Effect of Raw Material Powder Particle Size on Microstructure and Magnetic Properties of NiCuZn Soft Magnetic Ferrite
摘 要
通过改变二次球磨时间(1~6 h)调控原料粉体粒径,采用固相烧结法制备NiCuZn软磁铁氧体,研究了原料粉体粒径对软磁铁氧体微观结构和磁性能的影响。结果表明:粉体粒径随着二次球磨时间的延长而减小,尺寸分布逐渐集中;制备的软磁铁氧体晶粒尺寸的均匀性先变好后变差,晶界先变清晰后变模糊;随着粉体粒径的减小,NiCuZn软磁铁氧体的起始磁导率、饱和磁感应强度、相对密度及电阻率均先增大后减小,功率损耗先减小后增大;当二次球磨时间为3 h时,粉体粒径主要集中在2.5~3.5 μm,平均粒径为3.237 μm,烧结制备的软磁铁氧体的晶界较为清晰,晶粒尺寸均匀,起始磁导率、饱和磁感应强度最大,分别为1 385 H·m-1和360 mT,功率损耗最小,为284 kW·m-3。
Abstract
NiCuZn soft magnetic ferrite was prepared by solid state sintering with raw powder of different particle size prepared by changing the secondary ball milling time (1-6 h). The effect of the particle size on the microstructure and magnetic properties of the soft magnetic ferrite was studied. The results show that the powder particle size decreased with the extension of secondary ball milling time, and the size distribution gradually concentrated. The uniformity of grain size of soft magnetic ferrite prepared became better and then worse, and the grain boundary became clear and then blurred. With the decrease of the powder particle size, the initial permeability, saturation magnetic induction intensity, relative density and resistivity of the soft magnetic ferrite increased first and then decreased, and the power loss decreased first and then increased. When the secondary ball milling time was 3 h, the powder partide size was mainly between 2.5-3.5 μm, with average particle size of 3.237 μm. At this time, the grain boundary of the prepared soft magnetic ferrite was relatively clear, and the grain size was relatively uniform. The initial permeability and saturation magnetic induction intensity reached the maximum value of 1385 H·m-1 and 360 mT, respectively, and the power loss reached the minimum value of 284 kW · m-3.
中图分类号 TM277 DOI 10.11973/jxgccl202304012
所属栏目 材料性能及应用
基金项目 国家电网公司科技项目(5500-202058311A-0-0-00)
收稿日期 2022/3/27
修改稿日期 2023/2/16
网络出版日期
作者单位点击查看
联系人作者曹正锋
备注陈川(1984-),男,北京人,高级工程师,博士
引用该论文: CHEN Chuan,ZHANG Qiang,CAO Zhengfeng. Effect of Raw Material Powder Particle Size on Microstructure and Magnetic Properties of NiCuZn Soft Magnetic Ferrite[J]. Materials for mechancial engineering, 2023, 47(4): 61~66
陈川,张强,曹正锋. 原料粉体粒径对NiCuZn软磁铁氧体微观结构和磁性能的影响[J]. 机械工程材料, 2023, 47(4): 61~66
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【2】张晓梦,刘延辉,李忠,等.铁氧体含量对Fe/NiZnFe2O4铁粉芯磁性能的影响[J].功能材料,2019,50(1):1031-1034. ZHANG X M,LIU Y H,LI Z,et al.Effect of ferrite content on magnetic properties of Fe/NiZnFe2O4 powder core[J].Journal of Functional Materials,2019,50(1):1031-1034.
【3】张变芳,刘力虎.NiCuZn铁氧体的制备和磁性研究[J].功能材料,2011,42(增刊3):552-554. ZHANG B F,LIU L H.Study on synthesis and magnetic propertie of NiCuZn ferrite[J].Journal of Functional Materials,2011,42(S3):552-554.
【4】SU H,ZHANG H W,TANG X L,et al.Effects of composition and sintering temperature on properties of NiZn and NiCuZn ferrites[J].Journal of Magnetism and Magnetic Materials,2007,310(1):17-21.
