改性纳米Al2O3/环氧树脂复合防腐蚀涂料的制备及性能
Preparation and Properties of Modified Nano-Al2O3/Epoxy Resin Composite Anti-Corrosion Coatings
摘 要
在环氧树脂中添加不同量的改性纳米Al2O3颗粒，制备了改性纳米Al2O3/环氧树脂复合防腐蚀涂料。通过扫描电镜、显微维氏硬度计、傅里叶变换红光谱仪及摩擦磨损试验机，分别从表面形貌、硬度及耐磨性，研究了改性纳米Al2O3对涂层性能的影响。结果表明：在环氧树脂中添加5%（质量分数）的改性纳米Al2O3颗粒，可以使涂层的硬度由13.4 HV增加至19.5 HV，耐磨性明显提高。
环氧树脂
硬度
耐磨性
aluminum oxide
epoxy resin
hardness
wear resistance
Abstract
Modified nano-Al2O3/epoxy resin composite anti-corrosion coatings were prepared by adding different amounts of modified nano-Al2O3 particles into epoxy resin. The effects of nano-Al2O3 on the properties of the coating were investigated from the aspects of surface morphology, hardness and wear resistance by scanning electron microscopy, micro Vickers hardness test, Fourier transform infrared spectroscopy and friction and wear test. The results show that adding 5% (mass fraction) nano-Al2O3 particles into the epoxy resin could increase the hardness of the coating from 13.4 HV to 19.5 HV, and the wear resistance of the coating improved evidently.
中图分类号 TQ321.2 DOI 10.11973/fsyfh-202105008
所属栏目 试验研究
基金项目 智汇郑州1125·聚才计划（郑政2018-45号-15）
收稿日期 2019/8/31
修改稿日期
网络出版日期
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引用该论文: ZHANG Ruizhu,WANG Chongyang,WANG Wenbo,TIAN Weijie,MA Shuyun. Preparation and Properties of Modified Nano-Al2O3/Epoxy Resin Composite Anti-Corrosion Coatings[J]. Corrosion & Protection, 2021, 42(5): 38
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参考文献
【1】陈平,王德中. 环氧树脂及其应用[M]. 北京:化学工业出版社,2004.
【2】SAAD G R,ABDALLAH H M,AZIZ M S A,et al. Cure kinetics and thermal stability of maleimide modified epoxy TGIC/CPE powder coating system[J]. Thermochimica Acta,2015,617:191-199.
【3】YU J H,HUO R M,WU C,et al. Influence of interface structure on dielectric properties of epoxy/alumina nanocomposites[J]. Macromolecular Research,2012,20(8):816-826.
【4】张瑞珠,贾新杰,李林杰,等. 环氧树脂的增韧研究进展[J]. 化工新型材料,2018,46(9):21-24.
【5】于志强,姜月. 颗粒填充环氧复合材料的摩擦学性能研究进展[J]. 材料工程,2016,44(3):114-121.
【6】WANG Y,WEI D B,YU J,et al. Effects of Al2O3 nano-additive on performance of micro-arc oxidation coatings formed on AZ91D Mg alloy[J]. Journal of Materials Science & Technology,2014,30(10):984-990.
【7】BALANI K,AGARWAL A. Process map for plasma sprayed aluminum oxide-carbon nanotube nanocomposite coatings[J]. Surface and Coatings Technology,2008,202(17):4270-4277.
【8】LI Z,OKAMOTO K,OHKI Y,et al. Role of nano-fill er on partial discharge resistance and dielectric break- down strength of micro-Al2O3/epoxy composites[C]//2009 IEEE 9th International Conference on the Properties and Applications of Dielectric Materials.Harbin,China:IEEE,2009:753-756.
【9】吴聪,都怡佩,沈意斌,等. 氧化铝/环氧树脂复合材料的制备及散热性能研究[J]. 化工新型材料,2018,46(8):63-66.
【10】SU F S,LU C,KUO S C,et al. Adsorption of CO2 on amine-functionalized Y-type zeolites[J]. Energy & Fuels,2010,24(2):1441-1448.
