Microstructure and Mechanical Property Evolution of Rare Earth-Containing Al-Mg Alloy During Cold Drawing
摘 要
熔炼制备不同稀土加入量的Al-3.0Mg-xRE(质量分数/%,x=0,0.12,0.31,RE为La+Ce)合金,研究了该合金的显微组织、硬度和拉伸性能在冷拉拔过程中的演变规律。结果表明:冷拉拔过程中,试验合金的晶粒拉长,第二相拉长并破碎成细小粒子,并在晶界和枝晶界处逐渐聚集呈线状分布,Copper {112}〈111〉型变形织构强度逐渐增高;随着变形量的增大,合金的强度呈线性增大,塑性降低,显微硬度增大;适量稀土(0.12%)的加入能够改善合金组织与力学性能,但过量稀土(0.31%)的加入会导致合金中第二相数量和尺寸的增加,从而降低合金的力学性能。冷拉拔后,Al-3.0Mg-0.12RE合金中第二相的长度最小,数量最少,变形织构强度最高,力学性能最优。
Abstract
Al-3.0Mg-xRE (mass fraction/%, x=0, 0.12, 0.31, RE=La+Ce) alloys containing different-content rare earth were smelted. The evolution of the microstructure, hardness and tensile properties of the alloys were investigated in cold drawing. The results show that during the cold drawing, the grains of the test alloys were elongated; the second phase particles were also elongated and fragmented to small particles, and then gradually aligned on grain boundaries and dendrite boundaries in linearity; the intensity of Copper {112}〈111〉 deforming texture increased. With increasing deformation amount, the strength of the alloys increased linearly, the plasticity decreased and the hardness increased. Proper rare earth addition (0.12%) could improve the microstructure and the mechanical properties of the alloy. However, excessive rare earth addition (0.31%) increased the number and size of the second phases in the alloy, thereby reducing the mechanical properties of the alloy. After cold drawing, the Al-3.0Mg-0.12RE alloy had the smallest and the least second phases, the highest deforming texture intensity and the best mechanical properties.
中图分类号 TG174.442 DOI 10.11973/jxgccl202110005
所属栏目 试验研究
基金项目 国家自然科学基金资助项目(51909071);江苏省自然科学基金资助项目(BK20190493)
收稿日期 2020/12/16
修改稿日期 2021/9/15
网络出版日期
作者单位点击查看
备注张欣(1988-),男,辽宁鞍山人,副教授,博士
引用该论文: ZHANG Xin,YANG Guangheng,WANG Zehua,ZHOU Zehua,YI Yu,CAI Xin. Microstructure and Mechanical Property Evolution of Rare Earth-Containing Al-Mg Alloy During Cold Drawing[J]. Materials for mechancial engineering, 2021, 45(10): 34~42
张欣,杨光恒,王泽华,周泽华,易于,蔡新. 冷拉拔过程中含稀土铝镁合金的组织与力学性能演变[J]. 机械工程材料, 2021, 45(10): 34~42
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参考文献
【1】杨富尧, 程灵, 马光, 等.复杂电磁条件下不同取向硅钢的铁损性能[J].机械工程材料, 2016, 40(10):85-88. YANG F Y, CHENG L, MA G, et al.Iron loss of different oriented silicon steels under complex electromagnetic condition[J].Materials for Mechanical Engineering, 2016, 40(10):85-88.
【2】CHEN X H, LIU J, ZHANG Z H, et al.Effect of heat treatment on electromagnetic shielding effectiveness of ZK60 magnesium alloy[J].Materials & Design, 2012, 42:327-333.
【3】DHAWAN S K, SINGH N, RODRIGUES D.Electromagnetic shielding behaviour of conducting polyaniline composites[J].Science and Technology of Advanced Materials, 2003, 4(2):105-113.
【4】甘雪萍, 胡文彬, 张青青, 等.电磁波屏蔽织物的发展现状[J].表面技术, 2006, 35(6):48-50. GAN X P, HU W B, ZHANG Q Q, et al.Development of conductive fabric for electromagnetic shielding[J].Surface Technology, 2006, 35(6):48-50.
【5】詹建朝, 张辉, 沈兰萍.涤纶织物化学镀镍的研究[J].上海纺织科技, 2006, 34(6):15-18. ZHAN J Z, ZHANG H, SHEN L P.Study on chemical nickel plating on PET fabric[J].Shanghai Textile Science & Technology, 2006, 34(6):15-18.
