金属表面缓蚀组装技术的研究进展
Progress of Research on Inhibitor Assembling Technology on Metal Surface
摘 要
就近年来缓蚀组装技术的若干热点研究方向进行了归纳总结，并对其存在问题及发展前景进行了探讨与展望。主要内容包括：自组装膜结构的调控与优化；多层次可控组装；多功能智能化自组装；自组装膜的表征及理论模拟计算问题；缓蚀组装技术绿色化。
可控组装
绿色缓蚀
智能缓蚀
self-assembly
controllable assembly
green inhibition
smart inhibition
Abstract
In this paper, the hot research topics in inhibitor assembling technology in recent years are summarized, the existing problems and prospect are also discussed. The main contents include: the regulation and optimization of self-assembled film formation; the multiple and controllable self-assembly; the multifunctional and smart self-assembly; the characterization of self-assembled film and theoretical simulated calculation; the greening of inhibitor self-assembling technology.
中图分类号 TG174.4 DOI 10.11973/fsyfh-202007001
所属栏目 绿色缓蚀剂
基金项目 国家自然科学基金资助项目（51571140；21776172）
收稿日期 2019/9/25
修改稿日期
网络出版日期
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引用该论文: LI Jin,SHI Cheng,ZHANG Daquan,CHEN Donghui. Progress of Research on Inhibitor Assembling Technology on Metal Surface[J]. Corrosion & Protection, 2020, 41(7): 1
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参考文献
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【28】LI J,CHEN D H,ZHANG D Q,et al. Preparation of triazole compounds via click chemistry reaction and formation of the protective self-assembled membrane against copper corrosion[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2018,550:145-154.
【29】LI J,ZHANG D Q,ZHANG K,et al. A novel process for copper protection in the simulated industrial cooling water based on click synthesis and self-assembling method[J]. Materials and Corrosion,2019,70(11):1964-1976.
【30】YU Y Z,WANG Y Z,LI J,et al. In situ click-assembling monolayers on copper surface with enhanced corrosion resistance[J]. Corrosion Science,2016,113:133-144.
【31】SHI C,WANG Y Z,YU Y Z,et al. The role of cuprous ions on the click-assembled triazole films against copper corrosion[J]. Corrosion Science,2018,145:100-108.
【32】WANG Y Z,YU Y Z,ZHANG J,et al. Click-assembling triazole membrane on copper surface via one-step or two-steps and their corrosion inhibition performance[J]. Applied Surface Science,2018,427:1120-1128.
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【35】LI J,ZHANG D Q,SHI C,et al. Click-assembling film modified on different copper substrates and their comprehensive performance[J]. Applied Surface Science,2019,493:336-350.
【36】YANG Y,URBAN M W. Self-healing polymeric materials[J]. Chemical Society Reviews,2013,42(17):7446.
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【39】ZHANG D Q,YUAN T H,WEI G A,et al. Preparation of self-healing hydrophobic coating on AA6061 alloy surface and its anti-corrosion property[J]. Journal of Alloys and Compounds,2019,774:495-501.
【40】ZHANG D Q,LIU P H,GAO L X,et al. Photosensitive self-assembled membrane of cysteine against copper corrosion[J]. Materials Letters,2011,65(11):1636-1638.
【41】李瑾,张大全,陈东辉,等. 荧光标记铜材料在模拟冷却水中的耐蚀性能研究[J]. 工业水处理,2020,40(4):28-34.
【42】ZHANG J,LIU Z,HAN G C,et al. Inhibition of copper corrosion by the formation of Schiff base self-assembled monolayers[J]. Applied Surface Science,2016,389:601-608.
【43】XU F L,YANG J D,QIU R,et al. Thiol self-assemble layer as inhibitor to protect B10 from seawater corrosion[J]. Progress in Organic Coatings,2016,97:82-90.
【44】PETROVIC MIHAJLOVIC M B,RADOVANOVIC M B,TASIC Ž Z,et al. Imidazole based compounds as copper corrosion inhibitors in seawater[J]. Journal of Molecular Liquids,2017,225:127-136.
【45】OBAYES H R,AL-AMIERY A A,ALWAN G H,et al. Sulphonamides as corrosion inhibitor:Experimental and DFT studies[J]. Journal of Molecular Structure,2017,1138:27-34.