【11】HUANG A S,WANG N Y,CARO J. Seeding-free synthesis of dense zeolite FAU membranes on 3-aminopropyltriethoxysilane-functionalized alumina supports[J]. Journal of Membrane Science,2012,389:272-279.
【12】SU F S,LU C,KUO S C,et al. Adsorption of CO2 on amine-functionalized Y-type zeolites[J]. Energy & Fuels,2010,24(2):1441-1448.
【13】王新慧. 氧化铝表面处理对微米Al2O3/环氧树脂性能影响的研究[D]. 哈尔滨:哈尔滨工业大学,2012.
【14】马骄,石冬. 纳米SiO2在有机硅涂料中的分散性研究[J]. 辽宁化工,2008,37(1):24-27,30.
【15】汤戈,王振家,马全友,等. 纳米Al2O3粉末改善环氧树脂耐磨性的研究[J]. 热固性树脂,2002,17(1):4-8.
【16】高伟. 纳米改性环氧防腐涂料的制备与性能评价[D]. 成都:西南石油大学,2012.
【2】SAAD G R,ABDALLAH H M,AZIZ M S A,et al. Cure kinetics and thermal stability of maleimide modified epoxy TGIC/CPE powder coating system[J]. Thermochimica Acta,2015,617:191-199.
【3】YU J H,HUO R M,WU C,et al. Influence of interface structure on dielectric properties of epoxy/alumina nanocomposites[J]. Macromolecular Research,2012,20(8):816-826.
【4】张瑞珠,贾新杰,李林杰,等. 环氧树脂的增韧研究进展[J]. 化工新型材料,2018,46(9):21-24.
【5】于志强,姜月. 颗粒填充环氧复合材料的摩擦学性能研究进展[J]. 材料工程,2016,44(3):114-121.
【6】WANG Y,WEI D B,YU J,et al. Effects of Al2O3 nano-additive on performance of micro-arc oxidation coatings formed on AZ91D Mg alloy[J]. Journal of Materials Science & Technology,2014,30(10):984-990.
【7】BALANI K,AGARWAL A. Process map for plasma sprayed aluminum oxide-carbon nanotube nanocomposite coatings[J]. Surface and Coatings Technology,2008,202(17):4270-4277.
【8】LI Z,OKAMOTO K,OHKI Y,et al. Role of nano-fill er on partial discharge resistance and dielectric break- down strength of micro-Al2O3/epoxy composites[C]//2009 IEEE 9th International Conference on the Properties and Applications of Dielectric Materials.Harbin,China:IEEE,2009:753-756.
【9】吴聪,都怡佩,沈意斌,等. 氧化铝/环氧树脂复合材料的制备及散热性能研究[J]. 化工新型材料,2018,46(8):63-66.
【10】SU F S,LU C,KUO S C,et al. Adsorption of CO2 on amine-functionalized Y-type zeolites[J]. Energy & Fuels,2010,24(2):1441-1448.
【11】HUANG A S,WANG N Y,CARO J. Seeding-free synthesis of dense zeolite FAU membranes on 3-aminopropyltriethoxysilane-functionalized alumina supports[J]. Journal of Membrane Science,2012,389:272-279.
【12】SU F S,LU C,KUO S C,et al. Adsorption of CO2 on amine-functionalized Y-type zeolites[J]. Energy & Fuels,2010,24(2):1441-1448.
【13】王新慧. 氧化铝表面处理对微米Al2O3/环氧树脂性能影响的研究[D]. 哈尔滨:哈尔滨工业大学,2012.
【14】马骄,石冬. 纳米SiO2在有机硅涂料中的分散性研究[J]. 辽宁化工,2008,37(1):24-27,30.
【15】汤戈,王振家,马全友,等. 纳米Al2O3粉末改善环氧树脂耐磨性的研究[J]. 热固性树脂,2002,17(1):4-8.
【16】高伟. 纳米改性环氧防腐涂料的制备与性能评价[D]. 成都:西南石油大学,2012.
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