【6】WU Z G, SONG M, HE Y H.Effects of Er on the microstructure and mechanical properties of an as-extruded Al-Mg alloy[J].Materials Science and Engineering:A, 2009, 504(1/2):183-187.
【7】CHEN H H, WANG J Y, LEE J, et al.Superplasticity of AA5083 alloy as processed by equal channel angular extrusion[J].Journal of Alloys and Compounds, 2008, 460(1/2):305-308.
【8】ZHANG X, WANG Z H, ZHOU Z H, et al.Microstructure and mechanical property evolutions in Al-3.0 wt%Mg alloy wire drawing[J].Applied Physics A, 2018, 124(10):1-9.
【9】NARAYANAN K R, SUBBIAH S, SRIDHAR I.Indentation response of single-crystal copper using rate-independent crystal plasticity[J].Applied Physics A, 2011, 105(2):453-461.
【10】CAO T S, VACHEY C, MONTMITONNET P, et al.Comparison of reduction ability between multi-stage cold drawing and rolling of stainless steel wire:Experimental and numerical investigations of damage[J].Journal of Materials Processing Technology, 2015, 217:30-47.
【11】SHIN H J, JEONG H T, LEE D N.Deformation and annealing textures of silver wire[J].Materials Science and Engineering:A, 2000, 279(1/2):244-253.
【12】KUSTRA P, MILENIN A, BYRSKA-WÓJCIK D, et al.The process of ultra-fine wire drawing for magnesium alloy with the guaranteed restoration of ductility between passes[J].Journal of Materials Processing Technology, 2017, 247:234-242.
【13】KORCHEF A, KAHOUL A.Corrosion behavior of commercial aluminum alloy processed by equal channel angular pressing[J].International Journal of Corrosion, 2013, 2013:983261.
【14】AKIYAMA E, ZHANG Z G, WATANABE Y, et al.Effects of severe plastic deformation on the corrosion behavior of aluminum alloys[J].Journal of Solid State Electrochemistry, 2009, 13(2):277-282.
【15】ZHANG X, WANG Z H, ZHOU Z H, et al.Influence of rare earth (Ce and La) addition on the performance of Al-3.0 wt%Mg alloy[J].Journal of Wuhan University of Technology (Mater Sci Ed), 2017, 32(3):611-618.
【16】ZHANG X, WANG Z H, ZHOU Z H, et al.Effects of cerium and lanthanum on the corrosion behavior of Al-3.0Mg alloy[J].Journal of Materials Engineering and Performance, 2016, 25(3):1122-1128.
【17】毛卫民.金属材料的晶体学织构与各向异性[M].北京:科学出版社, 2002:11-15. MAO W M.Crystallographic texture and anisotropy of metallic materials[M].Beijing:Science Press, 2002:11-15.
【18】SIDOR J J, PETROV R H, KESTENS L A I.Microstructural and texture changes in severely deformed aluminum alloys[J].Materials Characterization, 2011, 62(2):228-236.
【19】付静波, 聂祚仁, 金头男, 等.微量稀土元素Er对1420合金织构的影响[J].金属热处理, 2006, 31(4):5-8. FU J B, NIE Z R, JIN T N, et al.Influence of trace rare earth element erbium on texture of 1420 alloy[J].Heat Treatment of Metals, 2006, 31(4):5-8.
【20】赖祖涵.金属的晶体缺陷与力学性质[M].北京:冶金工业出版社, 1988:266-268. LAI Z H. Crystallographic defects and mechanical properties of meals[M]. Beijing:Metallurgical Industry Press, 1988:266-268.
【21】HOU J P, WANG Q, YANG H J, et al.Microstructure evolution and strengthening mechanisms of cold-drawn commercially pure aluminum wire[J].Materials Science and Engineering:A, 2015, 639:103-106.
【2】CHEN X H, LIU J, ZHANG Z H, et al.Effect of heat treatment on electromagnetic shielding effectiveness of ZK60 magnesium alloy[J].Materials & Design, 2012, 42:327-333.
【3】DHAWAN S K, SINGH N, RODRIGUES D.Electromagnetic shielding behaviour of conducting polyaniline composites[J].Science and Technology of Advanced Materials, 2003, 4(2):105-113.
