Research Progress on Strengthening Methods of Ultra-lightweight Mg-Li Alloys
摘 要
镁锂合金作为密度最小的金属结构材料,具有高比强度和比刚度、优异的阻尼性能和电磁屏蔽性能等优点,但其绝对强度低,极大限制了其在实际工程中的规模化应用。对近年来镁锂合金的合金化强化、变形加工强化、热处理强化以及复合强化等强化方法的研究现状进行了总结,并给出了未来镁锂合金强化方法的研究方向。
Abstract
As the smallest density metal structure material, Mg-Li alloys have advantages of high specific strength and specific stiffness, excellent damping performance and electromagnetic shielding performance, but the low absolute strength greatly limits their wide application in practical engineering. The research status on strengthening methods of Mg-Li alloys such as alloying strengthening, deformation processing strengthening, heat treatment strengthening and composite strengthening in recent years are summarized. The future research direction of strengthening methods of Mg-Li alloys is prospected.
中图分类号 TG146.2 DOI 10.11973/jxgccl202305014
所属栏目 专题报道(金属材料强韧均衡)
基金项目 国家自然科学基金资助项目(U21A2049, 51871211, 52071220, 51701129, 51971054 ); 辽宁省“兴辽英才计划”项目(XLYC1907062); 辽宁省自然科学博士启动基金资助项目(2019-BS-200); 辽宁省“百千万人才工程”资助B类项目;魏桥国科高研院-中科院金属所研发项目(GYY-JSBU-2022-009)
收稿日期 2023/1/18
修改稿日期 2023/4/23
网络出版日期
作者单位点击查看
备注王硕(1992-),男,黑龙江鹤岗人,博士研究生
引用该论文: WANG Shuo,XU Daokui,WANG Dongliang,WANG Baojie,ZHANG Zhiqiang. Research Progress on Strengthening Methods of Ultra-lightweight Mg-Li Alloys[J]. Materials for mechancial engineering, 2023, 47(5): 94~101
王硕,许道奎,王东亮,王保杰,张志强. 超轻镁锂合金强化方法的研究现状[J]. 机械工程材料, 2023, 47(5): 94~101
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参考文献
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【35】王耀奇,侯红亮,李志强,等.纯铝累积叠轧焊组织与性能演变规律研究[J].塑性工程学报,2006,13(4):96-99. WANG Y Q,HOU H L,LI Z Q,et al.Study on microstructure and mechanical properties evolution of pure aluminum produced by accumulative roll-bonding process[J].Journal of Plasticity Engineering,2006,13(4):96-99.
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【48】WU R Z,ZHANG M L.Microstructure,mechanical properties and aging behavior of Mg-5Li-3Al-2Zn-xAg[J].Materials Science and Engineering:A,2009,520(1/2):36-39.
【49】LI C Q,XU D K,WANG B J,et al.Suppressing effect of heat treatment on the Portevin-Le Chatelier phenomenon of Mg-4%Li-6%Zn-1.2%Y alloy[J].Journal of Materials Science & Technology,2016,32(12):1232-1238.
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【51】LI X Q,LE Q C,ZHOU X,et al.The strengthening mechanism and deformation behavior of Mg-Li matrix composite reinforced by Al3La phase formed in situ through La2O3 particle[J].Composites Part B:Engineering,2021,216:108866.
【52】ZHANG Q Q,WU G Q,HUANG Z,et al.Effects of particle/matrix interfaces on the mechanical properties for SiCp or YAl2p reinforced Mg-Li composites[J].Journal of Alloys and Compounds,2014,588:1-6.
【53】K AU'G DELA S,ŠVEC P,BAJANA O,et al.Saffil alumina fibers reinforced dual-phase Mg-Li and Mg-Li-Zn alloys[J].Metallic Materials,2017,55(3):195-203.
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【2】CHU S,MAJUMDAR A.Opportunities and challenges for a sustainable energy future[J].Nature,2012,488(7411):294-303.
