Effect of Surface Treatment on Wear and Corrosion Resistance of Zr-Sn-Nb Alloy
摘 要
对Zr-Sn-Nb合金管材进行了喷丸和微弧氧化处理,采用显微硬度计、微动磨损装置和静态高压釜对表面处理前后试样的显微硬度、耐磨损和耐蚀性进行评价。结果表明:与未处理Zr-Sn-Nb合金基体试样相比,喷丸和微弧氧化处理使试样的表面显微硬度分别提高15%和60%,磨损体积降低6%和65%,而且在360 ℃/18.6 MPa去离子水和360 ℃/18.6 MPa/0.01 mol/L LiOH水溶液中的耐蚀性也有所提高。相对表面喷丸处理,微弧氧化更能提高Zr-Sn-Nb合金的表面硬度、耐磨损性能以及耐蚀性。
Abstract
Zr-Sn-Nb alloy tubes were treated by shot peening and micro-arc oxidation. Microhardness tester, fretting wear device and static autoclave were used to evaluate the microhardness, wear resistance and corrosion resistance of the samples before and after surface treatment. The results show that, compared with the untreated Zr-Sn-Nb alloy matrix samples, shot peening and micro-arc oxidation treatment increased the surface microhardness of the samples by 15% and 60%, and reduced the wear volume by 6% and 65%, respectively. And after surface treatment, the corrosion resistance of the samples in 360 ℃/18.6 MPa deionized water and 360 ℃/18.6 MPa/0.01 mol/L LiOH aqueous solution was also improved. Micro-arc oxidation was more effective than shot peening in improving the hardness, wear resistance as well as concurrent corrosion resistance of Zr-Sn-Nb alloy.
中图分类号 TL341 DOI 10.11973/fsyfh-202009005
所属栏目 核电设备的腐蚀与防护
基金项目 大型先进压水堆核电站重大专项(2017ZX06002005)
收稿日期 2020/5/15
修改稿日期
网络出版日期
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引用该论文: ZENG Qifeng,CHEN Fuliang,CHEN Lei,LI Cong,LU Junqiang,ZHOU Yunqing. Effect of Surface Treatment on Wear and Corrosion Resistance of Zr-Sn-Nb Alloy[J]. Corrosion & Protection, 2020, 41(9): 27
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参考文献
【1】吴华,范洪远,应诗浩,等. 表面处理对锆合金性能的影响[J]. 金属热处理,2006,31(1):17-19.
【2】赵文金,苗志,蒋宏曼,等. 表面处理对Zr-4合金抗疖状腐蚀性能的影响[J]. 稀有金属,1999,23(6):458-460.
【3】赵文金,苗志,蒋有荣,等. 预生氧化膜处理对锆-4包壳疖状腐蚀的影响[J]. 稀有金属,2000,24(2):150-153.
【4】张向宇,白新德. 锆合金表面改性研究进展[J]. 稀有金属材料与工程,2005,34(6):841-844.
【5】石明华,张喜燕,李忠奎,等. 喷丸处理Zr-4合金氧化膜组织和氧化动力学研究[J]. 稀有金属材料与工程,2009,38(7):1288-1291.
【6】张喜燕,朱玉涛,叶林凤,等. Zr-4合金表面变形纳米结构TEM研究[J]. 稀有金属材料与工程,2009,38(3):506-509.
【7】张聪惠,兰新哲,赵西成,等. 机械研磨处理Zr-4合金表面纳米化研究[J]. 稀有金属材料与工程,2010,39(3):511-514.
【8】孙彩云. Zr的晶粒细化和力学性能[D]. 太原:太原理工大学,2005.
【9】吴华. Zr-4合金表面Nb合金化研究[D]. 成都:四川大学,2006.
【10】CHENG Y L,WU F,DONG J L,et al. Comparison of plasma electrolytic oxidation of zirconium alloy in silicate and aluminate-based electrolytes and wear properties of the resulting coatings[J]. Electrochimica Acta,2012,85:25-32.
【11】SANDHYARANI M,ASHFAQ M,ARUNNELLAIAPPAN T,et al. Effect of electrical parameters on morphology and in-vitro corrosion resistance of plasma electrolytic oxidized films formed on zirconium[J]. Surface & Coatings Technology,2015,269:286-294.
【12】CHEN Y,NIE X,NORTHWOOD D O. Investigation of plasma electrolytic oxidation (PEO) coatings on a Zr-2.5Nb alloy using high temperature/pressure autoclave and tribological tests[J]. Surface & Coatings Technology,2010,205:1774-1782.
