钴掺杂锰氧化物水系锌离子电池正极材料的制备与电化学性能
Preparation and Electrochemical Performance of Cobalt-DopedManganese Oxide Aqueous Zinc-ion Battery Cathode Material
摘 要
以硝酸锰和硝酸钴为原料，通过溶剂热反应、水解和煅烧制备了可作为水系锌离子电池正极材料的钴掺杂锰氧化物，研究了钴掺杂锰氧化物的微观结构及电化学性能。结果表明：所制备的钴掺杂锰氧化物h-CoMn3.2Ox具有分级核壳结构，多孔壳表面存在径向尺寸大于100 nm的花瓣状纳米片，壳和纳米片均由平均粒径为5 nm的一次粒子构成，钴掺杂赋予锰氧化物较小的尺寸和精细的结构；h-CoMn3.2Ox具有方锰矿型一氧化锰的晶体结构；与锰氧化物相比，h-CoMn3.2Ox具有较大的比表面积与比容量，并具有良好的循环稳定性；h-CoMn3.2Ox的储能行为归因于H+/Zn2+的连续共嵌入反应。
钴掺杂
分级结构
水系锌离子电池
电化学性能
manganese oxide
cobalt-doping
hierarchical structure
aqueous zinc-ion battery
electrochemical performance
Abstract
The cobalt-doped manganese oxide for aqueous zinc-ion battery cathode material was prepared by solvothermal, hydrolyzing and annealing with cobalt nitrate and manganese nitrate as raw materials. The microstructure and electrochemical performance of cobalt-doped manganese oxide was investigated. The results show that the prepared cobalt-doped manganese oxide h-CoMn3.2Ox had a hierarchical yolk-shell structure, and the porous shell surface was decorated with petal-like nanosheets with radial dimension of more than 100 nm. Both of the shell and nanosheets were composed of primary nanoparticles with average size of 5 nm. Cobalt-doping endowed manganese oxides with small size and delicate structure. h-CoMn3.2Ox had the manganosite MnO crystal structure. Compared with monometallic manganese oxide, h-CoMn3.2Ox exhibited relatively large specific surface areas and specific capacities, and had good cyclic stability. The energy-storage behavior of h-CoMn3.2Ox was attributed to sequent co-insertion of H+ and Zn2+.
中图分类号 TM911 DOI 10.11973/jxgccl202101004
所属栏目 试验研究
基金项目 国家自然科学基金资助项目（51772152，21908110）；江苏省自然科学基金资助项目（1192261031693）；中央高校基本科研专项资金资助项目（30919011110，1191030558）
收稿日期 2020/5/8
修改稿日期 2020/12/16
网络出版日期
作者单位点击查看
备注胡入丹(1992-),女,四川绵阳人,博士研究生
引用该论文: HU Rudan,SUN Jingwen,LIU Yifan,QIAN Xingyue,ZHANG Litong,ZHU Junwu. Preparation and Electrochemical Performance of Cobalt-DopedManganese Oxide Aqueous Zinc-ion Battery Cathode Material[J]. Materials for mechancial engineering, 2021, 45(1): 20～27
胡入丹,孙敬文,刘一凡,钱惺悦,张丽童,朱俊武. 钴掺杂锰氧化物水系锌离子电池正极材料的制备与电化学性能[J]. 机械工程材料, 2021, 45(1): 20～27
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参考文献
【1】LIU J,ZHANG J G,YANG Z G,et al.Materials science and materials chemistry for large scale electrochemical energy storage:From transportation to electrical grid[J].Advanced Functional Materials, 2013,23(8):929-946.
【2】FULLER T F.Batteries:Bigger and better[J].Nature Energy, 2016,1(2):16003.
【3】CHEN L N,AN Q Y,MAI L Q.Recent advances and prospects of cathode materials for rechargeable aqueous zinc-ion batteries[J].Advanced Materials Interfaces, 2019,6(17):1900387.
【4】HUANG S,ZHU J C,TIAN J L,et al.Frontispiece:Recent progress in the electrolytes of aqueous zinc-ion batteries[J].Chemistry - A European Journal, 2019,25(64):201986461.
【5】LI C G,ZHANG X D,HE W,et al.Cathode materials for rechargeable zinc-ion batteries:From synthesis to mechanism and applications[J].Journal of Power Sources, 2020,449:227596.
【6】TANG B Y,SHAN L T,LIANG S Q,et al.Issues and opportunities facing aqueous zinc-ion batteries[J].Energy & Environmental Science, 2019,12(11):3288-3304.
