碳化物层状结构陶瓷的制备和强韧化研究进展
Research Progress on Preparation and Toughening Mechanisms ofCarbide Laminar Ceramics
摘 要
基于仿生学原理设计的层状结构可以较好地解决碳化物陶瓷固有的脆性问题，是目前碳化物陶瓷强韧化最有效的途径之一，具有良好的应用前景。介绍了层状陶瓷的结构设计特点，综述了SiC和B4C层状结构陶瓷的制备、性能和主要增韧机制，并对碳化物结构陶瓷材料的发展进行了总结与展望。
碳化物陶瓷
强韧化机理
laminated structure
carbide ceramics
strengthening-toughening mechanism
Abstract
Laminated structures designed by bionics principle can better solve intrinsic brittleness problems of carbide ceramics. It is now one of the most effective ways to strengthen and toughen carbide ceramics, and has good application prospects. The structural design features of laminar ceramics are described. The preparation, performance and main toughening mechanisms of SiC and B4C laminar ceramics are reviewed. The development of carbide laminar ceramic materials is summarized and prospected.
中图分类号 TQ174 DOI 10.11973/jxgccl202006002
所属栏目 综述
基金项目 宁波市2025专项项目（2018B10006）；浙江省公益计划项目（LGG18E020006）
收稿日期 2020/5/7
修改稿日期 2020/5/20
网络出版日期
作者单位点击查看
备注史秀梅(1973-),女,山东平度人,研究员,博士
引用该论文: SHI Xiumei,ZHANG Lijun,ZHENG Yangsheng,CHENG Yingye,WANG Qiang,ZHANG Le,ZHENG Shunqi,SHI Geping. Research Progress on Preparation and Toughening Mechanisms ofCarbide Laminar Ceramics[J]. Materials for mechancial engineering, 2020, 44(6): 6～9
史秀梅,张立君,郑阳升,程英晔,王强,张乐,郑顺奇,史戈平. 碳化物层状结构陶瓷的制备和强韧化研究进展[J]. 机械工程材料, 2020, 44(6): 6～9
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参考文献
【1】王零森.特种陶瓷[M].长沙:中南工业大学出版社,1994:160-161.
【2】任文科,高光发,朴春华,等.碳化硼陶瓷复合靶板抗侵彻性能实验研究[J].高压物理学报,2019,33(4):045104.
【3】李缨.碳化硅晶须及其陶瓷基复合材料[J].陶瓷,2007(8):39-42.
【4】DENG Y C,ZHANG Y M,ZHANG N L,et al.Preparation and characterization of pure SiC ceramics by high temperature physical vapor transport induced by seeding with nano SiC particles[J].Journal of Materials Science & Technology, 2019,35(12):2756-2760.
【5】潘登,李树丰,张鑫,等.B4C-W2B5复合陶瓷的原位反应制备及其强韧化机理[J].陶瓷学报,2019,40(4):451-457.
【6】肖汉宁,高朋召.高性能结构陶瓷及其应用[M].北京:化学工业出版社,2006.
【7】周玉.陶瓷材料学[M].北京:科学出版社,2004.
【8】江东亮.精细陶瓷材料[M].北京:中国物资出版社,2000:134-150.
【9】聂丹,王帅,邢鹏飞,等.碳化硼陶瓷的制备工艺及其应用现状[J].铁合金,2019,50(3):33-39.
【10】聂立芳,张玉军,魏红康.碳化硅晶须增韧陶瓷基复合材料的研究进展[J].山东陶瓷,2006,29(2):16-19.
【11】杨万利,代丽娜,樊振宁,等.PAS烧结SiC/h-BN复相陶瓷的韧性表征[J].材料导报,2019,33(8):1272-1275.
【12】曾凡,陈建军,姜敏,等.SiC纳米线增强反应烧结碳化硅陶瓷的性能研究[J].硅酸盐通报,2018,37(2):586-590.
【13】余小斌,孟江燕,范金娟,等.SiCf/SiC复合材料原位分析研究进展[J].失效分析与预防,2019,14(5):350-356.
【14】窦叔菊.高温陶瓷工艺学[M].沈阳:东北大学出版社,1994:217-220.
【15】邹志欢, 曾凡浩, 刘吉安,等. 熔渗制备B4C-MgSi复合材料的熔渗动力学、微观结构及力学性能[J]. 粉末冶金材料科学与工程, 2018,23(3):252-256.
【16】刘跃进,王晓刚,王雪莹.粒度对β/α复合SiC陶瓷的性能影响研究[J].人工晶体学报,2019,48(2):253-257.
【17】钟长荣,毕松,苏勋家,等.层状复合陶瓷的增韧与设计研究进展[J].耐火材料,2007,41(4):302-306.
