(MgCoNiCuZn)O高熵氧化物陶瓷涂层的制备及性能
Preparation and Properties of (MgCoNiCuZn)O High Entropy Oxide Ceramic Coating
摘 要
通过高温固相反应烧结法在不同烧结温度(700~1 000 ℃)下制备(MgCoNiCuZn)O高熵氧化物陶瓷粉体,并采用大气等离子喷涂技术在Inconel 718合金基体表面制备了陶瓷涂层,研究了陶瓷涂层的微观结构和性能。结果表明:在900,1 000 ℃烧结温度下均合成了具有单一岩盐相结构的(MgCoNiCuZn)O高熵氧化物陶瓷粉体;用这2种温度烧结陶瓷粉体制备的陶瓷涂层的硬度为5.42~5.94 GPa,结合强度为45.4~48.5 MPa,用1 000 ℃烧结粉体制备的陶瓷涂层的结合强度和硬度较高。陶瓷涂层与氧化铝球对磨时的摩擦因数为0.59~0.69,磨损率为2.59×10-5~4.13×10-5 mm3·N-1·m-1,主要磨损机理为磨粒磨损和疲劳剥落,用1 000 ℃烧结粉体制备的陶瓷涂层的摩擦因数与磨损率较低,磨损表面犁沟细而浅,剥落坑小而少。
陶瓷涂层
微观结构
摩擦学性能
high entropy oxide
ceramic coating
microstructure
tribological property
Abstract
High entropy oxide (MgCoNiCuZn)O ceramic powders were prepared by high temperature solid state reaction sintering at different temperatures (700-1 000 ℃). The ceramic coating was prepared on the surface of Inconel 718 alloy substrate by atmospheric plasma spraying technique, and the microstructure and properties of ceramic coatings were studied. The results show that (MgCoNiCuZn)O high entropy oxide ceramic powders with a single rock salt phase structure were synthesized at sintering temperatures of 900, 1 000 ℃. The ceramic coatings prepared with the ceraimic powders sintered at the two temperatures had hardness of 5.42-5.94 GPa and bonding strength of 45.4-48.5 MPa. The bonding strength and hardness of the ceramic coating prepared with powders sintered at 1 000 ℃ were relatively high. The friction coefficient of ceramic coating abrasing against alumina balls was 0.59-0.69, and the wear rate was 2.59×10-5-4.13×10-5 mm3·N-1·m-1; the main wear mechanism was abrasive wear and fatigue spalling. The friction coefficient and wear rate of the ceramic coating prepared with powders sintered at 1 000 ℃ were relatively low, and the worn surface had thin and shallow ploughing and small and few spalling pits.
中图分类号 TG356.16 DOI 10.11973/jxgccl202305007
所属栏目 新材料 新工艺
基金项目 国家自然科学基金资助项目(52175178);陕西省重点研发计划项目(2019GY-173)
收稿日期 2022/12/1
修改稿日期 2023/3/29
网络出版日期
作者单位点击查看
备注惠俊杰(1998-),男,陕西咸阳人,硕士研究生
引用该论文: HUI Junjie,JIA Junhong,BAI Ganyu,YUE Ruifang,ZHANG Xinyi,LI Jinxin. Preparation and Properties of (MgCoNiCuZn)O High Entropy Oxide Ceramic Coating[J]. Materials for mechancial engineering, 2023, 47(5): 41～46
惠俊杰,贾均红,白甘雨,岳瑞芳,张心怡,李金鑫. (MgCoNiCuZn)O高熵氧化物陶瓷涂层的制备及性能[J]. 机械工程材料, 2023, 47(5): 41～46
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【9】XIAO J K, TAN H, WU Y Q, et al.Microstructure and wear behavior of FeCoNiCrMn high entropy alloy coating deposited by plasma spraying[J].Surface and Coatings Technology,2020,385:125430.
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【24】USHARANI N J,BHANDARKAR A,SUBRAMANIAN S,et al.Antiferromagnetism in a nanocrystalline high entropy oxide (Co,Cu,Mg,Ni,Zn)O:Magnetic constituents and surface anisotropy leading to lattice distortion[J].Acta Materialia,2020,200:526-536.
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