TiO2抗菌涂层制备方法的研究进展
Research Progress on Preparation Methods of TiO2 Antibacterial Coating
摘 要
TiO2抗菌涂层具有杀菌时效长、污染损害小等特点,有着传统杀菌剂无法比拟的应用前景。综述了TiO2涂层的杀菌机理和涂层种类,对主要的制备工艺,如溶胶-凝胶法、电沉积法、磁控溅射法、等离子喷涂法、微弧氧化法的优缺点和应用现状进行了介绍,并对未来TiO2抗菌涂层的研究方向进行了展望。
光催化
杀菌性能
制备方法
TiO2 antibacterial coating
photocatalysis
bactericidal property
preparation method
Abstract
TiO2 antibacterial coating has the characteristics of long sterilization time and minimal pollution damage, and has an unparalleled application prospect compared with traditional fungicides. The bactericidal mechanism and coating types of TiO2 coatings are reviewed, and the advantages, disadvantages and application status of main preparation processes, such as sol-gel method, electro-deposition method, magnetron sputtering method, plasma spraying method, and micro arc oxidation method are introduced. The future research direction of TiO2 antibacterial coating is prospected.
中图分类号 TQ134.11 O614.411 DOI 10.11973/jxgccl202306002
所属栏目 综述
基金项目 上海市科技计划项目(20DZ2252300);上海高水平地方高校创新团队(海事安全与保障)项目(H20220008)
收稿日期 2022/4/2
修改稿日期 2023/3/24
网络出版日期
作者单位点击查看
联系人作者尹莉
备注钱钊(1997-),男,安徽滁州人,硕士研究生
引用该论文: QIAN Zhao,DU Xu,YIN Li,LIU Yanbo,LI Wenge,ZHANG Jing,ZHAO Yuantao. Research Progress on Preparation Methods of TiO2 Antibacterial Coating[J]. Materials for mechancial engineering, 2023, 47(6): 8～13
钱钊,杜旭,尹莉,刘彦伯,李文戈,张静,赵远涛. TiO2抗菌涂层制备方法的研究进展[J]. 机械工程材料, 2023, 47(6): 8～13
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参考文献
【1】QIN Y Y,GUO Y C,LIANG Z Q,et al.Au nanorods decorated TiO2 nanobelts with enhanced full solar spectrum photocatalytic antibacterial activity and the sterilization file cabinet application[J].Chinese Chemical Letters,2021,32(4):1523-1526.
【2】CHEN S G, GUO Y J, ZHONG H Q, et al.Synergistic antibacterial mechanism and coating application of copper/titanium dioxide nanoparticles[J].Chemical Engineering Journal,2014,256:238-246.
【3】WANG J Q, LIANG M F, PAN Y, et al.Control of surface composition and microstructure of nano super-hydrophilic TiO2-CuOy coatings through reactive sputtering to improve antibacterial ability,corrosion resistance,and biocompatibility[J].Applied Surface Science,2022,578:151893.
【4】DĚDKOVÁ K,MATĚJOVÁ K,LANG J,et al.Antibacterial activity of kaolinite/nano TiO2 composites in relation to irradiation time[J].Journal of Photochemistry and Photobiology.B,Biology,2014,135:17-22.
【5】刘冷,杜意恩,牛宪军.溶胶-凝胶法制备锐钛矿型TiO2光催化剂及其光催化性能研究[J].四川大学学报(自然科学版),2019,56(3):507-512. LIU L,DU Y E,NIU X J.Synthesis of anatase-type TiO2 photocatalysts by using sol-gel method and their photocatalytic performances[J].Journal of Sichuan University (Natural Science Edition),2019,56(3): 507-512.
【6】DOSTA S,ROBOTTI M,GARCIA-SEGURA S,et al.Influence of atmospheric plasma spraying on the solar photoelectro-catalytic properties of TiO2 coatings[J].Applied Catalysis B:Environmental,2016,189:151-159.
【7】ARMELAO L,BARRECA D,BOTTARO G,et al.Photocatalytic and antibacterial activity of TiO2 and Au/TiO2 nanosystems[J].Nanotechnology,2007,18(37):375709.
【8】MANESS P C,SMOLINSKI S,BLAKE D M,et al.Bactericidal activity of photocatalytic TiO2 reaction:Toward an understanding of its killing mechanism[J].Applied and Environmental Microbiology,1999,65(9):4094-4098.