【13】CENGIZ S,GENCER Y. The characterization of the oxide based coating synthesized on pure zirconium by plasma electrolytic oxidation[J]. Surface & Coatings Technology,2014,242:132-140.
【14】张岱岚,白新德,李娟,等. Zr-Nb合金的微弧阳极氧化表面改性[J]. 稀有金属材料与工程,2007,36(6):1085-1087.
【15】张岱岚,白新德,陈宝山,等. Zr-4合金的微弧氧化研究[J]. 稀有金属材料与工程,2003,32(8):658-661.
【16】LAI P,ZHANG H,ZHANG L F,et al. Effect of micro-arc oxidation on fretting wear behavior of zirconium alloy exposed to high temperature water[J]. Wear,2019,424/425:53-61.
【17】ZHANG L F,LAI P,LIU Q D,et al. Fretting wear behavior of zirconium alloy in B-Li water at 300℃[J]. Journal of Nuclear Materials,2018,499:401-409.
【18】XIN L,YANG B B,WANG Z H,et al. Effect of normal force on fretting wear behavior and mechanism of alloy 690TT in high temperature water[J]. Wear,2016,368/369:210-218.
【2】赵文金,苗志,蒋宏曼,等. 表面处理对Zr-4合金抗疖状腐蚀性能的影响[J]. 稀有金属,1999,23(6):458-460.
【3】赵文金,苗志,蒋有荣,等. 预生氧化膜处理对锆-4包壳疖状腐蚀的影响[J]. 稀有金属,2000,24(2):150-153.
【4】张向宇,白新德. 锆合金表面改性研究进展[J]. 稀有金属材料与工程,2005,34(6):841-844.
【5】石明华,张喜燕,李忠奎,等. 喷丸处理Zr-4合金氧化膜组织和氧化动力学研究[J]. 稀有金属材料与工程,2009,38(7):1288-1291.
【6】张喜燕,朱玉涛,叶林凤,等. Zr-4合金表面变形纳米结构TEM研究[J]. 稀有金属材料与工程,2009,38(3):506-509.
【7】张聪惠,兰新哲,赵西成,等. 机械研磨处理Zr-4合金表面纳米化研究[J]. 稀有金属材料与工程,2010,39(3):511-514.
【8】孙彩云. Zr的晶粒细化和力学性能[D]. 太原:太原理工大学,2005.
【9】吴华. Zr-4合金表面Nb合金化研究[D]. 成都:四川大学,2006.
【10】CHENG Y L,WU F,DONG J L,et al. Comparison of plasma electrolytic oxidation of zirconium alloy in silicate and aluminate-based electrolytes and wear properties of the resulting coatings[J]. Electrochimica Acta,2012,85:25-32.
【11】SANDHYARANI M,ASHFAQ M,ARUNNELLAIAPPAN T,et al. Effect of electrical parameters on morphology and in-vitro corrosion resistance of plasma electrolytic oxidized films formed on zirconium[J]. Surface & Coatings Technology,2015,269:286-294.
【12】CHEN Y,NIE X,NORTHWOOD D O. Investigation of plasma electrolytic oxidation (PEO) coatings on a Zr-2.5Nb alloy using high temperature/pressure autoclave and tribological tests[J]. Surface & Coatings Technology,2010,205:1774-1782.
【13】CENGIZ S,GENCER Y. The characterization of the oxide based coating synthesized on pure zirconium by plasma electrolytic oxidation[J]. Surface & Coatings Technology,2014,242:132-140.
【14】张岱岚,白新德,李娟,等. Zr-Nb合金的微弧阳极氧化表面改性[J]. 稀有金属材料与工程,2007,36(6):1085-1087.
【15】张岱岚,白新德,陈宝山,等. Zr-4合金的微弧氧化研究[J]. 稀有金属材料与工程,2003,32(8):658-661.
【16】LAI P,ZHANG H,ZHANG L F,et al. Effect of micro-arc oxidation on fretting wear behavior of zirconium alloy exposed to high temperature water[J]. Wear,2019,424/425:53-61.
【17】ZHANG L F,LAI P,LIU Q D,et al. Fretting wear behavior of zirconium alloy in B-Li water at 300℃[J]. Journal of Nuclear Materials,2018,499:401-409.
【18】XIN L,YANG B B,WANG Z H,et al. Effect of normal force on fretting wear behavior and mechanism of alloy 690TT in high temperature water[J]. Wear,2016,368/369:210-218.
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