回火硬度对4Cr5Mo2V钢抗铝液熔损性能的影响
Effect of Tempering Hardness on Erosion Resistance of 4Cr5Mo2V Steel inMolten Aluminum
摘 要
通过淬火和不同工艺的回火热处理得到不同回火硬度(41.2,45.0,49.3 HRC)的4Cr5Mo2V钢,采用试样在熔融铝合金中动态旋转的方法研究了回火硬度对该钢抗铝液熔损性能的影响。结果表明:随着回火硬度的升高,在相同熔损时间内试验钢的熔损质量损失降低;随着熔损时间的延长,试验钢迎铝面先形成细密点蚀坑,随后出现局部剥落以及局部严重腐蚀,最后发生全面腐蚀;界面层的金属间化合物由内层致密的η-Fe2Al5相和外层疏松多孔的αH-Fe2Al8Si相组成;随着回火硬度的升高,背铝面界面层内层厚度增大,外层占比降低,基体中固溶铬元素增多,试验钢的抗铝液熔损性能提高。
回火硬度
铝合金液
抗熔损性能
金属间化合物
hot work die steel
tempering hardness
aluminum alloy
erosion resistance
intermetallic compound
Abstract
4Cr5Mo2V steel with different hardness (41.2, 45.0, 49.3 HRC) was obtained by quenching and different tempering heat treatment processes. The effect of tempering hardness on the erosion resistance of the steel in molten aluminum was studied by making the samples rotate dynamically in the molten aluminum alloy. The results show that with increasing tempering hardness, the erosion mass loss of the test steel for the same erosion time decreased. With the extension of erosion time, fine pitting pits appeared on the face-aluminum surface of the test steel first, and then partly peeling and partly severe corrosion appeared, and finally comprehensive corrosion occurred. The intermetallic compound of the interface layer consisted of a dense η-Fe2Al5 phase inner layer and a porous αH-Fe2Al8Si phase outer layer. With increasing tempering hardness, the thickness of the inner layer of back-aluminum surface increased gradually, and the proportion of the outer layer decreased gradually, the chromium content in the matrix increased, resulting in the improvement of erosion resistance of the test steel in the molten aluminum alloy.
中图分类号 TG142 DOI doi: 10.11973/jxgccl202303009
所属栏目 材料性能及应用
基金项目 广东省重点领域研发计划项目(2020B010184002);省部共建高品质特殊钢冶金与制备国家重点实验室自主课题项目(SKLASS2020-Z08)
收稿日期 2022/2/28
修改稿日期 2023/2/28
网络出版日期
作者单位点击查看
备注楼通海(1997-),男,浙江诸暨人,硕士研究生
引用该论文: LOU Tonghai,ZUO Pengpeng,WU Xiaochun. Effect of Tempering Hardness on Erosion Resistance of 4Cr5Mo2V Steel inMolten Aluminum[J]. Materials for mechancial engineering, 2023, 47(3): 48～54
楼通海,左鹏鹏,吴晓春. 回火硬度对4Cr5Mo2V钢抗铝液熔损性能的影响[J]. 机械工程材料, 2023, 47(3): 48～54
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参考文献
【1】夏书文,左鹏鹏,吴晓春.国内外压铸模具钢发展概述[J].模具制造,2017,17(7):93-99. XIA S W,ZUO P P,WU X C.Development of die-casting die steels at home and abroad[J].Die & Mould Manufacture,2017,17(7):93-99.
【2】肖华强,陈禹伽,陈维平,等.材料在铝液中熔蚀-磨损行为的研究进展[J].材料导报,2020,34(7):7123-7129. XIAO H Q,CHEN Y J,CHEN W P,et al.Research progress on corrosion-wear behavior of materials in molten aluminum[J].Materials Reports,2020,34(7):7123-7129.
【3】CHEN G,WANG J,FAN H Y,et al.Combat molten aluminum corrosion of AISI H13 steel by low-temperature liquid nitrocarburizing[J].Journal of Alloys and Compounds,2019,776:702-711.
【4】杨浩鹏,吴晓春.H13钢低温固体渗硼及其热熔损性能的研究[J].上海金属,2019,41(4):23-28. YANG H P,WU X C.Study on the low-temperature pack boriding and erosion property of H13 steel[J].Shanghai Metals,2019,41(4):23-28.
【5】CHANG S H,TANG T P,HUANG K T.Improvement of aluminum erosion behavior and corrosion resistance of AISI H13 tool steel by oxidation treatment[J].ISIJ International,2010,50(4):569-573.