【9】BLAKE D,MANESS P,HUANG Z,et al.Application of the photocatalytic chemistry of titanium dioxide to disinfection and the killing of cancer cells[J].Separation and Purification Methods,1999,28:1-50.
【10】CERRADA M L,SERRANO C,SÁNCHEZ-CHAVES M,et al.Self-sterilized EVOH-TiO2 nanocomposites:Interface effects on biocidal properties[J].Advanced Functional Materials,2008,18(13):1949-1960.
【11】WANG J M,ZHANG C,YANG Y Q,et al.Poly (vinyl alcohol) (PVA) hydrogel incorporated with Ag/TiO2 for rapid sterilization by photoinspired radical oxygen species and promotion of wound healing[J].Applied Surface Science,2019,494:708-720.
【12】黄素涌,李凯夫.溶胶-凝胶法制备杉木/TiO2复合材料及其抗菌性的研究[J].林产工业,2010,37(5):21-23. HUANG S Y,LI K F.China fir/TiO2 composite prepared by using sol-gel method and its antibacterial property[J].China Forest Products Industry,2010,37(5):21-23.
【13】李灵珍,杨艳玲,李星,等.UV-TiO2技术在二次供水中的消毒效能研究[J].水处理技术,2017,43(12):83-88. LI L Z,YANG Y L,LI X,et al.Research on disinfection efficacy of secondary supply water by UV/TiO2 technique[J].Technology of Water Treatment,2017,43(12):83-88.
【14】郑学斌,季珩,黄静琪,等.等离子喷涂抗菌羟基磷灰石涂层研究[J].无机材料学报,2006,21(3):764-768. ZHENG X B,JI H,HUANG J Q,et al.Plasma sprayed antibacterial HA coatings[J].Journal of Inorganic Materials,2006,21(3):764-768.
【15】王宇华,朱梓园,张富强,等.单质银应用于等离子喷涂抗菌涂层的研究[J].上海口腔医学,2009,18(3):317-319. WANG Y H,ZHU Z Y,ZHANG F Q,et al.The antibacterial activity of plasma sprayed silver-containing hydroxyapatite coatings[J].Shanghai Journal of Stomatology,2009,18(3):317-319.
【16】GAO J J,LI C X,ZHOU J F,et al.Plasma sprayed alumina-nanosilver antibacterial coatings[J].RSC Advances,2015,5(26):20357-20364.
【17】时代,杨合,薛向欣.Zn、Co单掺杂及Co-Zn共掺杂TiO2纳米材料协同抗菌效应的研究[J].功能材料,2019,50(10):10133-10139. SHI D,YANG H,XUE X X.Synergistic antibacterial effect of Zn,Co doped and Co/Zn co-doped titania nano-materials[J].Journal of Functional Materials,2019,50(10):10133-10139.
【18】赵晓兵,刘高鹏.等离子喷涂TiO2-CeO2复合涂层的结构及抗菌性能研究[J].常州大学学报(自然科学版),2015,27(1): 26-31. ZHAO X B,LIU G P.Research on microstructure and antibacterial property of TiO2-CeO2 plasma-sprayed composite coatings[J].Journal of Changzhou University (Natural Science Edition),2015,27(1): 26-31.
【19】路怀峰,陆健,宋小霞,等.抗菌元素对纳米TiO2涂层结构和性能的影响[J].表面技术,2018,47(9):65-73. LU H F,LU J,SONG X X,et al.Influence of antibacterial elements on the structure and properties of nanostructured TiO2 coatings[J].Surface Technology,2018,47(9):65-73.
【20】SAFFARI M R,MIAB R K.Antibacterial property of PLA textiles coated by nano-TiO2 through eco-friendly low-temperature plasma[J].International Journal of Clothing Science and Technology,2016,28(6):830-840.
【21】UHM S H,LEE S B,SONG D H,et al.Fabrication of bioactive,antibacterial TiO2 nanotube surfaces,coated with magnetron sputtered Ag nanostructures for dental applications[J].Journal of Nanoscience and Nanotechnology,2014,14(10):7847-7854.
