Hydrogen Embrittlement of X80 Pipeline Steel
摘 要
制备了单边缺口拉伸(SENT)试样,在0.5 mol/L H2SO4+3 g/L NH4SCN溶液中,以10 mA/cm2的电流密度充氢4 h,采用拉伸试验和三点弯曲试验考察了氢脆对X80管线钢断裂韧性的影响。结果显示:充氢SENT试样的断裂韧性和承载力显著低于母材SENT试样的,使用三点弯曲试验测定的断裂韧性结果较为保守;充氢SENT试样的裂纹比较尖锐,呈现非稳态扩展特征,其塑性变形主要集中于裂纹尖端的局部区域;氢的存在会降低裂纹起裂和扩展所需的能量,促进韧性撕裂过程向脆性断裂转化。
Abstract
A single edge notched tensile (SENT) specimen was prepared, and hydrogen was charged in 0.5 mol/L H2SO4+3 g/L NH4SCN solution at a current density of 10 mA/cm2 for 4 h. The effect of hydrogen embrittlement on the fracture toughness of X80 pipeline steel was comparatively studied by tensile test and three-point bending test. The results show that the fracture toughness and bearing capacity of the hydrogen-charged SENT sample were significantly lower than those of the base material SENT sample. The fracture toughness results measured by the three-point bending test were conservative. Cracks of the hydrogen-charged SENT sample were relatively sharp, showing the characteristics of unsteady state propagation, and the plastic deformation was mainly concentrated in the localized area of the crack tip. The presence of hydrogen would reduce the energy required for crack initiation and propagation, and promote the transition from ductile tearing to brittle fracture.
中图分类号 TG174 DOI 10.11973/fsyfh-202101006
所属栏目 试验研究
基金项目 国家自然科学基金(51305295)
收稿日期 2020/3/17
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联系人作者李一哲(lyz@tju.edu.cn)
引用该论文: LI Yizhe. Hydrogen Embrittlement of X80 Pipeline Steel[J]. Corrosion & Protection, 2021, 42(1): 25
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参考文献
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【10】CHIESA M,NYHUS B,SKALLERUD B,et al. Efficient fracture assessment of pipelines. A constraint-corrected SENT specimen approach[J]. Engineering Fracture Mechanics,2001,68(5):527-547.
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【2】STENERUD G,WENNER S,OLSEN J S,et al. Effect of different microstructural features on the hydrogen embrittlement susceptibility of alloy 718[J]. International Journal of Hydrogen Energy,2018,43(13):6765-6776.
【3】WANG R. Effects of hydrogen on the fracture toughness of a X70 pipeline steel[J]. Corrosion Science,2009,51(12):2803-2810.
【4】WANG Y F,WANG X W,GONG J M,et al. Hydrogen embrittlement of catholically hydrogen-precharged 304L austenitic stainless steel:effect of plastic pre-strain[J]. International Journal of Hydrogen Energy,2014,39(25):13909-13918.
【5】MURAKAMI Y,KANEZAKI T,MINE Y. Hydrogen effect against hydrogen embrittlement[J]. Metallurgical and Materials Transactions A,2010,41(10):2548-2562.
【6】WANG P Y,LV Z,ZHENG S Q,et al. Tensile and impact properties of X70 pipeline steel exposed to wet H2S environments[J]. International Journal of Hydrogen Energy,2015,40(35):11514-11521.
【7】OLDEN V,ALVARO A,AKSELSEN O M. Hydrogen diffusion and hydrogen influenced critical stress intensity in an API X70 pipeline steel welded joint-Experiments and FE simulations[J]. International Journal of Hydrogen Energy,2012,37(15):11474-11486.
【8】WANG Y F,GONG J M,JIANG W C. A quantitative description on fracture toughness of steels in hydrogen gas[J]. International Journal of Hydrogen Energy,2013,38(28):12503-12508.
【9】WANG E Y,ZHOU W X,SHEN G W. Three-dimensional finite element analysis of crack-tip fields of clamped single-edge tension specimens-Part Ⅱ:Crack-tip constraints[J]. Engineering Fracture Mechanics,2014,116:144-157.
【10】CHIESA M,NYHUS B,SKALLERUD B,et al. Efficient fracture assessment of pipelines. A constraint-corrected SENT specimen approach[J]. Engineering Fracture Mechanics,2001,68(5):527-547.
【11】HAGI H. Thermal evolution spectrum of hydrogen from low carbon steel charged by cathodic polarization[J]. Materials Transactions,JIM,1997,38(11):970-977.
【12】DE ASSIS K S,LAGE M A,GUTTEMBERG G,et al. Influence of hydrogen on plasticity around the crack tip in high strength steels[J]. Engineering Fracture Mechanics,2017,176:116-125.
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