【3】ESTRIN Y,NENE S S,KASHYAP B P,et al.New hot rolled Mg-4Li-1Ca alloy:A potential candidate for automotive and biodegradable implant applications[J].Materials Letters,2016,173:252-256.
【4】MASSALSKI T B,MURRAY J L,BENNETT L H,et al.Binary alloy phase diagrams[M].Metals Park,Ohio:American Society for Metals,1986.
【5】FREETH W E, RAYNOR G V. The systems magnesium-lithium and magnesium-lithium-silver [J]. Journal of the Institute of Metals, 1954, 82: 575.
【6】FURUI M,KITAMURA H,ANADA H,et al.Influence of preliminary extrusion conditions on the superplastic properties of a magnesium alloy processed by ECAP[J].Acta Materialia,2007,55(3):1083-1091.
【7】LIU T,WANG Y D,WU S D,et al.Textures and mechanical behavior of Mg-3.3%Li alloy after ECAP[J].Scripta Materialia,2004,51(11):1057-1061.
【8】WU H Y,GAO Z W,LIN J Y,et al.Effects of minor scandium addition on the properties of Mg-Li-Al-Zn alloy[J].Journal of Alloys and Compounds,2009,474(1/2):158-163.
【9】WU R Z,QU Z K,ZHANG M.Reviews on the influences of alloying elements on the microstructure and mechanical properties of Mg-Li base alloys[J].Reviews on Advanced Materials Science,2010, 24: 35-42.
【10】CHANG T C,WANG J Y,CHU C L,et al.Mechanical properties and microstructures of various Mg-Li alloys[J].Materials Letters,2006,60(27):3272-3276.
【11】彭翔,刘文才,吴国华.镁锂合金的合金化及其应用[J].中国有色金属学报,2021,31(11):3024-3043. PENG X,LIU W C,WU G H.Alloying and application of Mg-Li alloys:A review[J].The Chinese Journal of Nonferrous Metals,2021,31(11):3024-3043.
【12】BHAGAT S P, SABAT R K, KUMARAN S, et al.Effect of aluminum addition on the evolution of microstructure,crystallographic texture and mechanical properties of single phase hexagonal close packed Mg-Li alloys[J].Journal of Materials Engineering and Performance,2018,27(2):864-874.
【13】PERUGU C S,KUMAR S,SUWAS S.Evolution of microstructure,texture,and tensile properties in two-phase Mg-Li alloys:Effect of Zn addition[J].JOM,2020,72(4):1627-1637.
【14】ZHAO Z L,SUN Z W,LIANG W,et al.Influence of Al and Si additions on the microstructure and mechanical properties of Mg-4Li alloys[J].Materials Science and Engineering:A,2017,702:206-217.
【15】SHI Q X,BIAN L P,LIANG W,et al.Effects of adding Al-Si eutectic alloy and hot rolling on microstructures and mechanical behavior of Mg-8Li alloys[J].Journal of Alloys and Compounds,2015,631:129-132.
【16】ZHAO Z L,XING X G,MA J Y,et al.Effect of addition of Al-Si eutectic alloy on microstructure and mechanical properties of Mg-12wt%Li alloy[J].Journal of Materials Science & Technology,2018,34(9):1564-1569.
【17】WANG T,WU R Z,ZHANG M L,et al.Effects of calcium on the microstructures and tensile properties of Mg-5Li-3Al alloys[J].Materials Science and Engineering:A,2011,528(18):5678-5684.
【18】XU T C,PENG X D,JIANG J W,et al.Effect of Sr content on microstructure and mechanical properties of Mg-Li-Al-Mn alloy[J].Transactions of Nonferrous Metals Society of China,2014,24(9):2752-2760.
【19】WU R Z,QU Z K,ZHANG M L.Effects of the addition of Y in Mg-8Li-(1,3)Al alloy[J].Materials Science and Engineering:A,2009,516(1/2):96-99.
【20】ZHONG F,WU H J,JIAO Y L,et al.Effect of Y and Ce on the microstructure,mechanical properties and anisotropy of as-rolled Mg-8Li-1Al alloy[J].Journal of Materials Science & Technology,2020,39:124-134.
