Effect of SO32- Concentration on Corrosion Behavior of 5052 AluminumAlloy in Alternating Electric Field with Cyclic Wet-Dry Condition
摘 要
采用pH为4.0的含氯腐蚀液及400 kV·m-1交变电场模拟工业输电环境,研究了SO32-浓度(0.005,0.01,0.02,0.05,0.1 mol·L-1)对5052铝合金在交变电场中干湿交替环境下腐蚀行为的影响。结果表明:随着SO32-浓度增加,5052铝合金的腐蚀质量增加、自腐蚀电位、溶液电阻、电荷转移电阻先增大后减小,自腐蚀电流密度、腐蚀速率则先减小后增大;当SO32-浓度为0.005~0.01 mol·L-1时,合金以点蚀为主,点蚀坑内开始出现成分为Al2O3、Al2O3·3H2O的龟裂状腐蚀产物;随SO32-浓度继续增加,合金表面腐蚀坑减少,与基体结合紧密的龟裂状腐蚀产物增多;SO32-浓度为0.02 mol·L-1时,合金腐蚀速率最小,腐蚀程度最低。
Abstract
The corrosive solution containing chlorine with pH 4.0 and 400 kV·m-1 alternating electric field were used to simulate the industrial transmission environment. The effect of SO32- concentration (0.005,0.010,0.020,0.050,0.100 mol·L-1) on corrosion behavior of 5052 aluminum alloy in alternating electric field with cyclic wet-dry condition was studied. The results show that with the increase of SO32- concentration, the corrosion mass increment, free-corrosion potential, solution resistance, and charge transfer resistance of 5052 aluminum alloy increased first and then decreased, while the free-corrosion current density and corrosion rate decreased first and then increased. When the concentration of SO32- was from 0.005 to 0.020 mol·L-1, the main corrosion was the pitting corrosion, and cracked corrosion products of Al2O3 and Al2O3·3H2O began to appear in pitting pits. When the concentration of SO32- continued to increase, the corrosion pits on the surface of the alloy were reduced, and the cracked corrosion products being tightly bound to the substrate with composition of Al2O3 · 3H2O were increased. The corrosion rate and degree of the alloy were both the smallest when the concentration of SO32- was 0.020 mol·L-1.
中图分类号 TG172.3 DOI 10.11973/jxgccl202006004
所属栏目 试验研究
基金项目 国家电网有限公司总部科技项目(52130417002K)
收稿日期 2020/2/21
修改稿日期 2020/4/29
网络出版日期
作者单位点击查看
备注林胤戎(1999-),男,福建福州人,本科生
引用该论文: LIN Yinrong,LIN Tianshun,ZHUANG Jianhuang,SHAO Yanqun. Effect of SO32- Concentration on Corrosion Behavior of 5052 AluminumAlloy in Alternating Electric Field with Cyclic Wet-Dry Condition[J]. Materials for mechancial engineering, 2020, 44(6): 16~20
林胤戎,林天顺,庄建煌,邵艳群. SO32-浓度对5052铝合金在交变电场、干湿交替条件下腐蚀行为的影响[J]. 机械工程材料, 2020, 44(6): 16~20
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参考文献
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【3】MANSFELD F,LIN S,KWIATKOWSKI L.The effects of process parameters on alternating voltage (AV) passivation of 304 stainless steel[J].Corrosion Science, 1993,34(12):2045-2058.
【4】李运超,严川伟,段红平,等.交变电场结合后处理技术对点蚀破坏电极的修复机理[J].金属学报,2003, 39(6): 639-643.
【5】LORENZ W J,MANSFELD F.Determination of corrosion rates by electrochemical DC and AC methods[J].Corrosion Science, 1981,21(9/10):647-672.
【6】蔡建宾,蔡振才,庄建煌,等.高压直流电场对5052系铝合金在3%NaCl溶液中干湿交替加速腐蚀行为的影响[J]. 机械工程材料,2020,44(3):18-24.
【7】陈云翔,林德源,洪毅成,等.35 kV架空输电线路钢芯铝绞线内层铝股线的腐蚀失效分析[J].腐蚀与防护,2015,36(6):594-598.
【8】夏晓健,金焱,乔汉文,等.输变电设备腐蚀状况调查与分析[J].腐蚀科学与防护技术,2019,31(2):121-127.
【9】刘海萍,邹忠利,毕四富.铝合金、镁合金表面强化技术[M].北京:化学工业出版社,2019.
【10】陈云翔,林德源,洪毅成,等.福建某海岛架空输电钢芯铝绞线的失效分析[J].热处理技术与装备,2014,35(6):52-56.
【11】杨九霄,邵艳群,陈云翔,等.某海岛35 kV南日#81-#82外层铝股线的腐蚀失效分析[J].测试技术学报,2015,29(5):455-460.
【12】陈玉树.电网设备金属材料手册[M].北京:中国电力出版社,2019.
【13】陈彬彬, 王宏, 郑秋萍, 等.福建省区域酸雨特征及成因分析[J]. 气象与环境学报, 2016, 32(4):70-76.
【14】邵艳群,何建,郭洁,等. 高压电场环境下进行干湿交替加速腐蚀的试验装置:201822093115.6[P].2018-12-13.
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