Effects of Trace Er on Microstructure and Properties of Hot-dip Galvanized Coating for Automobile
摘 要
采用热浸镀方法在汽车钢表面制备了不同Er含量的热浸镀锌镀层,研究了Er含量对镀层显微组织、硬度、厚度和耐蚀性的影响。结果表明:随着Er含量的增加,镀层平均晶粒尺寸呈现先减小而后增大的特征,且在Er质量分数为0.10%时取得最小值,添加适量Er可以在细化晶粒的同时改善表面质量。添加Er合金镀层的表面硬度平均值均高于Zn-0.6Al-0Er合金镀层的,且随着Er含量增加,镀层表面硬度呈现先增加而后减小特征,当Er质量分数为0.10%时硬度最大,而镀层厚度随Er含量的增加呈现逐渐减小特征;随着Er含量的增加,镀层平均腐蚀速率呈现先减小而后增大特征,Zn-0.6Al-0.10Er合金镀层具有最佳耐蚀性。
Abstract
Hot dip galvanized coatings with different Er content were prepared on the surface of automobile steel by hot dip plating. The effects of Er content on the microstructure, hardness, thickness and corrosion resistance of the coatings were studied. The results showed that the average grain size of the coating decreased first and then increased with the increase of Er content, the minimum grain size could be obtained when Er content was 0.10%, and the surface quality could be improved with the addition of appropriate Er content. The average surface hardness of the coatings with different Er content was higher than that of Zn-0.6Al-0Er alloy coating, with the increase of Er content, the surface hardness of the coating increased first and then decreased, when the Er content was 0.10%, the maximum hardness was obtained, while the thickness of the coating decreased with the increase of Er content. With the increase of Er content, the average corrosion rate of the coatings decreased first and then increased, and Zn-0.6Al-0.10Er alloy coating had the best corrosion resistance.
中图分类号 TG174.4 DOI 10.11973/fsyfh-202101004
所属栏目 试验研究
基金项目 国家自然科学基金(51602156);山西省高等学校科技创新项目(20161126)
收稿日期 2019/3/11
修改稿日期
网络出版日期
作者单位点击查看
联系人作者宋捷(one098@21cn.com)
引用该论文: SONG Jie,LU Xinfeng,TIAN Zhiqi. Effects of Trace Er on Microstructure and Properties of Hot-dip Galvanized Coating for Automobile[J]. Corrosion & Protection, 2021, 42(1): 17
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】王彭涛,蒋光锐,刘李斌. 热镀锌汽车板亮点缺陷研究[J]. 热加工工艺,2019,48(8):248-250.
【2】杜新,刘敬福,冯立丽,等. 热镀锌工业设备用钢铁材料耐锌液腐蚀的研究进展[J]. 材料保护,2019,52(1):107-112.
【3】李欣,李慧荣,马涛,等. 钢材表面热浸镀锌层的研究进展[J]. 热加工工艺,2019,48(2):7-9.
【4】保勇,鲍成人,宁媛媛,等. 热镀锌带钢表面锌渣缺陷形成分析及改进措施[J]. 冶金与材料,2019,39(1):14-16,19.
【5】刘耀鸿,王朝辉,刘轲,等. Er对Mg-5Zn-xEr镁合金热裂敏感性的影响[J]. 金属学报,2019,55(3):389-398.
【6】刘冉,黄晖,马俊,等. Al-6Mg-0.8Zn-0.5Mn-0.2Zr-0.2Er合金低温力学性能与微观组织研究[J]. 稀有金属材料与工程,2018,47(1):162-168.
【7】LEKBIR C,DAHOUN N,GUETITECH A,et al. Effect of immersion time and cooling mode on the electrochemical behavior of hot-dip galvanized steel in sulfuric acid medium[J]. Journal of Materials Engineering and Performance,2017,26(6):2502-2511.
【8】BONDAREVA O. Study of the temperature effect on the structure and thickness of hot-dip zinc coatings on fixing products[J]. Applied Mechanics and Materials,2014,698:355-359.
【9】YUWEI L,ZHENYAO W,JUN W,et al. Corrosion behavior of hot-dip galvanized steel for power transmission tower in simulated acid rain atmospheric environment[J]. Journal of Chinese Society for Corrosion & Protection,2014,34(5):426-432.
【10】WANG S M,HUANG G X,HE M Y,et al. Effect of Ti and Al addition on microstructure of hot-dip zinc coating[J]. Transactions of Materials & Heat Treatment,2013,34(8):158-162.