【18】黄勇,李翠伟,汪长安,等.陶瓷强韧化新纪元:仿生结构设计[J].材料导报,2000,14(8):8-11.
【19】李冬云,乔冠军,金志浩.SiC/C层状陶瓷的断裂行为研究[J].稀有金属材料与工程,2003,32(8):635-638.
【20】LI C W,WANG C G,HUANG Y,et al.Effects of sintering aids on the microstructure and mechanical properties of laminated Si3N4/BN ceramics[J].Materials Letters,2003,57(22/23):3473-3478.
【21】李冬云,杨辉,乔冠军,等.SiC/BN层状陶瓷的抗热震性能研究[J].材料科学与工程学报,2006,24(1):17-19.
【22】ZAN Q F,WANG C G,HUANG Y,et al.Effect of geometrical factors on the mechanical properties of Si3N4/BN multilayer ceramics[J].Ceramics International,2004,30(3):441-446.
【23】陈洪胜,王文先,李宇力,等.B4C/Al-Al层状复合材料的微观组织与力学性能[J].粉末冶金材料科学与工程,2016,21(1):146-153.
【24】WU C,XIE S H,LI Y K,et al.Effects of Al addition on the phase transformation and interfacial evolution in multilayer Ti-B4C composite[J].Ceramics International, 2018,44(4):4121-4125.
【25】YUE X Y,WANG J J,LI X M,et al.Microstructures and mechanical properties of a two-layer B4C/Al-B4C/TiB2 composite[J].Materials Science and Engineering:A, 2013,559:719-724.
【26】罗永明,潘伟,陈健,等.SiC/W层状复合材料力学性能与显微结构的研究[J].材料导报,2000,14(5):49-51.
【27】EL-SHAER Y,DERBY B.Modelling of R-curve behaviour in ceramic-metal laminates[J].Materials Science and Engineering:A, 2004,365(1/2):196-201.
【28】袁广江,罗永明,陈大明,等.SiC基层状复合材料界面层的选择[J].硅酸盐学报,2001,29(3):226-231.
【29】ZHANG J X,HUANG Z R,JIANG D L,et al.Preparation of titanium nitride/alumina laminate composites[J].Journal of the American Ceramic Society, 2004,85(5):1133-1138.
【30】WANG C A,HUANG Y,ZAN Q F,et al.Biomimetic structure design: A possible approach to change the brittleness of ceramics in nature[J].Materials Science and Engineering:C, 2000,11(1):9-12.
【31】LI C W,HUANG Y,WANG C A,et al.Mechanical properties and microstructure of laminated Si3N4+SiCw/BN+Al2O3 ceramics densified by spark plasma sintering[J].Materials Letters, 2002,57(2):336-342.
【32】苏盛彪,包亦望,杨建军.强界面陶瓷层状复合材料优化设计的最佳层厚比探讨[J].硅酸盐学报,2003,31(8):743-747.
【33】李冬云,乔冠军,金志浩.层状复合陶瓷材料的研究进展[J].无机材料学报,2002,17(1):10-16.
【34】张勋,刘书海,肖华平.冷冻铸造技术制备仿贝壳层状结构陶瓷复合材料研究进展[J].材料导报,2017,31(13):99-112.
【35】CLEGG W J,KENDALL K,ALFORD N M,et al.A simple way to make tough ceramics[J].Nature, 1990,347(6292):455-457.
【36】CLEGG W J.Design of ceramic laminates for structural applications[J].Materials Science and Technology, 1998,14(6):483-495.
【37】REYNAUD C,THÉVENOT F,CHARTIER T,et al.Mechanical properties and mechanical behaviour of SiC dense-porous laminates[J].Journal of the European Ceramic Society, 2005,25(5):589-597.
【38】TARIOLLE S,REYNAUD C,THÉVENOT F,et al.Preparation,microstructure and mechanical properties of SiC-SiC and B4C-B4C laminates[J].Journal of Solid State Chemistry, 2004,177(2):487-492.
【39】ZHANG L,KRSTIC V D.High toughness silicon carbide/graphite laminar composite by slip casting[J].Theoretical and Applied Fracture Mechanics, 1995,24(1):13-19.
【40】郑仕远,高永毅,郎悦.SiC/W层状复合材料力学性能及显微结构分析[J].机械工程材料,2000,24(6):13-15.
【41】李冬云,杨辉,乔冠军,等.弱层成分对SiC/BN层状陶瓷阻力行为的影响[J].复合材料学报,2006,23(2):110-114.
【42】解玉鹏,成来飞,张立同.SiCw/SiC层状结构陶瓷的制备及其应用[J].中国材料进展,2015,34(6):439-443.