【5】苏桦,张怀武,唐晓莉.CuO、MoO3和WO3掺杂对NiZn铁氧体磁性能的影响[J].材料研究学报,2005,19(5):549-554. SU H,ZHANG H W,TANG X L.Effects of CuO,MoO3 and WO3 dopping on magnetic properties of NiZn ferrites[J].Chinese Journal of Materials Research,2005,19(5):549-554.
【6】邱华,贾利军,张素娜,等.Al3+、Co2+取代对NiCuZn铁氧体材料微观结构和磁性能的影响[J].磁性材料及器件,2019,50(5):10-13. QIU H,JIA L J,ZHANG S N,et al.Effects of substitution of Al3+ and Co2+ on microstructure and magnetic properties of NiCuZn ferrite materials[J].Journal of Magnetic Materials and Devices,2019,50(5):10-13.
【7】欧阳辰鑫,肖淑敏,施威,等.镍锌比和BSZ玻璃对NiCuZn铁氧体组织与性能的影响[J].电子元件与材料,2015,34(8):52-55. OUYANG C X,XIAO S M,SHI W,et al.Influences of Ni/Zn mole ratio and BSZ glass addition on the microstructures and properties of NiCuZn ferrites[J].Electronic Components and Materials,2015,34(8):52-55.
【8】朱晓斌,聂敏.SnO2添加对低温烧结NiCuZn铁氧体材料耐电流冲击性能的影响[J].磁性材料及器件,2020,51(1):41-44. ZHU X B,NIE M.Effects of SnO2 addition on the current shock resistance of low temperature co-fired NiCuZn ferrites[J].Journal of Magnetic Materials and Devices,2020,51(1):41-44.
【9】程利霞,刘焕威,苏童霓,等.预烧工艺对镍锌铁氧体微观结构和磁性能的影响[J].磁性材料及器件,2021,52(4):65-69. CHENG L X,LIU H W,SU T N,et al.Effect of pre-sintering process on the microstructure and magnetic properties of NiZn ferrite[J].Journal of Magnetic Materials and Devices,2021,52(4):65-69.
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【11】陶文俊,陈文革,段希萌.粉体粒度对锰锌软磁铁氧体性能的影响[J].电工材料,2010(3):35-39. TAO W J,CHEN W G,DUAN X M.Influence of powder size on the properties of manganese-zinc ferrite[J].Electrical Engineering Materials,2010(3):35-39.
【12】周婷,张蓉,李雪莹,等.球磨工艺对钡铁氧体浆料粒径和磁性能的影响[J].中国粉体技术,2010,16(2):39-41. ZHOU T,ZHANG R,LI X Y,et al.Effect of milling process on particle size and magnetic properties of barium ferrite[J].China Powder Science and Technology,2010,16(2):39-41.
【13】刘文斌,晏沪盈,薛建,等.粉料粒度分布对宽温低功耗MnZn铁氧体性能的影响[J].磁性材料及器件,2021,52(2):74-79. LIU W B,YAN H Y,XUE J,et al.Influence of particle size distribution on the performance of wide temperature and low power loss MnZn ferrite[J].Journal of Magnetic Materials and Devices,2021,52(2):74-79.
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【16】李楷威,刘昕,陈川,等.CaCO3添加对NiCuZn铁氧体磁性能及电学性能的影响[J].磁性材料及器件,2019,50(2):10-14. LI K W,LIU X,CHEN C,et al.Influence of CaCO3 addition on the magnetic and electrical properties of NiCuZn ferrites[J].Journal of Magnetic Materials and Devices,2019,50(2):10-14.
【17】师凯旋,苏桦,张怀武,等.BBSZ玻璃掺杂对NiCuZn铁氧体性能的影响[J].电子元件与材料,2011,30(2):54-56. SHI K X,SU H,ZHANG H W,et al.Effects of BBSZ glass doping on the properties of NiCuZn ferrites[J].Electronic Components and Materials,2011,30(2):54-56.
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