【7】LIU W B,HAO J W,XU C J,et al.Investigation of zinc ion storage of transition metal oxides,sulfides,and borides in zinc ion battery systems[J].Chemical Communications, 2017,53(51):6872-6874.
【8】KUNDU D P,ADAMS B D,DUFFORT V,et al.A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode[J].Nature Energy, 2016,1(10):16119.
【9】YANG Q,MO F N,LIU Z X,et al.Activating C-coordinated iron of iron hexacyanoferrate for Zn hybrid-ion batteries with 10000-cycle lifespan and superior rate capability[J].Advanced Materials, 2019:1901521.
【10】SONG M,TAN H,CHAO D L,et al.Recent advances in Zn-ion batteries[J].Advanced Functional Materials, 2018,28(41):1802564.
【11】WEI W F,CUI X W,CHEN W X,et al.Manganese oxide-based materials as electrochemical supercapacitor electrodes[J].Chemical Society Reviews, 2011,40(3):1697-1721.
【12】WANG J J,WANG J G,LIU H Y,et al.Zinc ion stabilized MnO2 nanospheres for high capacity and long lifespan aqueous zinc-ion batteries[J].Journal of Materials Chemistry A, 2019,7(22):13727-13735.
【13】XU D W,LI B H,WEI C G,et al.Preparation and characterization of MnO2/acid-treated CNT nanocomposites for energy storage with zinc ions[J].Electrochimica Acta, 2014,133:254-261.
【14】WU B K,ZHANG G B,YAN M Y,et al.Graphene scroll-coated α-MnO2 nanowires as high-performance cathode materials for aqueous Zn-ion battery[J].Small, 2018,14(13):1703850.
【15】KHAMSANGA S,PORNPRASERTSUK R,YONEZAWA T,et al.δ-MnO2 nanoflower/graphite cathode for rechargeable aqueous zinc ion batteries[J].Scientific Reports, 2019,9:8441.
【16】ALFARUQI M H,ISLAM S,MATHEW V,et al.Ambient redox synthesis of vanadium-doped manganese dioxide nanoparticles and their enhanced zinc storage properties[J].Applied Surface Science,2017,404:435-442.
【17】GUAN C,LIU X M,REN W N,et al.Rational design of metal-organic framework derived hollow NiCo2O4 arrays for flexible supercapacitor and electrocatalysis[J].Advanced Energy Materials, 2017,7(12):1602391.
【18】STOŠEVSKI I,BONAKDARPOUR A,CUADRA F,et al.Highly crystalline ramsdellite as a cathode material for near-neutral aqueous MnO2/Zn batteries[J].Chemical Communications, 2019,55(14):2082-2085.
【19】XIONG T,YU Z G,WU H J,et al.Defect engineering of oxygen-deficient manganese oxide to achieve high-performing aqueous zinc ion battery[J].Advanced Energy Materials, 2019,9(14):1803815.
【20】WULAN SEPTIANI N L,KANETI Y V,FATHONI K B,et al.Self-assembly of nickel phosphate-based nanotubes into two-dimensional crumpled sheet-like architectures for high-performance asymmetric supercapacitors[J].Nano Energy, 2020,67:104270.
【21】WANG L,JIAO X Y,LIU P,et al.Self-template synthesis of yolk-shelled NiCo2O4 spheres for enhanced hybrid supercapacitors[J].Applied Surface Science,2018,427:174-181.
【22】XIAO J W,YANG S H.Sequential crystallization of sea urchin-like bimetallic (Ni,Co) carbonate hydroxide and its morphology conserved conversion to porous NiCo2O4 spinel for pseudocapacitors[J].RSC Advances, 2011,1(4):588.
【23】GAYER K H,GARRETT A B.The solubility of cobalt hydroxide,Co(OH)2,in solutions of hydrochloric acid and sodium hydroxide at 25°[J].Journal of the American Chemical Society, 1950,72(9):3921-3923.
【24】SWAIN H A,LEE C,ROZELLE R B.Determination of the solubility of manganese hydroxide and manganese dioxide at 25.deg.by atomic absorption spectrometry[J].Analytical Chemistry, 1975,47(7):1135-1137.
【25】DI CASTRO V,POLZONETTI G.XPS study of MnO oxidation[J].Journal of Electron Spectroscopy and Related Phenomena, 1989,48(1):117-123.
【26】HASSEL M,FREUND H J.High resolution XPS study of a thin CoO(111) film grown on Co(0001)[J].Surface Science Spectra, 1996,4(3):273-278.
