating[J].Tribology International, 2013,60:140-146.
【15】AMIRIYAN M,ALAMDARI H D,BLAIS C,et al. Dry sliding wear behavior of Fe3Al and Fe3Al/TiC coatings prepared by HVOF[J]. Wear, 2015, 342/343:154-162.
【16】JIN Y F,KONG W C,SHENG T Y,et al.Effect of load on friction-wear behavior of HVOF-sprayed WC-12Co coatings[J].Journal of Materials Engineering and Performance, 2017,26(7):3465-3473.
【17】WANG H B,WANG X Z,SONG X Y,et al. Sliding wear behavior of nanostructured WC-Co-Cr coatings[J]. Applied Surface Science, 2015, 355:453-460.
【18】兰箭, 张冰. H13钢表面超音速火焰喷涂制备耐磨涂层的研究[J]. 热加工工艺, 2010, 39(20):128-131.
【19】郭永明, 李绪强, 王海军, 等. 超音速等离子喷涂NiCr-Cr3C2/Mo复合涂层的高温摩擦磨损性能[J]. 中国表面工程, 2012,25(5):31-36.
【20】王东生, 田宗军, 王松林, 等. 激光重熔等离子喷涂WC颗粒增强镍基涂层组织及高温磨损性能[J]. 焊接学报, 2012, 33(11):13-16.
【21】CAI F,HUANG X,YANG Q.Mechanical properties,sliding wear and solid particle erosion behaviors of plasma enhanced magnetron sputtering CrSiCN coating systems[J].Wear, 2015,324/325:27-35.
【22】ARCHARD J F. Contact and rubbing of flat surfaces[J]. Journal of Applied Physics, 1953, 24(8):981-988.
【23】梁秀兵, 王慧, 商俊超, 等. FeCrBSiNb非晶涂层的制备及其性能[J]. 中国表面工程, 2017, 30(1):101-106.
【24】刘建金, 崔照雯, 贾成厂, 等. 超音速火焰喷涂WC-12Co涂层的滑动磨损特性[J]. 工程科学学报, 2015, 37(12): 1617-1623.
【25】ZHANG J F,LIU M,ZHOU K S,et al. Tribological behavior of HVOF cermet coatings as alternative to Cr-plating in artificial salt-fog atmosphere[J]. Rare Metal Materials and Engineering, 2016, 45(10): 2492-2497.
相关信息