【46】MOURYA P,BANERJEE S,SINGH M M. Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor[J]. Corrosion Science,2014,85:352-363.
【47】GECE G. The use of quantum chemical methods in corrosion inhibitor studies[J]. Corrosion Science,2008,50(11):2981-2992.
【48】BREEDON M,PER M C,COLE I S,et al. Molecular ionization and deprotonation energies as indicators of functional coating performance[J]. J Mater Chem A,2014,2(39):16660-16668.
【49】WINKLER D A,BREEDON M,HUGHES A E,et al. Towards chromate-free corrosion inhibitors:structure-property models for organic alternatives[J]. Green Chem,2014,16(6):3349-3357.
【50】BAGHERZADEH M,JABERINIA F. Electrochemical study of Monel alloy corrosion in hydrochloric acid solution and pyrrolidine dithiocarboxylate self-assembled monolayers as its corrosion protector[J]. Journal of Alloys and Compounds,2018,750:677-686.
【51】KURNIAWAN F,MADURANI K A. Electrochemical and optical microscopy study of red pepper seed oil corrosion inhibition by self-assembled monolayers (SAM) on 304 SS[J]. Progress in Organic Coatings,2015,88:256-262.
【52】NASERI E,HAJISAFARI M,KOSARI A,et al. Inhibitive effect of Clopidogrel as a green corrosion inhibitor for mild steel;statistical modeling and quantum Monte Carlo simulation studies[J]. Journal of Molecular Liquids,2018,269:193-202.
【2】BEHPOUR M,GHOREISHI S M,KHAYATKASHANI M,et al. Green approach to corrosion inhibition of mild steel in two acidic solutions by the extract of Punica granatum peel and main constituents[J]. Materials Chemistry and Physics,2012,131(3):621-633.
【3】GRASSINO A N,HALAMBEK J,DJAKOVIC S,et al. Utilization of tomato peel waste from canning factory as a potential source for pectin production and application as tin corrosion inhibitor[J]. Food Hydrocolloids,2016,52:265-274.
【4】李瑾,张大全. 缓蚀膜自组装技术的研究与发展[J]. 腐蚀与防护,2010,31(3):183-187.
【5】张大全. 缓蚀技术研究进展及在能源工业中的应用[J]. 上海电力学院学报,2013,29(4):355-363.
【6】QIANG Y J,FU S L,ZHANG S T,et al. Designing and fabricating of single and double alkyl-chain indazole derivatives self-assembled monolayer for corrosion inhibition of copper[J]. Corrosion Science,2018,140:111-121.
【7】YAN R,GAO X,LV D,et al. A study on the differences in morphology and corrosion resistance performance between two different bis (2-ethylhexyl) phosphate self-assembled thin films prepared on an iron substrate in water and ethanol solvents[J]. RSC Advances,2016,6(61):55936-55945.
【8】王宇,林海昕,丁松园,等. 关于可控组装的一些思考(一)——从催化到催组装[J]. 中国科学:化学,2012,42(4):525-547.
【9】MURUGAN P,KRISHNAMURTHY M,JAISANKAR S N,et al. Controlled decoration of the surface with macromolecules:polymerization on a self-assembled monolayer (SAM)[J]. Chemical Society Reviews,2015,44(10):3212-3243.
【10】SCHREIBER F,EBERHARDT A,LEUNG T Y B,et al. Adsorption mechanisms,structures,and growth regimes of an archetypal self-assembling system:Decanethiol on Au(111)[J]. Physical Review B,1998,57(19):12476.
【11】FINKLEA H O. Electrochemistry of organized monolayers of thiols and related molecules on electrodes[J]. Electroanalytical Chemistry,1996,19:109-335.
【12】VERICAT C,VELA M E,BENITEZ G,et al. Self-assembled monolayers of thiols and dithiols on gold:new challenges for a well-known system[J]. Chemical Society Reviews,2010,39(5):1805.
【13】SUBRAMANIAN S,SAMPATH S. Enhanced thermal stability and structural ordering in short chain n-alkanethiol monolayers on gold probed by vibrational spectroscopy and EQCM[J]. Analytical and Bioanalytical Chemistry,2007,388(1):135-145.