【11】MOHAMMADNEJAD M,HABIBOLAHZADEH A,YOUSEFPOUR M. Effect of Nano-oxide addition on corrosion performance of hot dip zinc coating[J]. Protection of Metals and Physical Chemistry of Surfaces,2016,52(1):100-103.
【12】LI S W,GAO B,TU G F,et al. The effects of RE and Si on the thickness and cross section morphology of Zn-6Al-3Mg alloy coating[J]. Key Engineering Materials,2013,562/563/564/565:935-941.
【13】王颖,邢泽城. Er含量对暖通空调管道表面镀锌层耐蚀性的影响[J]. 腐蚀与防护,2018,39(8):603-606,612.
【14】DONG A P,LI B P,LU Y L,et al. Effect of Mg on the microstructure and corrosion resistance of the continuously hot-dip galvanizing Zn-Mg coating[J]. Materials,2017,10(8):980.
【15】MADERTHANER M,JAROSIK A,ANGELI G,et al. 3rd generation hot-dip galvanized steel sheet for automobile manufacturing-interface reactions between zinc and metal oxide[J]. Key Engineering Materials,2017,742:463-470.
【16】HE S Q,ZHONG H. EIS study of corrosion behavior of hot-dip galvanized steel in 5% NaCl aqueous solution[J]. Advanced Materials Research,2011,335/336:779-782.
【2】杜新,刘敬福,冯立丽,等. 热镀锌工业设备用钢铁材料耐锌液腐蚀的研究进展[J]. 材料保护,2019,52(1):107-112.
【3】李欣,李慧荣,马涛,等. 钢材表面热浸镀锌层的研究进展[J]. 热加工工艺,2019,48(2):7-9.
【4】保勇,鲍成人,宁媛媛,等. 热镀锌带钢表面锌渣缺陷形成分析及改进措施[J]. 冶金与材料,2019,39(1):14-16,19.
【5】刘耀鸿,王朝辉,刘轲,等. Er对Mg-5Zn-xEr镁合金热裂敏感性的影响[J]. 金属学报,2019,55(3):389-398.
【6】刘冉,黄晖,马俊,等. Al-6Mg-0.8Zn-0.5Mn-0.2Zr-0.2Er合金低温力学性能与微观组织研究[J]. 稀有金属材料与工程,2018,47(1):162-168.
【7】LEKBIR C,DAHOUN N,GUETITECH A,et al. Effect of immersion time and cooling mode on the electrochemical behavior of hot-dip galvanized steel in sulfuric acid medium[J]. Journal of Materials Engineering and Performance,2017,26(6):2502-2511.
【8】BONDAREVA O. Study of the temperature effect on the structure and thickness of hot-dip zinc coatings on fixing products[J]. Applied Mechanics and Materials,2014,698:355-359.
【9】YUWEI L,ZHENYAO W,JUN W,et al. Corrosion behavior of hot-dip galvanized steel for power transmission tower in simulated acid rain atmospheric environment[J]. Journal of Chinese Society for Corrosion & Protection,2014,34(5):426-432.
【10】WANG S M,HUANG G X,HE M Y,et al. Effect of Ti and Al addition on microstructure of hot-dip zinc coating[J]. Transactions of Materials & Heat Treatment,2013,34(8):158-162.
【11】MOHAMMADNEJAD M,HABIBOLAHZADEH A,YOUSEFPOUR M. Effect of Nano-oxide addition on corrosion performance of hot dip zinc coating[J]. Protection of Metals and Physical Chemistry of Surfaces,2016,52(1):100-103.
【12】LI S W,GAO B,TU G F,et al. The effects of RE and Si on the thickness and cross section morphology of Zn-6Al-3Mg alloy coating[J]. Key Engineering Materials,2013,562/563/564/565:935-941.
【13】王颖,邢泽城. Er含量对暖通空调管道表面镀锌层耐蚀性的影响[J]. 腐蚀与防护,2018,39(8):603-606,612.
【14】DONG A P,LI B P,LU Y L,et al. Effect of Mg on the microstructure and corrosion resistance of the continuously hot-dip galvanizing Zn-Mg coating[J]. Materials,2017,10(8):980.
【15】MADERTHANER M,JAROSIK A,ANGELI G,et al. 3rd generation hot-dip galvanized steel sheet for automobile manufacturing-interface reactions between zinc and metal oxide[J]. Key Engineering Materials,2017,742:463-470.
【16】HE S Q,ZHONG H. EIS study of corrosion behavior of hot-dip galvanized steel in 5% NaCl aqueous solution[J]. Advanced Materials Research,2011,335/336:779-782.
相关信息