Ni-Mn-In基磁制冷合金的研究进展
Research Progress on Ni-Mn-In Based Magnetic Refrigeration Alloys
摘 要
基于磁热效应的新型固体磁制冷技术因具有节能高效、稳定可靠的优点而备受关注,该技术利用磁性材料在磁相变过程中与外界环境之间的热交换作用而产生制冷效果。Ni-Mn-In基磁制冷合金在磁场诱导下可以产生逆磁热效应,具有较大的磁熵变。介绍了Ni-Mn-In基磁制冷合金的晶体结构和相变行为,重点综述了晶粒尺寸、化学成分、热处理工艺等因素对Ni-Mn-In基磁制冷合金磁热效应的影响,以及通过微合金化提高合金力学性能的研究进展。对未来该系列合金的研究方向进行了展望。
晶体结构
马氏体相变
磁热效应
力学性能
Ni-Mn-In based alloy
crystal structure
martensitic transformation
magnetocaloric effect
mechanical property
Abstract
New solid-state magnetic refrigeration technology based on magnetocaloric effects has attracted much attention due to its advantages of energy saving, high efficiency, and stability and reliability. This technology utilizes heat exchange between magnetic materials and external environments during magnetic phase transition to produce refrigeration effects. Ni-Mn-In based magnetic refrigeration alloys can produce an inverse magnetocaloric effect under a magnetic field and have a large magnetic entropy change. The crystal structure and phase transformation behavior of Ni-Mn-In based magnetic refrigeration alloys are described. Research progress on the influence of grain size, chemical composition and heat treatment process on the magnetocaloric effect of Ni-Mn-In based magnetic refrigeration alloys, as well as on improving mechanical properties of the alloys by microalloying is emphatically reviewed. The future research direction of this series of alloys is also prospected.
中图分类号 TG111 TG115 DOI 10.11973/jxgccl202305001
所属栏目 综述
基金项目 国家青年科学基金资助项目(51401122)
收稿日期 2021/11/6
修改稿日期 2022/10/20
网络出版日期
作者单位点击查看
备注刘紫莉(1998-),女,河南驻马店人,硕士研究生
引用该论文: LIU Zili,GAO Li,LIAO Huayu,HU Shaohui. Research Progress on Ni-Mn-In Based Magnetic Refrigeration Alloys[J]. Materials for mechancial engineering, 2023, 47(5): 1～7
刘紫莉,高丽,廖华玉,胡少辉. Ni-Mn-In基磁制冷合金的研究进展[J]. 机械工程材料, 2023, 47(5): 1～7
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【29】AGUILAR-ORTIZ C O,CAMARILLO-GARCÍA J P,VERGARA J,et al.Effect of solidification rate on martensitic transformation behavior and adiabatic magnetocaloric effect of Ni50Mn35In15 ribbons[J].Journal of Alloys and Compounds,2018,748:464-472.
【30】PAVLUKHINA O,SOKOLOVSKIY V,BUCHELNIKOV V.Modeling of heat transfer processes in Ni2MnIn magnetic wires[J].Physica Status Solidi (a),2016,213(2):390-398.
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【34】DEVI P,MEJÍA C S,ZAVAREH M G,et al.Improved magnetostructural and magnetocaloric reversibility in magnetic Ni-Mn-In shape-memory Heusler alloy by optimizing the geometric compatibility condition[J].Physical Review Materials,2019,3(6):062401.
【35】HUANG L,CONG D Y,MA L,et al.Large reversible magnetocaloric effect in a Ni-Co-Mn-In magnetic shape memory alloy[J].Applied Physics Letters,2016,108(3):032405.
【36】CHENG F,GAO L M,WANG Y,et al.Large refrigeration capacity in a Ni42Co8Mn37.7In12.3 magnetocaloric alloy[J].Journal of Magnetism and Magnetic Materials,2019,478:234-238.
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