【14】HASAN A,PANDEY L M. Kinetic studies of attachment and re-orientation of octyltriethoxysilane for formation of self-assembled monolayer on a silica substrate[J]. Materials Science and Engineering:C,2016,68:423-429.
【15】MA C X,HARRIS J M. Surface-enhanced Raman scattering study of the kinetics of self-assembly of carboxylate-terminatedn-alkanethiols on silver[J]. Langmuir,2012,28(5):2628-2636.
【16】PASTERNACK R M,RIVILLON AMY S,CHABAL Y J. Attachment of 3-(aminopropyl) triethoxysilane on silicon oxide surfaces:dependence on solution temperature[J]. Langmuir,2008,24(22):12963-12971.
【17】AISSAOUI N,BERGAOUI L,LANDOULSI J,et al. Silane layers on silicon surfaces:mechanism of interaction,stability,and influence on protein adsorption[J]. Langmuir,2012,28(1):656-665.
【18】MO Y F,ZHU M,BAI M W. Preparation and nano/microtribological properties of perfluorododecanoic acid (PFDA)-3-aminopropyltriethoxysilane (APS) self-assembled dual-layer film deposited on silicon[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2008,322(1/2/3):170-176.
【19】张漫路,赵景茂. 缓蚀剂协同效应与协同机理的研究进展[J]. 中国腐蚀与防护学报,2016,36(1):1-10.
【20】ZHANG D Q,WU H,GAO L X. Synergistic inhibition effect of l-phenylalanine and rare earth Ce(IV) ion on the corrosion of copper in hydrochloric acid solution[J]. Materials Chemistry and Physics,2012,133(2/3):981-986.
【21】YU Y Z,ZHANG D Q,ZENG H J,et al. Synergistic effects of sodium lauroyl sarcosinate and glutamic acid in inhibition assembly against copper corrosion in acidic solution[J]. Applied Surface Science,2015,355:1229-1237.
【22】刘培慧,高立新,张大全. 铜表面苯丙氨酸和色氨酸复合自组装膜的缓蚀性能研究[J]. 中国腐蚀与防护学报,2012,32(2):163-167.
【23】YANG W J,LI T Q,ZHOU H H,et al. Electrochemical and anti-corrosion properties of octadecanethiol and benzotriazole binary self-assembled monolayers on copper[J]. Electrochimica Acta,2016,220:245-251.
【24】GONZÁLEZ-OLVERA R,ESPINOZA-VáZQUEZ A,NEGRóN-SILVA G,et al. Multicomponent click synthesis of new 1,2,3-triazole derivatives of pyrimidine nucleobases:promising acidic corrosion inhibitors for steel[J]. Molecules,2013,18(12):15064-15079.
【25】NEGRóN-SILVA G,GONZáLEZ-OLVERA R,ANGELES-BELTRáN D,et al. Synthesis of new 1,2,3-triazole derivatives of uracil and thymine with potential inhibitory activity against acidic corrosion of steels[J]. Molecules,2013,18(4):4613-4627.
【26】DENG Q,HE X P,SHI H W,et al. Concise CuI-catalyzed azide-alkyne 1,3-dipolar cycloaddition reaction ligation remarkably enhances the corrosion inhibitive potency of natural amino acids for mild steel in HCl[J]. Industrial & Engineering Chemistry Research,2012,51(21):7160-7169.
【27】施成,高立新,张大全. 点击化学反应及其在材料保护领域的应用[J]. 表面技术,2018,47(10):1-10.
【28】LI J,CHEN D H,ZHANG D Q,et al. Preparation of triazole compounds via click chemistry reaction and formation of the protective self-assembled membrane against copper corrosion[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2018,550:145-154.
【29】LI J,ZHANG D Q,ZHANG K,et al. A novel process for copper protection in the simulated industrial cooling water based on click synthesis and self-assembling method[J]. Materials and Corrosion,2019,70(11):1964-1976.
【30】YU Y Z,WANG Y Z,LI J,et al. In situ click-assembling monolayers on copper surface with enhanced corrosion resistance[J]. Corrosion Science,2016,113:133-144.
【31】SHI C,WANG Y Z,YU Y Z,et al. The role of cuprous ions on the click-assembled triazole films against copper corrosion[J]. Corrosion Science,2018,145:100-108.