【27】TODOROVA S,KOLEV H,HOLGADO J P,et al.Complete n-hexane oxidation over supported Mn-Co catalysts[J].Applied Catalysis B:Environmental,2010,94(1/2):46-54.
【28】LI W,WANG G J,CHEN C,et al.Enhanced visible light photocatalytic activity of ZnO nanowires doped with Mn2+ and Co2+ ions[J].Nanomaterials, 2017,7(1):20.
【29】LONG J,GU J X,YANG Z H,et al.Highly porous,low band-gap NixMn3-xO4 (0.55≤ x ≤ 1.2) spinel nanoparticles with in situ coated carbon as advanced cathode materials for zinc-ion batteries[J].Journal of Materials Chemistry A, 2019,7(30):17854-17866.
【30】ZHU C Y,FANG G Z,ZHOU J,et al.Binder-free stainless steel@Mn3O4 nanoflower composite:A high-activity aqueous zinc-ion battery cathode with high-capacity and long-cycle-life[J].Journal of Materials Chemistry A, 2018,6(20):9677-9683.
【31】LU Z X,WANG N N,ZHANG Y H,et al.Pyrite FeS2@C nanorods as smart cathode for sodium ion battery with ultra-long lifespan and notable rate performance from tunable pseudocapacitance[J].Electrochimica Acta, 2018,260:755-761.
【32】GE P,ZHANG C Y,HOU H S,et al.Anions induced evolution of Co3X4 (X=O,S,Se) as sodium-ion anodes:The influences of electronic structure,morphology,electrochemical property[J].Nano Energy,2018,48:617-629.
【33】SELVAKUMARAN D,PAN A Q,LIANG S Q,et al.A review on recent developments and challenges of cathode materials for rechargeable aqueous Zn-ion batteries[J].Journal of Materials Chemistry A, 2019,7(31):18209-18236.
【2】FULLER T F.Batteries:Bigger and better[J].Nature Energy, 2016,1(2):16003.
【3】CHEN L N,AN Q Y,MAI L Q.Recent advances and prospects of cathode materials for rechargeable aqueous zinc-ion batteries[J].Advanced Materials Interfaces, 2019,6(17):1900387.
【4】HUANG S,ZHU J C,TIAN J L,et al.Frontispiece:Recent progress in the electrolytes of aqueous zinc-ion batteries[J].Chemistry - A European Journal, 2019,25(64):201986461.
【5】LI C G,ZHANG X D,HE W,et al.Cathode materials for rechargeable zinc-ion batteries:From synthesis to mechanism and applications[J].Journal of Power Sources, 2020,449:227596.
【6】TANG B Y,SHAN L T,LIANG S Q,et al.Issues and opportunities facing aqueous zinc-ion batteries[J].Energy & Environmental Science, 2019,12(11):3288-3304.
【7】LIU W B,HAO J W,XU C J,et al.Investigation of zinc ion storage of transition metal oxides,sulfides,and borides in zinc ion battery systems[J].Chemical Communications, 2017,53(51):6872-6874.
【8】KUNDU D P,ADAMS B D,DUFFORT V,et al.A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode[J].Nature Energy, 2016,1(10):16119.
【9】YANG Q,MO F N,LIU Z X,et al.Activating C-coordinated iron of iron hexacyanoferrate for Zn hybrid-ion batteries with 10000-cycle lifespan and superior rate capability[J].Advanced Materials, 2019:1901521.
【10】SONG M,TAN H,CHAO D L,et al.Recent advances in Zn-ion batteries[J].Advanced Functional Materials, 2018,28(41):1802564.
【11】WEI W F,CUI X W,CHEN W X,et al.Manganese oxide-based materials as electrochemical supercapacitor electrodes[J].Chemical Society Reviews, 2011,40(3):1697-1721.
【12】WANG J J,WANG J G,LIU H Y,et al.Zinc ion stabilized MnO2 nanospheres for high capacity and long lifespan aqueous zinc-ion batteries[J].Journal of Materials Chemistry A, 2019,7(22):13727-13735.
【13】XU D W,LI B H,WEI C G,et al.Preparation and characterization of MnO2/acid-treated CNT nanocomposites for energy storage with zinc ions[J].Electrochimica Acta, 2014,133:254-261.
【14】WU B K,ZHANG G B,YAN M Y,et al.Graphene scroll-coated α-MnO2 nanowires as high-performance cathode materials for aqueous Zn-ion battery[J].Small, 2018,14(13):1703850.
【15】KHAMSANGA S,PORNPRASERTSUK R,YONEZAWA T,et al.δ-MnO2 nanoflower/graphite cathode for rechargeable aqueous zinc ion batteries[J].Scientific Reports, 2019,9:8441.
