Determination of Moisture in Aerosol of Heated Not Burned Cigarette by Gas Chromatography with Filters Trap
摘 要
基于加热卷烟抽吸前后水分转移规律,分析了环境条件、抽吸参数和滤片捕集能力等对加热卷烟气溶胶中水分测定值的影响,提出了滤片捕集-气相色谱法(GC)测定加热卷烟气溶胶中水分含量的方法。利用吸烟机,按照抽吸容量35 mL,抽吸间隔30 s,每支卷烟抽吸7口的条件对加热卷烟进行抽吸;抽吸结束后,取出一张剑桥滤片(直径44 mm),捕集加热卷烟气溶胶,每个滤片捕集5支卷烟;再用四分之一块的新剑桥滤片擦拭捕集器,将所有使用过的滤片放入100 mL的圆底瓶中,迅速加入20 mL萃取剂(由1 000.00 mL异丙醇和5.00 mL无水乙醇混合而成),密封,以150次·min-1的速率振荡萃取30 min,得到的萃取液进行GC测定。结果显示:水的质量浓度在8.0 g·L-1以内与其对应的峰面积与内标(乙醇)峰面积的比值呈线性关系,检出限(3S/N)为0.154 mg·支-1;对实际样品进行加标回收试验,回收率为98.4%~101%。方法用于实际加热卷烟分析,气溶胶中水分测定值为10.71~22.50 mg·支-1,测定值的相对标准偏差(n=5)均小于2.0%。
Abstract
Based on the principle of moisture conservation in the heated not burn cigarettes before and after smoking, the effects of environmental conditions, puff parameters and filter capacity on the determined values of moisture in aerosol of heated not burned cigarette were analyzed, then a method for the determination of the moisture in aerosol of heated not burned cigarette by gas chromatography (GC) with filters trap was proposed. Heated not burned cigarettes were smoked by suction machine at the conditions of puff capacity of 35 mL, puff interval of 30 s and each cigarette puff number of 7. After smoking, Cambridge filter (diameter of 44 mm) was used to capture the aerosol of heated not burned cigarettes, and each filter captured 5 cigarettes. The quarter of new Cambridge filter was used to wipe the trap machine. Then the all filters used were put into a 100 mL round-bottom bottle and 20 mL of extraction agent (1 000.00 mL isopropyl alcohol mixed with 5.00 mL anhydrous ethanol) were quickly added. Then the above solution was sealed and vibrating extracted at a rate of 150 times·min-1 for 30 min. The extraction solution was determined by GC. As shown by the results, linear relationship between value of mass concentration of moisture and ratios of its peak area to internal standard (ethanol) peak area was kept within 8.0 g·L-1, with detection limit (3S/N) of 0.154 mg·cig-1. Test for recovery was made on actual sample at 3 concentration levels by standard addition method, giving results in the range of 98.4%-101%. This method has been used to analyze the heated not burned cigarettes. The determined values of moisture in aerosol of heated not burned cigarettes were in the range of 10.71-22.50 mg·cig-1, and RSDs (n=5) of the determined values were less than 2.0%.
中图分类号 O657.71 DOI 10.11973/lhjy-hx202204005
所属栏目 工作简报
基金项目 河南中烟项目(ZW201907)
收稿日期 2020/10/13
修改稿日期
网络出版日期
作者单位点击查看
联系人作者张孟伟(zoro_mw@163.com)
备注邱建华,高级工程师,硕士,主要从事卷烟及烟气分析研究
引用该论文: QIU Jianhua,HE Jingyu,LI Qian,YUAN Qishan,HE Wenjie,LIU Wenzhao,ZHANG Mengwei. Determination of Moisture in Aerosol of Heated Not Burned Cigarette by Gas Chromatography with Filters Trap[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2022, 58(4): 400~405
邱建华,何静宇,李倩,袁岐山,何文婕,刘文召,张孟伟. 滤片捕集-气相色谱法测定加热卷烟气溶胶中水分的含量[J]. 理化检验-化学分册, 2022, 58(4): 400~405
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参考文献
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【13】张洪非,姜兴益,庞永强,等.两种抽吸模式下加热不燃烧卷烟主流烟气释放物分析[J].烟草科技, 2018,51(9):40-48.
【2】HUGHES J R, KEELY J P. The effect of a novel smoking system-Accord-on ongoing smoking and toxin exposure[J]. Nicotine&Tobacco Research, 2004,6(6):1021-1027.
【3】KOGEL U, SCHLAGE W K, MARTIN F, et al. A 28-day rat inhalation study with an integrated molecular toxicology endpoint demonstrates reduced exposure effects for a prototypic modified risk tobacco product compared with conventional cigarettes[J]. Food and Chemical Toxicology, 2014,68:204-217.
【4】HOFFMANN D, HOFFMANN I. The changing cigarette, 1950-1995[J]. Journal of Toxicology and Environmental Health, 1997,50(4):307-364.
【5】李翔,谢复炜,刘惠民.新型烟草制品毒理学评价研究进展[J].烟草科技, 2016,49(1):88-93.
【6】王康,柳均,肖少红,等.GC-TCD法同时检测加热不燃烧卷烟气溶胶水分,及烟碱、丙三醇、1,2-丙二醇、三乙酸甘油酯和薄荷醇的释放量[J].烟草科技, 2019,52(3):63-68.
【7】杨继,杨帅,段沅杏,等.加热不燃烧卷烟烟草材料的热分析研究[J].中国烟草学报, 2015,21(6):7-13.
【8】张丽,王维维,张小涛,等.气相色谱法测定新型卷烟气溶胶中水、烟碱、1,2-丙二醇和丙三醇的含量[J].理化检验-化学分册, 2018,54(10):1188-1193.
【9】李朝建,刘献军,庄亚东,等.卷烟主流烟气水分的检测及影响因素分析[C]//中国烟草学会2017年学术年会论文集.北京, 2017:910-919.
【10】李朝建,金勇,周成喜,等.水分含量对不同类型加热不燃烧卷烟化学成分的影响[J].食品与机械, 2019,35(10):35-39.
【11】肯生叶,温光和,杨雪燕,等.GC-TCD法同时检测加热不燃烧卷烟烟草材料中的水分、1,2-丙二醇、烟碱和丙三醇[J].烟草科技, 2020,53(5):41-46.
【12】中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.卷烟总粒相物中水分的测定第1部分:气相色谱法:GB/T 23203.1-2008[S].北京:中国标准出版社, 2009.
【13】张洪非,姜兴益,庞永强,等.两种抽吸模式下加热不燃烧卷烟主流烟气释放物分析[J].烟草科技, 2018,51(9):40-48.
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