【43】解玉鹏,成来飞,张立同.增强体含量对SiCw/SiC层状陶瓷复合材料强韧性的影响[J].复合材料学报,2016,33(12):2854-2859.
【44】TARIOLLE S,THÉVENOT F,CHARTIER T,et al.Properties of reinforced boron carbide laminar composites[J].Journal of the European Ceramic Society, 2005,25(16):3639-3647.
【45】刘维良,谈军,唐春宝,等.B4C/BN层状陶瓷复合材料的研究[J].稀有金属材料与工程,2008,37(增刊1):387-390.
【46】李冬云,乔冠军,金志浩.SiC/BN层状陶瓷耐损伤性能[J].复合材料学报,2003,20(6):21-25.
【47】李冬云,乔冠军,金志浩.SiC/BN层状陶瓷的阻力曲线行为[J].中国有色金属学报,2003,13(4):944-948.
【48】高永毅,焦群英,郑仕远.SiC-W层状复合材料增韧机理分析[J].中国农业大学学报,2002,7(2):53-56.
【2】任文科,高光发,朴春华,等.碳化硼陶瓷复合靶板抗侵彻性能实验研究[J].高压物理学报,2019,33(4):045104.
【3】李缨.碳化硅晶须及其陶瓷基复合材料[J].陶瓷,2007(8):39-42.
【4】DENG Y C,ZHANG Y M,ZHANG N L,et al.Preparation and characterization of pure SiC ceramics by high temperature physical vapor transport induced by seeding with nano SiC particles[J].Journal of Materials Science & Technology, 2019,35(12):2756-2760.
【5】潘登,李树丰,张鑫,等.B4C-W2B5复合陶瓷的原位反应制备及其强韧化机理[J].陶瓷学报,2019,40(4):451-457.
【6】肖汉宁,高朋召.高性能结构陶瓷及其应用[M].北京:化学工业出版社,2006.
【7】周玉.陶瓷材料学[M].北京:科学出版社,2004.
【8】江东亮.精细陶瓷材料[M].北京:中国物资出版社,2000:134-150.
【9】聂丹,王帅,邢鹏飞,等.碳化硼陶瓷的制备工艺及其应用现状[J].铁合金,2019,50(3):33-39.
【10】聂立芳,张玉军,魏红康.碳化硅晶须增韧陶瓷基复合材料的研究进展[J].山东陶瓷,2006,29(2):16-19.
【11】杨万利,代丽娜,樊振宁,等.PAS烧结SiC/h-BN复相陶瓷的韧性表征[J].材料导报,2019,33(8):1272-1275.
【12】曾凡,陈建军,姜敏,等.SiC纳米线增强反应烧结碳化硅陶瓷的性能研究[J].硅酸盐通报,2018,37(2):586-590.
【13】余小斌,孟江燕,范金娟,等.SiCf/SiC复合材料原位分析研究进展[J].失效分析与预防,2019,14(5):350-356.
【14】窦叔菊.高温陶瓷工艺学[M].沈阳:东北大学出版社,1994:217-220.
【15】邹志欢, 曾凡浩, 刘吉安,等. 熔渗制备B4C-MgSi复合材料的熔渗动力学、微观结构及力学性能[J]. 粉末冶金材料科学与工程, 2018,23(3):252-256.
【16】刘跃进,王晓刚,王雪莹.粒度对β/α复合SiC陶瓷的性能影响研究[J].人工晶体学报,2019,48(2):253-257.
【17】钟长荣,毕松,苏勋家,等.层状复合陶瓷的增韧与设计研究进展[J].耐火材料,2007,41(4):302-306.
【18】黄勇,李翠伟,汪长安,等.陶瓷强韧化新纪元:仿生结构设计[J].材料导报,2000,14(8):8-11.
【19】李冬云,乔冠军,金志浩.SiC/C层状陶瓷的断裂行为研究[J].稀有金属材料与工程,2003,32(8):635-638.
【20】LI C W,WANG C G,HUANG Y,et al.Effects of sintering aids on the microstructure and mechanical properties of laminated Si3N4/BN ceramics[J].Materials Letters,2003,57(22/23):3473-3478.
【21】李冬云,杨辉,乔冠军,等.SiC/BN层状陶瓷的抗热震性能研究[J].材料科学与工程学报,2006,24(1):17-19.
【22】ZAN Q F,WANG C G,HUANG Y,et al.Effect of geometrical factors on the mechanical properties of Si3N4/BN multilayer ceramics[J].Ceramics International,2004,30(3):441-446.
【23】陈洪胜,王文先,李宇力,等.B4C/Al-Al层状复合材料的微观组织与力学性能[J].粉末冶金材料科学与工程,2016,21(1):146-153.
