泡沫钛制备工艺及应用的研究进展
Research Progress on Preparation Technology and Application of Titanium Foam
摘 要
泡沫钛具有较小的密度、优异的力学性能以及独特的功能特性，广泛应用在航空航天、国防、海洋工程、汽车、生物医学等领域。介绍了泡沫钛的主要制备方法，包括烧结法、添加造孔剂法、浸渍法、凝胶浇铸法、3D打印法，对泡沫钛的压缩性能、吸能性能、生物相容性、电磁屏蔽性能、吸声性能、微动磨损性能等进行了讨论，并阐述了泡沫钛在生物医用、电池电极、航空航天等领域的应用前景。
制备方法
性能
应用前景
titanium foam
preparation method
property
application prospect
Abstract
Titanium foam is widely used in aerospace, military, marine engineering, automotive, biomedical, and other industries because it has low density, good mechanical properties, and unique functional features. The main preparation methods of titanium foam, such as sintering method, adding pore forming agent method, dipping method, gel casting method and 3D printing method are described. The compression properties, energy absorption properties, biocompatibility, electromagnetic shielding property, sound absorption property and fretting wear property, as well as its broad application prospect in the field of biomedicine, battery electrode and aerospace are discussed.
中图分类号 TG146.23 DOI 10.11973/jxgccl202201001
所属栏目 综述
基金项目 国家重点研发计划项目（2017YFB0103700）；江苏省大学生实践创新训练计划项目（202111276098H）；南京工程学院大学生科技创新基金项目（TB202102017）
收稿日期 2020/11/16
修改稿日期 2021/11/16
网络出版日期
作者单位点击查看
备注张振(1988-),男,河南周口人,副教授,博士
引用该论文: ZHANG Zhen,MA Yinghan,HU Zhengfei,TU Haoyun,BAI Jiaxu,DUAN Yuhang. Research Progress on Preparation Technology and Application of Titanium Foam[J]. Materials for mechancial engineering, 2022, 46(1): 1～6
张振,马颖涵,胡正飞,涂昊昀,白嘉旭,端宇航. 泡沫钛制备工艺及应用的研究进展[J]. 机械工程材料, 2022, 46(1): 1～6
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参考文献
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【22】MANONUKUL A,SRIKUDVIEN P,TANGE M.Microstructure and mechanical properties of commercially pure titanium foam with varied cell size fabricated by replica impregnation method[J].Materials Science and Engineering:A,2016,650:432-437.
【23】BIASETTO L,DE MORAES E G,COLOMBO P,et al.Ovalbumin as foaming agent for Ti6Al4V foams produced by gelcasting[J].Journal of Alloys and Compounds,2016,687:839-844.
【24】LUX J,GUZI DE MORAES E,MAIRE E,et al.Gas permeability of Ti6Al4V foams prepared via gelcasting,experiments and modelling[J].Computational Materials Science,2018,152:363-373.
【25】SHISHKOVSKY I V,VOLOVA L T,KUZNETSOV M V,et al.Porous biocompatible implants and tissue scaffolds synthesized by selective laser sintering from Ti and NiTi[J].Journal of Materials Chemistry,2008,18(12):1309.
【26】MATSUSHITA T,FUJIBAYASHI S,SASAKI K.Additive manufacturing in titanium metal:Porous devices for medical application[J].Journal of the Japan Society for Technology of Plasticity,2015,56(649):112-117.
【27】LI J P,HABIBOVIC P,VAN DEN DOEL M,et al.Bone ingrowth in porous titanium implants produced by 3D fiber deposition[J].Biomaterials,2007,28(18):2810-2820.
【28】MANONUKUL A,SRIKUDVIEN P,TANGE M,et al.Geometry anisotropy and mechanical property isotropy in titanium foam fabricated by replica impregnation method[J].Materials Science and Engineering:A,2016,655:388-395.
【29】KARAGEORGIOU V,KAPLAN D.Porosity of 3D biomaterial scaffolds and osteogenesis[J].Biomaterials,2005,26(27):5474-5491.
【30】TAKEMOTO M,FUJIBAYASHI S,NEO M,et al.A porous bioactive titanium implant for spinal interbody fusion:An experimental study using a canine model[J].Journal of Neurosurgery,2007,7(4):435-443.
【31】JAWED S F,RABADIA C D,LIU Y J,et al.Beta-type Ti-Nb-Zr-Cr alloys with large plasticity and significant strain hardening[J].Materials and Design,2019,181:108064.
【32】LIU P S, CUI G.Characterization of the electromagnetic shielding and compressive behavior of a highly porous titanium foam with spherical pores[J].Journal of Materials Research, 2015,30(22):3510-3517.