【21】XU D K,WANG B J,LI C Q,et al.Effect of icosahedral phase on the thermal stability and ageing response of a duplex structured Mg-Li alloy[J].Materials & Design,2015,69:124-129.
【22】XU D K,ZU T T,YIN M,et al.Mechanical properties of the icosahedral phase reinforced duplex Mg-Li alloy both at room and elevated temperatures[J].Journal of Alloys and Compounds,2014,582:161-166.
【23】XU D K,LIU L,XU Y B,et al.The strengthening effect of icosahedral phase on as-extruded Mg-Li alloys[J].Scripta Materialia,2007,57(3):285-288.
【24】XU D K,LI C Q,WANG B J,et al.Effect of icosahedral phase on the crystallographic texture and mechanical anisotropy of duplex structured Mg-Li alloys[J].Materials & Design,2015,88:88-97.
【25】LI C Q,XU D K,YU S,et al.Effect of icosahedral phase on crystallographic texture and mechanical anisotropy of Mg-4%Li based alloys[J].Journal of Materials Science & Technology,2017,33(5):475-480.
【26】XU D K,HAN E H.Effects of icosahedral phase formation on the microstructure and mechanical improvement of Mg alloys:A review[J].Progress in Natural Science:Materials International,2012,22:364-385.
【27】ZHANG M Q,ZHANG J H,WU R Z,et al.The effect of Y/Er and Zn addition on the microstructure and mechanical properties of Mg-11Li alloy[J].Materials (Basel,Switzerland),2019,12(19):3066.
【28】SONG W J,LIU J,HE S,et al.Microstructure and mechanical properties of as-cast ultralight and high strength Mg-10Li-3Al-3Zn-xY alloy with multi-precipitates[J].Materials Characterization,2022,189:111972.
【29】徐晨,徐林,王佳豪,等.镁锂合金强化研究进展[J].轻合金加工技术,2022,50(8):1-11. XU C,XU L,WANG J H,et al.Research progress on strengthening methods of Mg-Li alloys[J].Light Alloy Fabrication Technology,2022,50(8):1-11.
【30】LIU W C,FENG S,LI Z Q,et al.Effect of rolling strain on microstructure and tensile properties of dual-phase Mg-8Li-3Al-2Zn-0.5Y alloy[J].Journal of Materials Science & Technology,2018,34(12):2256-2262.
【31】ZHANG X,SU K Q,KANG H J,et al.Improving the mechanical properties of duplex Mg-Li-Zn alloy by mixed rolling processing[J].Materials Today Communications,2022,31:103538.
【32】LIU H Y,WANG Y,LI B C,et al.Effect of cryogenic rolling process on microstructure and mechanical properties of Mg-14Li-1Al alloy[J].Materials Characterization,2019,157:109903.
【33】JI Q,WANG Y,WU R Z,et al.High specific strength Mg-Li-Zn-Er alloy processed by multi deformation processes[J].Materials Characterization,2020,160:110135.
【34】KLU E E, SONG D, LI C, et al. Achieving ultra-fine grains and high strength of Mg-9Li alloy via room-temperature ECAP and post rolling [J]. Materials Science and Engineering:A, 2022, 833: 142371.
【35】王耀奇,侯红亮,李志强,等.纯铝累积叠轧焊组织与性能演变规律研究[J].塑性工程学报,2006,13(4):96-99. WANG Y Q,HOU H L,LI Z Q,et al.Study on microstructure and mechanical properties evolution of pure aluminum produced by accumulative roll-bonding process[J].Journal of Plasticity Engineering,2006,13(4):96-99.
【36】WU H J,WANG Y,WU R Z,et al.Microstructure,mechanical properties and strain hardening behavior of alternative α/β Mg-Li composite sheets prepared by accumulative roll bonding[J].Metals and Materials International,2022,28(5):1277-1289.
【37】ZHOU G,YANG Y,ZHANG H Z,et al.Microstructure and strengthening mechanism of hot-extruded ultralight Mg-Li-Al-Sn alloys with high strength[J].Journal of Materials Science & Technology,2022,103:186-196.