【24】WU C,XIE S H,LI Y K,et al.Effects of Al addition on the phase transformation and interfacial evolution in multilayer Ti-B4C composite[J].Ceramics International, 2018,44(4):4121-4125.
【25】YUE X Y,WANG J J,LI X M,et al.Microstructures and mechanical properties of a two-layer B4C/Al-B4C/TiB2 composite[J].Materials Science and Engineering:A, 2013,559:719-724.
【26】罗永明,潘伟,陈健,等.SiC/W层状复合材料力学性能与显微结构的研究[J].材料导报,2000,14(5):49-51.
【27】EL-SHAER Y,DERBY B.Modelling of R-curve behaviour in ceramic-metal laminates[J].Materials Science and Engineering:A, 2004,365(1/2):196-201.
【28】袁广江,罗永明,陈大明,等.SiC基层状复合材料界面层的选择[J].硅酸盐学报,2001,29(3):226-231.
【29】ZHANG J X,HUANG Z R,JIANG D L,et al.Preparation of titanium nitride/alumina laminate composites[J].Journal of the American Ceramic Society, 2004,85(5):1133-1138.
【30】WANG C A,HUANG Y,ZAN Q F,et al.Biomimetic structure design: A possible approach to change the brittleness of ceramics in nature[J].Materials Science and Engineering:C, 2000,11(1):9-12.
【31】LI C W,HUANG Y,WANG C A,et al.Mechanical properties and microstructure of laminated Si3N4+SiCw/BN+Al2O3 ceramics densified by spark plasma sintering[J].Materials Letters, 2002,57(2):336-342.
【32】苏盛彪,包亦望,杨建军.强界面陶瓷层状复合材料优化设计的最佳层厚比探讨[J].硅酸盐学报,2003,31(8):743-747.
【33】李冬云,乔冠军,金志浩.层状复合陶瓷材料的研究进展[J].无机材料学报,2002,17(1):10-16.
【34】张勋,刘书海,肖华平.冷冻铸造技术制备仿贝壳层状结构陶瓷复合材料研究进展[J].材料导报,2017,31(13):99-112.
【35】CLEGG W J,KENDALL K,ALFORD N M,et al.A simple way to make tough ceramics[J].Nature, 1990,347(6292):455-457.
【36】CLEGG W J.Design of ceramic laminates for structural applications[J].Materials Science and Technology, 1998,14(6):483-495.
【37】REYNAUD C,THÉVENOT F,CHARTIER T,et al.Mechanical properties and mechanical behaviour of SiC dense-porous laminates[J].Journal of the European Ceramic Society, 2005,25(5):589-597.
【38】TARIOLLE S,REYNAUD C,THÉVENOT F,et al.Preparation,microstructure and mechanical properties of SiC-SiC and B4C-B4C laminates[J].Journal of Solid State Chemistry, 2004,177(2):487-492.
【39】ZHANG L,KRSTIC V D.High toughness silicon carbide/graphite laminar composite by slip casting[J].Theoretical and Applied Fracture Mechanics, 1995,24(1):13-19.
【40】郑仕远,高永毅,郎悦.SiC/W层状复合材料力学性能及显微结构分析[J].机械工程材料,2000,24(6):13-15.
【41】李冬云,杨辉,乔冠军,等.弱层成分对SiC/BN层状陶瓷阻力行为的影响[J].复合材料学报,2006,23(2):110-114.
【42】解玉鹏,成来飞,张立同.SiCw/SiC层状结构陶瓷的制备及其应用[J].中国材料进展,2015,34(6):439-443.
【43】解玉鹏,成来飞,张立同.增强体含量对SiCw/SiC层状陶瓷复合材料强韧性的影响[J].复合材料学报,2016,33(12):2854-2859.
【44】TARIOLLE S,THÉVENOT F,CHARTIER T,et al.Properties of reinforced boron carbide laminar composites[J].Journal of the European Ceramic Society, 2005,25(16):3639-3647.
【45】刘维良,谈军,唐春宝,等.B4C/BN层状陶瓷复合材料的研究[J].稀有金属材料与工程,2008,37(增刊1):387-390.
【46】李冬云,乔冠军,金志浩.SiC/BN层状陶瓷耐损伤性能[J].复合材料学报,2003,20(6):21-25.
【47】李冬云,乔冠军,金志浩.SiC/BN层状陶瓷的阻力曲线行为[J].中国有色金属学报,2003,13(4):944-948.
【48】高永毅,焦群英,郑仕远.SiC-W层状复合材料增韧机理分析[J].中国农业大学学报,2002,7(2):53-56.
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