【33】LIU P S,QING H B,HOU H L,et al.EMI shielding and thermal conductivity of a high porosity reticular titanium foam[J].Materials & Design,2016,92:823-828.
【34】XU Z B,HAO H.Electromagnetic interference shielding effectiveness of aluminum foams with different porosity[J].Journal of Alloys and Compounds,2014,617:207-213.
【35】LIU P S,QING H B,HOU H L.Primary investigation on sound absorption performance of highly porous titanium foams[J].Materials & Design,2015,85:275-281.
【36】CHOI H,SHIL'KO S,GUBICZA J,et al.Study of the compression and wear-resistance properties of freeze-cast Ti and Ti-5W alloy foams for biomedical applications[J].Journal of the Mechanical Behavior of Biomedical Materials,2017,72:66-73.
【37】MAJUMDAR D D,GHOSH M,MONDAL D P,et al.Fretting wear resistance of titanium foam developed by powder metallurgy route[J].Procedia Manufacturing,2019,35:833-839.
【38】SADRNEZHAAD S K,HOSSEINI S A.Fabrication of porous NiTi-shape memory alloy objects by partially hydrided titanium powder for biomedical applications[J].Materials & Design,2009,30(10):4483-4487.
【39】SHBEH M,WALLY Z J,ELBADAWI M,et al.Incorporation of HA into porous titanium to form Ti-HA biocomposite foams[J].Journal of the Mechanical Behavior of Biomedical Materials,2019,96:193-203.
【40】ABHASH A,SINGH P,A N CH V,et al.Study of newly developed Ti-Al-Co alloys foams for bioimplant application[J].Materials Science and Engineering:A,2020,774:138910.
【41】LIAO Y C,SONG S M,LI T H,et al.Synthesis and characterization of an open-pore toxic-element-free Ti-based bulk metallic glass foam for bio-implant application[J].Journal of Materials Research and Technology,2020,9(3):4518-4526.
【42】DEVILLE S,SAIZ E,NALLA R K,et al.Freezing as a path to build complex composites[J].Science,2006,311(5760):515-518.
【43】PARK I K,AHN C Y,LEE J H,et al.Three-dimensionally interconnected titanium foam anode for an energy-efficient zero gap-type chlor-alkali electrolyzer[J].International Journal of Hydrogen Energy,2019,44(31):16079-16086.
【44】CHOI H,KIM O H,KIM M,et al.Next-generation polymer-electrolyte-membrane fuel cells using titanium foam as gas diffusion layer[J].ACS Applied Materials & Interfaces,2014,6(10):7665-7671.
【45】CHOI H,PARK H,UM J H,et al.Processing and characterization of titanium dioxide grown on titanium foam for potential use as Li-ion electrode[J].Applied Surface Science,2017,411:363-367.
【46】WANG Q Y,QIU L Y,TAN X Y,et al.Amorphous TiO2 granular nanodisks on porous Ti foam for highly effective solar cells and photocatalysts[J].Journal of the Taiwan Institute of Chemical Engineers,2019,102:85-91.
【47】WANG X L,LI Z W,ZHAO J L,et al.Preparation and synergistically enhanced supercapacitance properties of MnO2-PANI/Ti foam composite electrodes[J].Journal of Alloys and Compounds,2019,781:101-110.
【48】ZHANG Y W,YAN L L,ZHANG C,et al.Low-velocity impact response of tube-reinforced honeycomb sandwich structure[J].Thin-Walled Structures,2021,158:107188.
【2】SCHUH A,BIGONEY J,HÖNLE W,et al.Second generation (low modulus) titanium alloys in total hip arthroplasty[J].Materialwissenschaft und Werkstofftechnik,2007,38(12):1003-1007.
【3】BANHART J.Manufacture,characterisation and application of cellular metals and metal foams[J].Progress in Materials Science,2001,46(6):559-632.
【4】LIU P S,LIANG K M.Review Functional materials of porous metals made by P/M,electroplating and some other techniques[J].Journal of Materials Science,2001,36(21):5059-5072.
【5】LIU P S, CHEN G F. Porous materials:Processing and applications[M]. Boston:Elsevier Science, 2014:1-10.
【6】WEN C E,XIONG J Y,LI Y C,et al.Porous shape memory alloy scaffolds for biomedical applications:A review[J].Physica Scripta,2010,T139:014070.
【7】SIEGKAS P,TAGARIELLI V L,PETRINIC N,et al.The compressive response of a titanium foam at low and high strain rates[J].Journal of Materials Science,2011,46(8):2741-2747.
