Influences of CO2 Partial Pressure and Salinity on Corrosion of J55 Steel Tubing
摘 要
采用高温高压釜模拟CO2驱油工况,通过失重法测得J55管材钢在CO2驱油注采环境中的腐蚀速率,采用扫描电镜(SEM)、X射线衍射仪(XRD)、EDS能谱对腐蚀产物的形貌与成分进行分析,考察了CO2分压和矿化度对J55管材的腐蚀影响。结果表明:模拟CO2驱工况下,J55钢在CO2分压为0~25 MPa时,气、液相的腐蚀速率均超过0.076 mm/a的标准要求,CO2分压为10 MPa时,其腐蚀速率高达7.047 mm/a,腐蚀产物由FeCO3和FeS组成;Cl-浓度增加会使溶液矿化度增大,并导致腐蚀介质电导率增大、电荷传输速率加快,从而加剧腐蚀,腐蚀结垢产物呈增加趋势,平均腐蚀程度逐渐减小,但点蚀增加。
Abstract
The high temperature autoclave was used to simulate the CO2 flooding condition, and the corrosion rate of J55 tubular steel in the CO2 flooding oil injection and production environment was measured by the weight loss method. Scanning electron microscopy (SEM), X-ray diffractometer (XRD), and EDS energy spectrum were used to analyze the morphology and composition of corrosion products, and the effects of CO2 partial pressure and salinity on the corrosion of J55 pipes were investigated. The results showed that under the simulated CO2 flooding condition, when the CO2 partial pressure of J55 steel was 0-25 MPa, the corrosion rates of the gas and liquid phases both exceed the standard requirement of 0.076 mm/a. When the partial pressure of CO2 was 10 MPa, the corrosion rate was high as 7.047 mm/a, and the corrosion products were composed of FeCO3 and FeS. The increase of Cl- concentration would increase the salinity of the solution, and led to the increase of the conductivity of the corrosion medium and the acceleration of the charge transfer rate, thereby intensifying the corrosion, the corrosion and scaling products showed an increasing trend, the average corrosion degree gradually decreased, but the pitting increased.
中图分类号 TG172.8 DOI 10.11973/fsyfh-202210008
所属栏目 试验研究
基金项目 国家重点研发计划(2018YFB0605502)
收稿日期 2021/12/15
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联系人作者于海(lh820616@126.com)
引用该论文: LI Hui,YU Hai,LIU Xiaoqing,LIU Xingyue. Influences of CO2 Partial Pressure and Salinity on Corrosion of J55 Steel Tubing[J]. Corrosion & Protection, 2022, 43(10): 51
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