Microstructure and Tensile Properties of Heat Affected Zone bySimulation Welding of Service-Degraded HP40Nb Furnace Tube
摘 要
通过焊接热模拟,研究了服役劣化HP40Nb制氢转化炉管热影响区的显微组织和拉伸性能。结果表明:服役劣化炉管的奥氏体晶界上存在粗大、连续的G相和富铬M23C6碳化物;在峰值温度(1 100~1 200℃)下热循环后,析出相仍主要为G相和M23C6碳化物,二者含量随峰值温度升高而减少;当峰值温度升至1 250℃时,析出相主要为M23C6和NbC相;在较低峰值温度(950~1 050℃)下所得热影响区试样的抗拉强度和断后伸长率均较低;峰值温度高于1 100℃时,抗拉强度和断后伸长率总体上均随温度的升高而增大,且在1 150℃及以上时,抗拉强度满足未服役HP40Nb合金的强度要求,但伸长率远小于标准要求。
Abstract
The microstructure and tensile properties of the heat affected zone of a service-degraded HP40Nb hydrogen production convert furnace tube were studied by the welding thermal simulation. The results show that coarse and continuous G phase and chromium-rich M23C6 carbides existed on austenite grain boundaries in the service-degraded furnace tube. After thermal cycling at peak temperature of 1 100-1 200 ℃, the precipitates still consisted of G phase and M23C6 carbides, and both decreased in content with increasing peak temperature. When the peak temperature was 1 250 ℃, the precipitates were composed of M23C6 and NbC phases. The tensile strength and elongation of the heat affected zone samples obtained at lower peak temperatures (950-1 050 ℃) were lower. When the peak temperature was higher than 1 100 ℃, the tensile strength and elongation increased with increasing temperature. When the peak temperature increased to 1 150 ℃ and above, the tensile strength reached the requirements of the unserviced HP40Nb alloy, while the elongation was smaller than the standard requirement.
中图分类号 TG457.11 DOI 10.11973/jxgccl202012006
所属栏目 试验研究
基金项目 国家重点研发计划项目(2017YFF0210401)
收稿日期 2019/10/9
修改稿日期 2020/9/30
网络出版日期
作者单位点击查看
备注李松林(1995-),男,河南邓州人,硕士研究生
引用该论文: LI Songlin,CAO Luowei,HAN Zhiyuan,CHENG Fangjie. Microstructure and Tensile Properties of Heat Affected Zone bySimulation Welding of Service-Degraded HP40Nb Furnace Tube[J]. Materials for mechancial engineering, 2020, 44(12): 33~36
李松林,曹逻炜,韩志远,程方杰. 服役劣化HP40Nb炉管模拟焊接热影响区的显微组织和拉伸性能[J]. 机械工程材料, 2020, 44(12): 33~36
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【6】赵宝纯,李桂艳,杨静.Gleeble-3800热模拟试验机的应用研究[J].鞍钢技术,2010(5):28-31.
【7】穆宏伟.超级奥氏体不锈钢254SMo焊接热模拟组织及耐蚀性研究[D].太原:太原科技大学,2018.
【8】丁连征,王锴,孟庆森.SA738Gr.B钢焊接热影响区组织及性能的热模拟试验[J].焊接学报,2014,35(8):91-94.
【9】张文钺.焊接冶金学:基本原理[M].北京:机械工业出版社,1995.
【10】SINDO K.焊接冶金学(第二版)[M].闫久春,杨建国,张广军,译.北京:高等教育出版社,2012.
【11】LIU C J,CHEN Y.Variations of the microstructure and mechanical properties of HP40Nb hydrogen reformer tube with time at elevated temperature[J].Materials & Design,2011,32(4):2507-2512.
【12】张忠政,巩建鸣,奚冬兴,等.新旧HP-Nb炉管焊接后的剩余寿命[J].石油化工设备技术,2005,26(4):1-4.
【13】CHEN Q Z,THOMAS C W,KNOWLES D M.Characterisation of 20Cr32Ni1Nb alloys in as-cast and ex-service conditions by SEM,TEM and EDX[J].Materials Science and Engineering:A,2004,374(1/2):398-408.
【14】KENIK E A,MAZIASZ P J,SWINDEMAN R W,et al.Structure and phase stability in a cast modified-HP austenite after long-term ageing[J].Scripta Materialia,2003,49(2):117-122.
【15】VOICU R,ANDRIEU E,POQUILLON D,et al.Microstructure evolution of HP40-Nb alloys during aging under air at 1000℃[J].Materials Characterization,2009,60(9):1020-1027.
【16】ALVINO A,LEGA D,GIACOBBE F,et al.Damage characterization in two reformer heater tubes after nearly 10 years of service at different operative and maintenance conditions[J].Engineering Failure Analysis,2010,17(7/8):1526-1541.
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