【32】WANG Y Z,YU Y Z,ZHANG J,et al. Click-assembling triazole membrane on copper surface via one-step or two-steps and their corrosion inhibition performance[J]. Applied Surface Science,2018,427:1120-1128.
【33】施成. 点击组装缓蚀膜对铜的保护机理研究[D]. 上海:上海电力大学,2019.
【34】SHUBHA H N,VENKATESHA T V,PAVITHRA M K,et al. Surface modification of mild steel by a self-assembled cetyl-trimethyl ammonium bromide (CTAB) monolayer:Evaluation of its corrosion protection property[J]. Progress in Organic Coatings,2016,90:267-276.
【35】LI J,ZHANG D Q,SHI C,et al. Click-assembling film modified on different copper substrates and their comprehensive performance[J]. Applied Surface Science,2019,493:336-350.
【36】YANG Y,URBAN M W. Self-healing polymeric materials[J]. Chemical Society Reviews,2013,42(17):7446.
【37】王巍,王鑫,刘晓杰,等. 海洋环境中自修复涂层研究进展[J]. 装备环境工程,2018,15(10):89-97.
【38】FAN,ZHOU C Y,WANG X,et al. Layer-by-layer assembly of a self-healing anticorrosion coating on magnesium alloys[J]. ACS Applied Materials & Interfaces,2015,7(49):27271-27278.
【39】ZHANG D Q,YUAN T H,WEI G A,et al. Preparation of self-healing hydrophobic coating on AA6061 alloy surface and its anti-corrosion property[J]. Journal of Alloys and Compounds,2019,774:495-501.
【40】ZHANG D Q,LIU P H,GAO L X,et al. Photosensitive self-assembled membrane of cysteine against copper corrosion[J]. Materials Letters,2011,65(11):1636-1638.
【41】李瑾,张大全,陈东辉,等. 荧光标记铜材料在模拟冷却水中的耐蚀性能研究[J]. 工业水处理,2020,40(4):28-34.
【42】ZHANG J,LIU Z,HAN G C,et al. Inhibition of copper corrosion by the formation of Schiff base self-assembled monolayers[J]. Applied Surface Science,2016,389:601-608.
【43】XU F L,YANG J D,QIU R,et al. Thiol self-assemble layer as inhibitor to protect B10 from seawater corrosion[J]. Progress in Organic Coatings,2016,97:82-90.
【44】PETROVIC MIHAJLOVIC M B,RADOVANOVIC M B,TASIC Ž Z,et al. Imidazole based compounds as copper corrosion inhibitors in seawater[J]. Journal of Molecular Liquids,2017,225:127-136.
【45】OBAYES H R,AL-AMIERY A A,ALWAN G H,et al. Sulphonamides as corrosion inhibitor:Experimental and DFT studies[J]. Journal of Molecular Structure,2017,1138:27-34.
【46】MOURYA P,BANERJEE S,SINGH M M. Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor[J]. Corrosion Science,2014,85:352-363.
【47】GECE G. The use of quantum chemical methods in corrosion inhibitor studies[J]. Corrosion Science,2008,50(11):2981-2992.
【48】BREEDON M,PER M C,COLE I S,et al. Molecular ionization and deprotonation energies as indicators of functional coating performance[J]. J Mater Chem A,2014,2(39):16660-16668.
【49】WINKLER D A,BREEDON M,HUGHES A E,et al. Towards chromate-free corrosion inhibitors:structure-property models for organic alternatives[J]. Green Chem,2014,16(6):3349-3357.
【50】BAGHERZADEH M,JABERINIA F. Electrochemical study of Monel alloy corrosion in hydrochloric acid solution and pyrrolidine dithiocarboxylate self-assembled monolayers as its corrosion protector[J]. Journal of Alloys and Compounds,2018,750:677-686.
【51】KURNIAWAN F,MADURANI K A. Electrochemical and optical microscopy study of red pepper seed oil corrosion inhibition by self-assembled monolayers (SAM) on 304 SS[J]. Progress in Organic Coatings,2015,88:256-262.
【52】NASERI E,HAJISAFARI M,KOSARI A,et al. Inhibitive effect of Clopidogrel as a green corrosion inhibitor for mild steel;statistical modeling and quantum Monte Carlo simulation studies[J]. Journal of Molecular Liquids,2018,269:193-202.
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