Corrosion Behavior and Life Prediction of A Newly Developed Train Body Steel S500AW in Outdoor Atmospheric Environment
摘 要
通过大气暴晒试验结合室内加速腐蚀试验,研究了新开发的车体钢S500AW和用于对比的传统Q450NQR1钢及Q345B钢的早期腐蚀行为,采用扫描电镜(SEM)、拉曼光谱仪,分析了试验前后试样表面的腐蚀形貌和腐蚀产物成分。结果表明:在北京大气环境暴露初期,S500AW钢表面更为平整光洁,仅有少量尘埃颗粒附着物,耐蚀性更优异;腐蚀产物为Fe2O3和一定量的γ-FeOOH,随着腐蚀时间的延长,γ-FeOOH含量逐渐增加,钢的耐蚀性逐渐提高;以腐蚀质量损失数据为参照,建立铁路车辆车体用钢腐蚀试验方法和腐蚀寿命预测模型,通过灰色关联度分析方法,证实了周期浸润试验与户外自然环境大气暴露试验良好的相关性。
Abstract
The early corrosion behavior of newly developed train body steel S500AW and traditional Q450NQR1 steel and Q345B steel for comprision was studied by atmospheric exposure test combined with indoor accelerated corrosion test. The corrosion morphology and corrosion product composition on surface of the sample before and after the test were analyzed by scanning electron microscopy ( SEM ) and Raman spectrometer. The results showed that the surface of S500AW steel was smoother and cleaner in the early stage of exposure in Beijing atmospheric environment, with only a small amount of dust particles attached, and the corrosion resistance was better. The corrosion product was Fe2O3 and some γ-FeOOH. With the extension of corrosion time, the content of γ-FeOOH increased gradually, and the corrosion resistance of steel increased gradually. Based on the data of corrosion mass loss, the corrosion test method and corrosion life prediction model of steel for railway vehicle body were established. Through the grey correlation analysis method, the good correlation between periodic wetting test and outdoor natural environment atmospheric exposure test was confirmed.
中图分类号 TG174.4 DOI 10.11973/fsyfh-202306008
所属栏目 试验研究
基金项目 国家重点研发计划课题资助项目(2017YFB 0304605)
收稿日期 2021/7/12
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联系人作者吴毅(wuyi930@163.com)
引用该论文: LI Bin,WU Yi,YIN Hongxiang,JIN Ying,ZHU Jinyang. Corrosion Behavior and Life Prediction of A Newly Developed Train Body Steel S500AW in Outdoor Atmospheric Environment[J]. Corrosion & Protection, 2023, 44(6): 47
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参考文献
【1】梁斐.中国钢铁工业高质量发展之路探析[J].冶金管理,2019(24):47-49.
【2】王俊岭,徐丹宁,刘辰玥.中国钢铁工业技术创新效率分析[J].河北地质大学学报,2019,42(6):63-67.
【3】文小明.铁道货车用Q450NQR1高强钢的研制开发[C]//第四届中国金属学会青年学术年会论文集.北京:[出版者不详],2008:157-161.
【4】张国超,林冠发,孙育禄,等.13Cr不锈钢腐蚀性能的研究现状与进展[J].全面腐蚀控制,2011,25(4):16-20,39.
【5】黄涛,陈小平,王向东,等.光照对Q450NQR1耐候钢在干湿交替下腐蚀行为的影响[J].工程科学学报,2016,38(12):1762-1769.
【6】郝远,陈队志.锑铸铁的耐腐蚀性[J].甘肃工业大学学报,1991,17(4):54-58.
【7】郝远,李子全,董庚茂,等.锑铸铁的抗汽蚀性[J].甘肃工业大学学报,1994,20(2):35-39.
【8】黄涛,王向东,陈小平,等.Sn-Sb耐候钢在模拟高湿热海洋大气环境中的耐蚀性研究[C]//2018第五届海洋材料与腐蚀防护大会暨海洋新材料及防护新技术展览会论文集.珠海:[出版者不详],2018:133-145.
【9】SPOTORNO R,GHIARA G,LATRONICO G,et al.Corrosion of the filled skutterudite Sm0.1(Fe0.45Ni0.55)4Sb12 by NaCl solutions:an electrochemical study[J].Journal of Electronic Materials,2020,49(5):2872-2880.
【10】XAVIER J R.Enhanced adhesion and corrosion protection properties of surface modified Sb2O3-epoxy nanocomposite coatings on mild steel[J].Journal of Failure Analysis and Prevention,2020,20(2):523-531.
【11】刘健,李灏.Sb对低合金钢在上甲板环境下耐蚀性的影响[J].物理测试,2018,36(5):8-14.
【12】AHN S,PARK K J,OH K,et al.Effects of Sn and Sb on the corrosion resistance of AH 32 steel in a cargo oil tank environment[J].Metals and Materials International,2015,21(5):865-873.