【8】MONDAL D P,DATTA MAJUMDER J,JHA N,et al.Titanium-cenosphere syntactic foam made through powder metallurgy route[J].Materials & Design,2012,34:82-89.
【9】RAO X,CHU C L,ZHENG Y Y.Phase composition,microstructure,and mechanical properties of porous Ti-Nb-Zr alloys prepared by a two-step foaming powder metallurgy method[J].Journal of the Mechanical Behavior of Biomedical Materials,2014,34:27-36.
【10】LEE B,LEE T,LEE Y,et al.Space-holder effect on designing pore structure and determining mechanical properties in porous titanium[J].Materials & Design,2014,57:712-718.
【11】张铭君,刘培生.泡沫钛的制备和性能研究进展[J].金属功能材料,2014,21(4):47-56. ZHANG M J,LIU P S.Research progress of foamed titanium in preparations and properties[J].Metallic Functional Materials,2014,21(4):47-56.
【12】TUCHINSKIY L, LOUTFY R. Metal foams and porous metal structures[M]. Bremen:MIT Press-Verlag, 1999.
【13】ZHANG X X,WEI L S.Processing and damping capacity of NiTi foams with laminated pore architecture[J].Journal of the Mechanical Behavior of Biomedical Materials,2019,96:108-117.
【14】杨倩倩,邵星海,刘源,等.陶瓷空心球/钛合金复合泡沫材料的制备与分析[J].铸造,2020,69(2):115-120. YANG Q Q,SHAO X H,LIU Y,et al.Preparation and analysis of ceramic hollow spheres/titanium alloy composite foam materials[J].Foundry,2020,69(2):115-120.
【15】XIAO J, QIU G B, LIAO Y L, et al. Microstructure and mechanical properties of titanium foams prepared with carbamide as spacer holder[J]. Rare Metal Materials and Engineering, 2015, 44(7):1724-1729.
【16】肖健,邱贵宝.大孔径高孔隙率烧结泡沫钛的造孔剂研究述评[J].中国材料进展,2018,37(5):372-378. XIAO J,QIU G B.Research review of space holders of sintered titanium foams with large pores and high porosity[J].Materials China,2018,37(5):372-378.
【17】王耀奇,王晓华,王哲磊,等.泡沫钛制备及力学性能评价研究[J].稀有金属材料与工程,2020,49(3):1051-1057. WANG Y Q,WANG X H,WANG Z L,et al.Preparation of titanium foam and mechanical properties evaluation[J].Rare Metal Materials and Engineering,2020,49(3):1051-1057.
【18】SHBEH M M,GOODALL R.Open pore titanium foams via metal injection molding of metal powder with a space holder[J].Metal Powder Report,2016,71(6):450-455.
【19】SALVO C,AGUILAR C,GUZMÁN D,et al.Mechanically enhanced novel Ti-based alloy foams obtained by hot pressing[J].Materials Science and Engineering:A,2019,759:112-123.
【20】XIE B,FAN Y Z,MU T Z,et al.Fabrication and energy absorption properties of titanium foam with CaCl2 as a space holder[J].Materials Science and Engineering:A,2017,708:419-423.
【21】TANGE M,MANONUKUL A,SRIKUDVIEN P.The effects of organic template and thickening agent on structure and mechanical properties of titanium foam fabricated by replica impregnation method[J].Materials Science and Engineering:A,2015,641:54-61.
【22】MANONUKUL A,SRIKUDVIEN P,TANGE M.Microstructure and mechanical properties of commercially pure titanium foam with varied cell size fabricated by replica impregnation method[J].Materials Science and Engineering:A,2016,650:432-437.
【23】BIASETTO L,DE MORAES E G,COLOMBO P,et al.Ovalbumin as foaming agent for Ti6Al4V foams produced by gelcasting[J].Journal of Alloys and Compounds,2016,687:839-844.
【24】LUX J,GUZI DE MORAES E,MAIRE E,et al.Gas permeability of Ti6Al4V foams prepared via gelcasting,experiments and modelling[J].Computational Materials Science,2018,152:363-373.
【25】SHISHKOVSKY I V,VOLOVA L T,KUZNETSOV M V,et al.Porous biocompatible implants and tissue scaffolds synthesized by selective laser sintering from Ti and NiTi[J].Journal of Materials Chemistry,2008,18(12):1309.
【26】MATSUSHITA T,FUJIBAYASHI S,SASAKI K.Additive manufacturing in titanium metal:Porous devices for medical application[J].Journal of the Japan Society for Technology of Plasticity,2015,56(649):112-117.
【27】LI J P,HABIBOVIC P,VAN DEN DOEL M,et al.Bone ingrowth in porous titanium implants produced by 3D fiber deposition[J].Biomaterials,2007,28(18):2810-2820.