【4】甘雪萍, 胡文彬, 张青青, 等.电磁波屏蔽织物的发展现状[J].表面技术, 2006, 35(6):48-50. GAN X P, HU W B, ZHANG Q Q, et al.Development of conductive fabric for electromagnetic shielding[J].Surface Technology, 2006, 35(6):48-50.
【5】詹建朝, 张辉, 沈兰萍.涤纶织物化学镀镍的研究[J].上海纺织科技, 2006, 34(6):15-18. ZHAN J Z, ZHANG H, SHEN L P.Study on chemical nickel plating on PET fabric[J].Shanghai Textile Science & Technology, 2006, 34(6):15-18.
【6】WU Z G, SONG M, HE Y H.Effects of Er on the microstructure and mechanical properties of an as-extruded Al-Mg alloy[J].Materials Science and Engineering:A, 2009, 504(1/2):183-187.
【7】CHEN H H, WANG J Y, LEE J, et al.Superplasticity of AA5083 alloy as processed by equal channel angular extrusion[J].Journal of Alloys and Compounds, 2008, 460(1/2):305-308.
【8】ZHANG X, WANG Z H, ZHOU Z H, et al.Microstructure and mechanical property evolutions in Al-3.0 wt%Mg alloy wire drawing[J].Applied Physics A, 2018, 124(10):1-9.
【9】NARAYANAN K R, SUBBIAH S, SRIDHAR I.Indentation response of single-crystal copper using rate-independent crystal plasticity[J].Applied Physics A, 2011, 105(2):453-461.
【10】CAO T S, VACHEY C, MONTMITONNET P, et al.Comparison of reduction ability between multi-stage cold drawing and rolling of stainless steel wire:Experimental and numerical investigations of damage[J].Journal of Materials Processing Technology, 2015, 217:30-47.
【11】SHIN H J, JEONG H T, LEE D N.Deformation and annealing textures of silver wire[J].Materials Science and Engineering:A, 2000, 279(1/2):244-253.
【12】KUSTRA P, MILENIN A, BYRSKA-WÓJCIK D, et al.The process of ultra-fine wire drawing for magnesium alloy with the guaranteed restoration of ductility between passes[J].Journal of Materials Processing Technology, 2017, 247:234-242.
【13】KORCHEF A, KAHOUL A.Corrosion behavior of commercial aluminum alloy processed by equal channel angular pressing[J].International Journal of Corrosion, 2013, 2013:983261.
【14】AKIYAMA E, ZHANG Z G, WATANABE Y, et al.Effects of severe plastic deformation on the corrosion behavior of aluminum alloys[J].Journal of Solid State Electrochemistry, 2009, 13(2):277-282.
【15】ZHANG X, WANG Z H, ZHOU Z H, et al.Influence of rare earth (Ce and La) addition on the performance of Al-3.0 wt%Mg alloy[J].Journal of Wuhan University of Technology (Mater Sci Ed), 2017, 32(3):611-618.
【16】ZHANG X, WANG Z H, ZHOU Z H, et al.Effects of cerium and lanthanum on the corrosion behavior of Al-3.0Mg alloy[J].Journal of Materials Engineering and Performance, 2016, 25(3):1122-1128.
【17】毛卫民.金属材料的晶体学织构与各向异性[M].北京:科学出版社, 2002:11-15. MAO W M.Crystallographic texture and anisotropy of metallic materials[M].Beijing:Science Press, 2002:11-15.
【18】SIDOR J J, PETROV R H, KESTENS L A I.Microstructural and texture changes in severely deformed aluminum alloys[J].Materials Characterization, 2011, 62(2):228-236.
【19】付静波, 聂祚仁, 金头男, 等.微量稀土元素Er对1420合金织构的影响[J].金属热处理, 2006, 31(4):5-8. FU J B, NIE Z R, JIN T N, et al.Influence of trace rare earth element erbium on texture of 1420 alloy[J].Heat Treatment of Metals, 2006, 31(4):5-8.
【20】赖祖涵.金属的晶体缺陷与力学性质[M].北京:冶金工业出版社, 1988:266-268. LAI Z H. Crystallographic defects and mechanical properties of meals[M]. Beijing:Metallurgical Industry Press, 1988:266-268.
【21】HOU J P, WANG Q, YANG H J, et al.Microstructure evolution and strengthening mechanisms of cold-drawn commercially pure aluminum wire[J].Materials Science and Engineering:A, 2015, 639:103-106.
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