【6】RAMOS-MASANA A,COLOMINAS C.Evaluation of DC-MS and HiPIMS TiB2 and TaN coatings as diffusion barriers against molten aluminum:An insight into the wetting mechanism[J].Surface and Coatings Technology,2019,375:171-181.
【7】VACHHANI H,RATHOD M, SHAH R.Dissolution and erosion behavior of AISI H13 shot sleeve in high pressure die casting process[J].Engineering Failure Analysis,2019,101:206-214.
【8】张宇,黄泽军,张恒华,等.钴和镍对4Cr5Mo2V压铸模具钢抗热损伤性能的影响[J].上海金属,2021,43(2):7-12. ZHANG Y,HUANG Z J,ZHANG H H,et al.Effect of cobalt and nickel on resistance to thermal damage of 4Cr5Mo2V die-casting die steel[J].Shanghai Metals,2021,43(2):7-12.
【9】陈维平,刘路生,张先满,等.热处理对Fe-Cr-B铸钢组织和耐铝液腐蚀性能的影响[J].铸造,2017,66(1):58-63. CHEN W P,LIU L S,ZHANG X M,et al.Effect of heat treatment on microstructure and corrosion resistance in molten aluminum of Fe-Cr-B cast steel[J].Foundry,2017,66(1):58-63.
【10】KIM J H,KIM S Y, KANG C Y.Effect of phase difference on growth kinetic of alloy layer in aluminized and diffusion-treated 12% Cr heating resistant steels[J].Surface and Coatings Technology,2014,240:387-392.
【11】YU M,SHIVPURI R,RAPP R A.Effects of molten aluminum on H13 dies and coatings[J].Journal of Materials Engineering and Performance,1995,4(2):175-181.
【12】YAN M,FAN Z.The erosion of H21 tool steel in molten A380 alloy[J].Journal of Materials Science,2000,35(7):1661-1667.
【13】CHEN Z W, FRASER D T, JAHEDI M Z,et al.Structures of intermetallic phases formed during immersion of H13 tool steel in an Al-11Si-3Cu die casting alloy melt[J].Materials Science and Engineering:A,1999,260(1/2):188-196.
【14】黄苏起,李玲,吴晓春.新型热作模具钢4Cr3Mn1Mo2V的抗铝熔损性能[J].材料热处理学报,2021,42(8):91-98. HUANG S Q,LI L,WU X C.Erosion resistance of new hot working die steel 4Cr3Mn1Mo2V in molten aluminum[J].Transactions of Materials and Heat Treatment,2021,42(8):91-98.
【15】HU X B, LI L, WU X C, et al.Coarsening behavior of M23C6 carbides after ageing or thermal fatigue in AISI H13 steel with niobium[J].International Journal of Fatigue,2006,28(3):175-182.
【16】王要利.4Cr5MoSiV1(Ti)组织性能调控及损伤机理研究[D].洛阳:河南科技大学,2020. WANG Y L.Regulation of microstructure and properties and damage mechanism study for 4Cr5MoSiV1(Ti)[D].Luoyang:Henan University of Science and Technology,2020.
【17】左鹏鹏.压铸模具钢热机械疲劳行为及损伤机理研究[D].上海:上海大学,2018. ZUO P P.Research on thermomechanical fatigue behavior and damage mechanism of die-casting die steel[D].Shanghai:Shanghai University,2018.
【18】张先满,陈再雨,罗洪峰.合金元素对Fe/Al界面反应影响的研究进展[J].材料导报,2021,35(7):7145-7154. ZHANG X M,CHEN Z Y,LUO H F.Influences of alloying elements on the interfacial reaction of Fe/Al:A review[J].Materials Reports,2021,35(7):7145-7154.
【19】ZHANG X M, CHEN W P, LUO H F, et al.Corrosion resistance and interfacial morphologies of novel Fe-Cr-Mo-B cast steels in molten aluminum[J].Corrosion Science,2017,125:20-28.
【20】CHENG W J, WANG C J.Effect of chromium on the formation of intermetallic phases in hot-dipped aluminide Cr-Mo steels[J].Applied Surface Science,2013,277:139-145.
【2】肖华强,陈禹伽,陈维平,等.材料在铝液中熔蚀-磨损行为的研究进展[J].材料导报,2020,34(7):7123-7129. XIAO H Q,CHEN Y J,CHEN W P,et al.Research progress on corrosion-wear behavior of materials in molten aluminum[J].Materials Reports,2020,34(7):7123-7129.
【3】CHEN G,WANG J,FAN H Y,et al.Combat molten aluminum corrosion of AISI H13 steel by low-temperature liquid nitrocarburizing[J].Journal of Alloys and Compounds,2019,776:702-711.