【16】ALFARUQI M H,ISLAM S,MATHEW V,et al.Ambient redox synthesis of vanadium-doped manganese dioxide nanoparticles and their enhanced zinc storage properties[J].Applied Surface Science,2017,404:435-442.
【17】GUAN C,LIU X M,REN W N,et al.Rational design of metal-organic framework derived hollow NiCo2O4 arrays for flexible supercapacitor and electrocatalysis[J].Advanced Energy Materials, 2017,7(12):1602391.
【18】STOŠEVSKI I,BONAKDARPOUR A,CUADRA F,et al.Highly crystalline ramsdellite as a cathode material for near-neutral aqueous MnO2/Zn batteries[J].Chemical Communications, 2019,55(14):2082-2085.
【19】XIONG T,YU Z G,WU H J,et al.Defect engineering of oxygen-deficient manganese oxide to achieve high-performing aqueous zinc ion battery[J].Advanced Energy Materials, 2019,9(14):1803815.
【20】WULAN SEPTIANI N L,KANETI Y V,FATHONI K B,et al.Self-assembly of nickel phosphate-based nanotubes into two-dimensional crumpled sheet-like architectures for high-performance asymmetric supercapacitors[J].Nano Energy, 2020,67:104270.
【21】WANG L,JIAO X Y,LIU P,et al.Self-template synthesis of yolk-shelled NiCo2O4 spheres for enhanced hybrid supercapacitors[J].Applied Surface Science,2018,427:174-181.
【22】XIAO J W,YANG S H.Sequential crystallization of sea urchin-like bimetallic (Ni,Co) carbonate hydroxide and its morphology conserved conversion to porous NiCo2O4 spinel for pseudocapacitors[J].RSC Advances, 2011,1(4):588.
【23】GAYER K H,GARRETT A B.The solubility of cobalt hydroxide,Co(OH)2,in solutions of hydrochloric acid and sodium hydroxide at 25°[J].Journal of the American Chemical Society, 1950,72(9):3921-3923.
【24】SWAIN H A,LEE C,ROZELLE R B.Determination of the solubility of manganese hydroxide and manganese dioxide at 25.deg.by atomic absorption spectrometry[J].Analytical Chemistry, 1975,47(7):1135-1137.
【25】DI CASTRO V,POLZONETTI G.XPS study of MnO oxidation[J].Journal of Electron Spectroscopy and Related Phenomena, 1989,48(1):117-123.
【26】HASSEL M,FREUND H J.High resolution XPS study of a thin CoO(111) film grown on Co(0001)[J].Surface Science Spectra, 1996,4(3):273-278.
【27】TODOROVA S,KOLEV H,HOLGADO J P,et al.Complete n-hexane oxidation over supported Mn-Co catalysts[J].Applied Catalysis B:Environmental,2010,94(1/2):46-54.
【28】LI W,WANG G J,CHEN C,et al.Enhanced visible light photocatalytic activity of ZnO nanowires doped with Mn2+ and Co2+ ions[J].Nanomaterials, 2017,7(1):20.
【29】LONG J,GU J X,YANG Z H,et al.Highly porous,low band-gap NixMn3-xO4 (0.55≤ x ≤ 1.2) spinel nanoparticles with in situ coated carbon as advanced cathode materials for zinc-ion batteries[J].Journal of Materials Chemistry A, 2019,7(30):17854-17866.
【30】ZHU C Y,FANG G Z,ZHOU J,et al.Binder-free stainless steel@Mn3O4 nanoflower composite:A high-activity aqueous zinc-ion battery cathode with high-capacity and long-cycle-life[J].Journal of Materials Chemistry A, 2018,6(20):9677-9683.
【31】LU Z X,WANG N N,ZHANG Y H,et al.Pyrite FeS2@C nanorods as smart cathode for sodium ion battery with ultra-long lifespan and notable rate performance from tunable pseudocapacitance[J].Electrochimica Acta, 2018,260:755-761.
【32】GE P,ZHANG C Y,HOU H S,et al.Anions induced evolution of Co3X4 (X=O,S,Se) as sodium-ion anodes:The influences of electronic structure,morphology,electrochemical property[J].Nano Energy,2018,48:617-629.
【33】SELVAKUMARAN D,PAN A Q,LIANG S Q,et al.A review on recent developments and challenges of cathode materials for rechargeable aqueous Zn-ion batteries[J].Journal of Materials Chemistry A, 2019,7(31):18209-18236.
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