【13】YANG Y,JIANG C,CHENG X Q,et al.Effect of Sb on the corrosion behavior of low-alloy steels in a simulated polluted marine atmosphere[J].Journal of Materials Engineering and Performance,2020,29(4):2648-2657.
【14】赵建印,王玺,刘星.海洋大气环境下装备腐蚀量预测[J].兵工自动化,2019,38(12):5-9.
【15】郝献超,肖葵,张汉青,等.模拟海洋大气环境下Cu和Cr对耐候钢耐腐蚀性能的影响[J].材料保护,2009,42(1):21-23,43,90.
【16】张新生,曹昕,韩文超,等.基于参数优化GM-Markov模型的海底管道腐蚀预测[J].油气储运,2020,39(8)953-960.
【17】陈俊航,白子恒,薛伟,等.304不锈钢在青岛污染海洋大气环境中的腐蚀寿命预测模型[J].材料保护,2019,52(12):48-55,68.
【18】高蒙,赖俊滨,张兴华,等.北京大气试验站典型环境因素监测分析[J].环境技术,2015,33(5):13-16.
【19】施建成,王桂华,王欣,等.新鲜铁表面锈蚀过程的拉曼光谱研究[J].上海师范大学学报(自然科学版),2001,30(4):62-66.
【2】王俊岭,徐丹宁,刘辰玥.中国钢铁工业技术创新效率分析[J].河北地质大学学报,2019,42(6):63-67.
【3】文小明.铁道货车用Q450NQR1高强钢的研制开发[C]//第四届中国金属学会青年学术年会论文集.北京:[出版者不详],2008:157-161.
【4】张国超,林冠发,孙育禄,等.13Cr不锈钢腐蚀性能的研究现状与进展[J].全面腐蚀控制,2011,25(4):16-20,39.
【5】黄涛,陈小平,王向东,等.光照对Q450NQR1耐候钢在干湿交替下腐蚀行为的影响[J].工程科学学报,2016,38(12):1762-1769.
【6】郝远,陈队志.锑铸铁的耐腐蚀性[J].甘肃工业大学学报,1991,17(4):54-58.
【7】郝远,李子全,董庚茂,等.锑铸铁的抗汽蚀性[J].甘肃工业大学学报,1994,20(2):35-39.
【8】黄涛,王向东,陈小平,等.Sn-Sb耐候钢在模拟高湿热海洋大气环境中的耐蚀性研究[C]//2018第五届海洋材料与腐蚀防护大会暨海洋新材料及防护新技术展览会论文集.珠海:[出版者不详],2018:133-145.
【9】SPOTORNO R,GHIARA G,LATRONICO G,et al.Corrosion of the filled skutterudite Sm0.1(Fe0.45Ni0.55)4Sb12 by NaCl solutions:an electrochemical study[J].Journal of Electronic Materials,2020,49(5):2872-2880.
【10】XAVIER J R.Enhanced adhesion and corrosion protection properties of surface modified Sb2O3-epoxy nanocomposite coatings on mild steel[J].Journal of Failure Analysis and Prevention,2020,20(2):523-531.
【11】刘健,李灏.Sb对低合金钢在上甲板环境下耐蚀性的影响[J].物理测试,2018,36(5):8-14.
【12】AHN S,PARK K J,OH K,et al.Effects of Sn and Sb on the corrosion resistance of AH 32 steel in a cargo oil tank environment[J].Metals and Materials International,2015,21(5):865-873.
【13】YANG Y,JIANG C,CHENG X Q,et al.Effect of Sb on the corrosion behavior of low-alloy steels in a simulated polluted marine atmosphere[J].Journal of Materials Engineering and Performance,2020,29(4):2648-2657.
【14】赵建印,王玺,刘星.海洋大气环境下装备腐蚀量预测[J].兵工自动化,2019,38(12):5-9.
【15】郝献超,肖葵,张汉青,等.模拟海洋大气环境下Cu和Cr对耐候钢耐腐蚀性能的影响[J].材料保护,2009,42(1):21-23,43,90.
【16】张新生,曹昕,韩文超,等.基于参数优化GM-Markov模型的海底管道腐蚀预测[J].油气储运,2020,39(8)953-960.
【17】陈俊航,白子恒,薛伟,等.304不锈钢在青岛污染海洋大气环境中的腐蚀寿命预测模型[J].材料保护,2019,52(12):48-55,68.
【18】高蒙,赖俊滨,张兴华,等.北京大气试验站典型环境因素监测分析[J].环境技术,2015,33(5):13-16.
【19】施建成,王桂华,王欣,等.新鲜铁表面锈蚀过程的拉曼光谱研究[J].上海师范大学学报(自然科学版),2001,30(4):62-66.
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