【4】杨浩鹏,吴晓春.H13钢低温固体渗硼及其热熔损性能的研究[J].上海金属,2019,41(4):23-28. YANG H P,WU X C.Study on the low-temperature pack boriding and erosion property of H13 steel[J].Shanghai Metals,2019,41(4):23-28.
【5】CHANG S H,TANG T P,HUANG K T.Improvement of aluminum erosion behavior and corrosion resistance of AISI H13 tool steel by oxidation treatment[J].ISIJ International,2010,50(4):569-573.
【6】RAMOS-MASANA A,COLOMINAS C.Evaluation of DC-MS and HiPIMS TiB2 and TaN coatings as diffusion barriers against molten aluminum:An insight into the wetting mechanism[J].Surface and Coatings Technology,2019,375:171-181.
【7】VACHHANI H,RATHOD M, SHAH R.Dissolution and erosion behavior of AISI H13 shot sleeve in high pressure die casting process[J].Engineering Failure Analysis,2019,101:206-214.
【8】张宇,黄泽军,张恒华,等.钴和镍对4Cr5Mo2V压铸模具钢抗热损伤性能的影响[J].上海金属,2021,43(2):7-12. ZHANG Y,HUANG Z J,ZHANG H H,et al.Effect of cobalt and nickel on resistance to thermal damage of 4Cr5Mo2V die-casting die steel[J].Shanghai Metals,2021,43(2):7-12.
【9】陈维平,刘路生,张先满,等.热处理对Fe-Cr-B铸钢组织和耐铝液腐蚀性能的影响[J].铸造,2017,66(1):58-63. CHEN W P,LIU L S,ZHANG X M,et al.Effect of heat treatment on microstructure and corrosion resistance in molten aluminum of Fe-Cr-B cast steel[J].Foundry,2017,66(1):58-63.
【10】KIM J H,KIM S Y, KANG C Y.Effect of phase difference on growth kinetic of alloy layer in aluminized and diffusion-treated 12% Cr heating resistant steels[J].Surface and Coatings Technology,2014,240:387-392.
【11】YU M,SHIVPURI R,RAPP R A.Effects of molten aluminum on H13 dies and coatings[J].Journal of Materials Engineering and Performance,1995,4(2):175-181.
【12】YAN M,FAN Z.The erosion of H21 tool steel in molten A380 alloy[J].Journal of Materials Science,2000,35(7):1661-1667.
【13】CHEN Z W, FRASER D T, JAHEDI M Z,et al.Structures of intermetallic phases formed during immersion of H13 tool steel in an Al-11Si-3Cu die casting alloy melt[J].Materials Science and Engineering:A,1999,260(1/2):188-196.
【14】黄苏起,李玲,吴晓春.新型热作模具钢4Cr3Mn1Mo2V的抗铝熔损性能[J].材料热处理学报,2021,42(8):91-98. HUANG S Q,LI L,WU X C.Erosion resistance of new hot working die steel 4Cr3Mn1Mo2V in molten aluminum[J].Transactions of Materials and Heat Treatment,2021,42(8):91-98.
【15】HU X B, LI L, WU X C, et al.Coarsening behavior of M23C6 carbides after ageing or thermal fatigue in AISI H13 steel with niobium[J].International Journal of Fatigue,2006,28(3):175-182.
【16】王要利.4Cr5MoSiV1(Ti)组织性能调控及损伤机理研究[D].洛阳:河南科技大学,2020. WANG Y L.Regulation of microstructure and properties and damage mechanism study for 4Cr5MoSiV1(Ti)[D].Luoyang:Henan University of Science and Technology,2020.
【17】左鹏鹏.压铸模具钢热机械疲劳行为及损伤机理研究[D].上海:上海大学,2018. ZUO P P.Research on thermomechanical fatigue behavior and damage mechanism of die-casting die steel[D].Shanghai:Shanghai University,2018.
【18】张先满,陈再雨,罗洪峰.合金元素对Fe/Al界面反应影响的研究进展[J].材料导报,2021,35(7):7145-7154. ZHANG X M,CHEN Z Y,LUO H F.Influences of alloying elements on the interfacial reaction of Fe/Al:A review[J].Materials Reports,2021,35(7):7145-7154.
【19】ZHANG X M, CHEN W P, LUO H F, et al.Corrosion resistance and interfacial morphologies of novel Fe-Cr-Mo-B cast steels in molten aluminum[J].Corrosion Science,2017,125:20-28.
【20】CHENG W J, WANG C J.Effect of chromium on the formation of intermetallic phases in hot-dipped aluminide Cr-Mo steels[J].Applied Surface Science,2013,277:139-145.
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