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氨基改性SBA-15介孔分子筛固定化双酶/环氧复合涂层的制备及其耐蚀性
          
Preparation of Amino-Modified SBA-15 Mesoporous Molecular Sieves Co-immobilized Double Enzymes/Epoxy Composite Coating and Its Corrosion Resistance

摘    要
制备了氨基改性的SBA-15介孔分子筛,以氨基改性SBA-15介孔分子筛为载体分别对溶菌酶和脂肪酶进行固定化,并优化固定化条件。通过正交试验确定氨基改性SBA-15介孔分子筛共固定化双酶的最佳条件。将该共固定化双酶添加到环氧树脂中制备复合涂层。采用极化曲线法和电化学阻抗法分析该复合涂层的耐蚀性。结果表明:共固定化双酶的最佳条件为溶菌酶质量浓度0.2 g/L、溶菌酶固定化时间6 h、脂肪酶质量浓度为0.8 g/L,脂肪酶固定化时间10 h;复合涂层中添加1.5%(质量分数)的共固定化双酶时,其耐腐蚀性最佳,缓蚀率可达96.61%。
标    签 氨基改性SBA-15   固定化   复合涂层   耐蚀性   缓蚀率   amino-modified SBA-15   immobilization   composite coating   corrosion resistance   inhibition efficiency  
 
Abstract
Amino-modified SBA-15 mesoporous molecular sieves were prepared first. The amino-modified SBA-15 mesoporous molecular sieve was used as a carrier to immobilize lysozyme and lipase respectively, and the immobilization conditions were optimized. The optimal conditions for co-immobilization of double enzymes on amino-modified SBA-15 mesoporous molecular sieve were determined by orthogonal test. The co-immobilized double enzymes were added to epoxy resin to prepare a composite coating. Polarization curve method and electrochemical impedance method were used to analyze the corrosion resistance of the composite coating. The results show that the optimal conditions of co-immobilization of double enzymes were as following: the mass fraction of lysozyme was 0.2 g/L and the time of immobilizing lysozyme was 6 h, the mass fraction of lipase was 0.8 g/L and the time of immobilizing lipase was 10 h. The composite coating added with 1.5% (mass fraction) immobilized double enzymes had the best corrosion resistance, its corrosion inhibition efficiency hit 96.61%.

中图分类号 TQ085   DOI 10.11973/fsyfh-202012002

 
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所属栏目 试验研究

基金项目 山东省自然科学基金(ZR2017MEM013)

收稿日期 2018/12/16

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引用该论文: CHEN Xiaorui,LU Xin,SUN Junzhi,LIU Fang,ZHAO Chaocheng. Preparation of Amino-Modified SBA-15 Mesoporous Molecular Sieves Co-immobilized Double Enzymes/Epoxy Composite Coating and Its Corrosion Resistance[J]. Corrosion & Protection, 2020, 41(12): 7


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