【28】MANONUKUL A,SRIKUDVIEN P,TANGE M,et al.Geometry anisotropy and mechanical property isotropy in titanium foam fabricated by replica impregnation method[J].Materials Science and Engineering:A,2016,655:388-395.
【29】KARAGEORGIOU V,KAPLAN D.Porosity of 3D biomaterial scaffolds and osteogenesis[J].Biomaterials,2005,26(27):5474-5491.
【30】TAKEMOTO M,FUJIBAYASHI S,NEO M,et al.A porous bioactive titanium implant for spinal interbody fusion:An experimental study using a canine model[J].Journal of Neurosurgery,2007,7(4):435-443.
【31】JAWED S F,RABADIA C D,LIU Y J,et al.Beta-type Ti-Nb-Zr-Cr alloys with large plasticity and significant strain hardening[J].Materials and Design,2019,181:108064.
【32】LIU P S, CUI G.Characterization of the electromagnetic shielding and compressive behavior of a highly porous titanium foam with spherical pores[J].Journal of Materials Research, 2015,30(22):3510-3517.
【33】LIU P S,QING H B,HOU H L,et al.EMI shielding and thermal conductivity of a high porosity reticular titanium foam[J].Materials & Design,2016,92:823-828.
【34】XU Z B,HAO H.Electromagnetic interference shielding effectiveness of aluminum foams with different porosity[J].Journal of Alloys and Compounds,2014,617:207-213.
【35】LIU P S,QING H B,HOU H L.Primary investigation on sound absorption performance of highly porous titanium foams[J].Materials & Design,2015,85:275-281.
【36】CHOI H,SHIL'KO S,GUBICZA J,et al.Study of the compression and wear-resistance properties of freeze-cast Ti and Ti-5W alloy foams for biomedical applications[J].Journal of the Mechanical Behavior of Biomedical Materials,2017,72:66-73.
【37】MAJUMDAR D D,GHOSH M,MONDAL D P,et al.Fretting wear resistance of titanium foam developed by powder metallurgy route[J].Procedia Manufacturing,2019,35:833-839.
【38】SADRNEZHAAD S K,HOSSEINI S A.Fabrication of porous NiTi-shape memory alloy objects by partially hydrided titanium powder for biomedical applications[J].Materials & Design,2009,30(10):4483-4487.
【39】SHBEH M,WALLY Z J,ELBADAWI M,et al.Incorporation of HA into porous titanium to form Ti-HA biocomposite foams[J].Journal of the Mechanical Behavior of Biomedical Materials,2019,96:193-203.
【40】ABHASH A,SINGH P,A N CH V,et al.Study of newly developed Ti-Al-Co alloys foams for bioimplant application[J].Materials Science and Engineering:A,2020,774:138910.
【41】LIAO Y C,SONG S M,LI T H,et al.Synthesis and characterization of an open-pore toxic-element-free Ti-based bulk metallic glass foam for bio-implant application[J].Journal of Materials Research and Technology,2020,9(3):4518-4526.
【42】DEVILLE S,SAIZ E,NALLA R K,et al.Freezing as a path to build complex composites[J].Science,2006,311(5760):515-518.
【43】PARK I K,AHN C Y,LEE J H,et al.Three-dimensionally interconnected titanium foam anode for an energy-efficient zero gap-type chlor-alkali electrolyzer[J].International Journal of Hydrogen Energy,2019,44(31):16079-16086.
【44】CHOI H,KIM O H,KIM M,et al.Next-generation polymer-electrolyte-membrane fuel cells using titanium foam as gas diffusion layer[J].ACS Applied Materials & Interfaces,2014,6(10):7665-7671.
【45】CHOI H,PARK H,UM J H,et al.Processing and characterization of titanium dioxide grown on titanium foam for potential use as Li-ion electrode[J].Applied Surface Science,2017,411:363-367.
【46】WANG Q Y,QIU L Y,TAN X Y,et al.Amorphous TiO2 granular nanodisks on porous Ti foam for highly effective solar cells and photocatalysts[J].Journal of the Taiwan Institute of Chemical Engineers,2019,102:85-91.
【47】WANG X L,LI Z W,ZHAO J L,et al.Preparation and synergistically enhanced supercapacitance properties of MnO2-PANI/Ti foam composite electrodes[J].Journal of Alloys and Compounds,2019,781:101-110.
【48】ZHANG Y W,YAN L L,ZHANG C,et al.Low-velocity impact response of tube-reinforced honeycomb sandwich structure[J].Thin-Walled Structures,2021,158:107188.
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