【38】YANG Y,XIONG X M,SU J F,et al.Influence of extrusion temperature on microstructure and mechanical behavior of duplex Mg-Li-Al-Sr alloy[J].Journal of Alloys and Compounds,2018,750:696-705.
【39】FENG S,LIU W C,ZHAO J,et al.Effect of extrusion ratio on microstructure and mechanical properties of Mg-8Li-3Al-2Zn-0.5Y alloy with duplex structure[J].Materials Science and Engineering:A,2017,692:9-16.
【40】GUO Y H,HE X C,DAI Y B,et al.Microstructures and mechanical properties of Mg-5Li-4Sn-2Al-1Zn alloy after hot extrusion[J].Materials Science and Engineering:A,2022,860:144329.
【41】MINETA T,HASEGAWA K,SATO H.High strength and plastic deformability of Mg-Li-Al alloy with dual BCC phase produced by a combination of heat treatment and multi-directional forging in channel die[J].Materials Science and Engineering:A,2020,773:138867.
【42】ZHAO J,LI Z Q,LIU W C,et al.Influence of heat treatment on microstructure and mechanical properties of as-cast Mg-8Li-3Al-2Zn-xY alloy with duplex structure[J].Materials Science and Engineering:A,2016,669:87-94.
【43】WEI Z,ZHANG J H,BAO R R,et al.Achieving high strength in a Mg-Li-Zn-Y alloy by α-Mg precipitation[J].Materials Science and Engineering:A,2022,846:143272.
【44】GUO F,LIU L,MA Y L,et al.Mechanism of phase refinement and its effect on mechanical properties of a severely deformed dual-phase Mg-Li alloy during annealing[J].Materials Science and Engineering:A,2020,772:138792.
【45】SHEN Y Z,LI D F,GUO S L,et al.Effect of heat treatment on microstructure and mechanical properties of Mg-10Li-3Al-3Zn-0.22Si alloy[J].Metals and Materials International,2022,28(10):2462-2471.
【46】JI H,WU G H,LIU W C,et al.Origin of the age-hardening and age-softening response in Mg-Li-Zn based alloys[J].Acta Materialia,2022,226:117673.
【47】JI H,PENG X,ZHANG X L,et al.Balance of mechanical properties of Mg-8Li-3Al-2Zn-0.5Y alloy by solution and low-temperature aging treatment[J].Journal of Alloys and Compounds,2019,791:655-664.
【48】WU R Z,ZHANG M L.Microstructure,mechanical properties and aging behavior of Mg-5Li-3Al-2Zn-xAg[J].Materials Science and Engineering:A,2009,520(1/2):36-39.
【49】LI C Q,XU D K,WANG B J,et al.Suppressing effect of heat treatment on the Portevin-Le Chatelier phenomenon of Mg-4%Li-6%Zn-1.2%Y alloy[J].Journal of Materials Science & Technology,2016,32(12):1232-1238.
【50】SUN Y H,WANG R C,PENG C Q,et al.Recent progress in Mg-Li matrix composites[J].Transactions of Nonferrous Metals Society of China,2019,29(1):1-14.
【51】LI X Q,LE Q C,ZHOU X,et al.The strengthening mechanism and deformation behavior of Mg-Li matrix composite reinforced by Al3La phase formed in situ through La2O3 particle[J].Composites Part B:Engineering,2021,216:108866.
【52】ZHANG Q Q,WU G Q,HUANG Z,et al.Effects of particle/matrix interfaces on the mechanical properties for SiCp or YAl2p reinforced Mg-Li composites[J].Journal of Alloys and Compounds,2014,588:1-6.
【53】K AU'G DELA S,ŠVEC P,BAJANA O,et al.Saffil alumina fibers reinforced dual-phase Mg-Li and Mg-Li-Zn alloys[J].Metallic Materials,2017,55(3):195-203.
【54】WILCOX B A, CLAUER A H.Tensile and creep deformation of a fiber reinforced MgLi alloy[J].Composites,1969,1(1):62.
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