Applicability of 3 Stainless Steels in H2S/CO2 and High Salinity Brine Environment
摘 要
通过高温高压模拟试验,现场挂片试验,电化学试验,腐蚀形貌观察等研究了普通马氏体不锈钢13Cr、超级马氏体不锈钢HP2-13Cr和双相不锈钢22Cr在含CO2、H2S高矿化度油气水多相流中的耐蚀性,探究了原油对不锈钢耐蚀性尤其是点蚀机制的影响。结果表明:经过90 d现场挂片试验后,13Cr、HP2-13Cr和22Cr的均匀腐蚀速率分别为0.107 7 mm/a、0.099 4 mm/a和0.003 4 mm/a;在H2S饱和溶液中,HP2-13Cr比22Cr更容易钝化;在不含H2S环境中HP2-13Cr的再活化率比22Cr高,充入饱和H2S后,HP2-13Cr的再活化率低于22Cr。在含原油、H2S、CO2、Cl-及水的环境中,13Cr会发生局部腐蚀,22Cr会产生点蚀,HP2-13Cr会发生均匀腐蚀。
Abstract
The corrosion resistance of ordinary martensitic stainless steel 13Cr, super martensitic stainless steel HP2-13Cr and duplex stainless steel 22Cr in high salinity oil-gas-water multiphase flow containing CO2 and H2S was studied through high temperature and high pressure simulation test, field coupon test, electrochemical test, and corrosion morphology observation. The effect of crude oil on the corrosion resistance of stainless steel, especially on the pitting mechanism, was explored. The results showed that the uniform corrosion rates of 13Cr, HP2-13Cr and 22Cr were 0.107 7 mm/a, 0.099 4 mm/a and 0.003 4 mm/a, respectively, after a 90 day field coupon test. In H2S saturated solution, HP2-13Cr was easier to passivate than 22Cr; the reactivation rate of HP2-13Cr was higher than that of 22Cr in H2S-free environment, and the reactivation rate of HP2-13Cr was lower than that of 22Cr after being aerated with saturated H2S. In the environment containing crude oil, H2S, CO2, Cl- and water, 13Cr suffered localized corrosion, 22Cr suffered pitting, and HP2-13Cr suffered uniform corrosion.
中图分类号 TG174 DOI 10.11973/fsyfh-202204002
所属栏目 试验研究
基金项目 国家自然科学基金青年基金(51604289)
收稿日期 2020/3/23
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引用该论文: LI Lei,LI Zhong,LIU Hexing,DENG Jingen,LIU Hailong,YAN Wei,XIANG Yong,WU Jianshu. Applicability of 3 Stainless Steels in H2S/CO2 and High Salinity Brine Environment[J]. Corrosion & Protection, 2022, 43(4): 7
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参考文献
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【3】MLYSSAKA A,DENPO K,OGAWA H. Corrosion and cracking of steel in production of gas with liquid H2S and brine[J]. SPE Production Engineering,1988,3(4):579-583.
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【5】KERMANI B,ESAKLUL K,MARTIN J. Materials design strategy:effects of H2S/CO2 corrosion on materials selection[C]//[S.l.]:[s.n.],2006.
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【7】MU L J,ZHAO W Z. Investigation on carbon dioxide corrosion behaviour of HP13Cr110 stainless steel in simulated stratum water[J]. Corrosion Science,2010,52(1):82-89.
【8】FISCHMEISTER H,ROLL U. Passivschichten auf rostfreien stählen:eineübersichtüber oberflächenanalytische ergebnisse[J]. Fresenius' Zeitschrift Für Analytische Chemie,1984,319(6/7):639-645.
【9】OLSSON C O A,LANDOLT D. Passive films on stainless steels-chemistry,structure and growth[J]. Electrochimica Acta,2003,48(9):1093-1104.
【10】SIDORIN D,PLETCHER D,HEDGES B. The electrochemistry of 13% chromium stainless steel in oilfield brines[J]. Electrochimica Acta,2005,50(20):4109-4116.
【11】SHU J,BI H Y,LI X,et al. The effect of copper and molybdenum on pitting corrosion and stress corrosion cracking behavior of ultra-pure ferritic stainless steels[J]. Corrosion Science,2012,57:89-98.
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【13】CHENG X L,MA H Y,CHEN S H,et al. Electrochemical behaviour of chromium in acid solutions with H2S[J]. Corrosion Science,1999,41(4):773-788.
【14】GARFIAS-MESIAS L F,SYKES J M,TUCK C D S. The effect of phase compositions on the pitting corrosion of 25 Cr duplex stainless steel in chloride solutions[J]. Corrosion Science,1996,38(8):1319-1330.
【15】SHUJI H,KATSUMI M,KAZUO Y. Performance of High Strength Super 13% Cr Martensitic Stainless Steels.
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