【22】LI B E, LIU X Y, MENG F H, et al. Preparation and antibacterial properties of plasma sprayed nano-titania/silver coatings[J]. Materials Chemistry and Physics, 2009, 118(1): 99-104.
【23】ZHAI M J,LIU Y,HUANG J,et al.Fabrication of TiO2-SrCO3 composite coatings by suspension plasma spraying:Microstructure and enhanced visible light photocatalytic performances[J].Journal of Thermal Spray Technology,2020,29(5):1172-1182.
【24】YIN L L,FU Z X,LI Y,et al.Enhanced antibacterial properties of biocompatible titanium via electrochemically deposited Ag/TiO2 nanotubes and chitosan-gelatin-Ag-ZnO complex coating[J].RSC Advances,2019,9(8):4521-4529.
【25】NADIMI M,DEHGHANIAN C.Incorporation of ZnO-ZrO2 nanoparticles into TiO2 coatings obtained by PEO on Ti-6Al-4V substrate and evaluation of its corrosion behavior,microstructural and antibacterial effects exposed to SBF solution[J].Ceramics International,2021,47(23):33413-33425.
【26】LIU S,ZHANG Z M,ZHANG J Q,et al.Construction of a TiO2/Cu2O multifunctional coating on Ti-Cu alloy and its influence on the cell compatibility and antibacterial properties[J].Surface and Coatings Technology,2021,421:127438.
【27】ZHANG Z Q,ZHANG Y,ZHANG S Q,et al.Synthesis of rare earth doped MOF base coating on TiO2 nanotubes arrays by electrochemical method using as antibacterial implant material[J].Inorganic Chemistry Communications,2021,127:108484.
【28】YIN L L,FU Z X,LI Y,et al.Enhanced antibacterial properties of biocompatible titanium via electrochemically deposited Ag/TiO2 nanotubes and chitosan-gelatin-Ag-ZnO complex coating[J].RSC Advances,2019,9(8):4521-4529.
【29】QIAO H X,SONG G Q,HUANG Y,et al.Si,Sr,Ag co-doped hydroxyapatite/TiO2 coating:Enhancement of its antibacterial activity and osteoinductivity[J].RSC Advances,2019,9(24):13348-13364.
【30】KHARITONOV D S,KASACH A A,SERGIEVICH D S,et al.Ultrasonic-assisted electrodeposition of Cu-Sn-TiO2 nanocomposite coatings with enhanced antibacterial activity[J].Ultrasonics Sonochemistry,2021,75:105593.
【31】YAN Y J,ZHANG X J,HUANG Y,et al.Antibacterial and bioactivity of silver substituted hydroxyapatite/TiO2 nanotube composite coatings on titanium[J].Applied Surface Science,2014,314:348-357.
【32】KHARITONOV D S,KASACH A A,SERGIEVICH D S,et al.Ultrasonic-assisted electrodeposition of Cu-Sn-TiO2 nanocomposite coatings with enhanced antibacterial activity[J].Ultrasonics Sonochemistry,2021,75:105593.
【33】WU H B, ZHANG X Y, GENG Z H, et al. Preparation, antibacterial effects and corrosion resistant of porous Cu-TiO2 coatings[J]. Applied Surface Science, 2014, 308: 43-49.
【34】ZHOU J H,LI B,HAN Y.F-doped TiO2 microporous coating on titanium with enhanced antibacterial and osteogenic activities[J].Scientific Reports,2018,8(1):17858.
【35】YAO X H, ZHANG X Y, WU H B, et al. Microstructure and antibacterial properties of Cu-doped TiO2 coating on titanium by micro-arc oxidation[J]. Applied Surface Science, 2014, 292: 944-947.
【36】KANG B B,LAN D M,YAO C,et al.Evaluation of antibacterial property and biocompatibility of Cu doped TiO2 coated implant prepared by micro-arc oxidation[J].Frontiers in Bioengineering and Biotechnology,2022,10:941109.
【37】ZHU W, ZHANG Z X, GU B B, et al. Biological activity and antibacterial property of nano-structured TiO2 coating incorporated with Cu prepared by micro-arc oxidation[J].Journal of Materials Science & Technology, 2013, 29(3): 237-244.
【38】ZHANG X, WANG H, LI J, et al. Corrosion behavior of Zn-incorporated antibacterial TiO2 porous coating on titanium[J]. Ceramics International 2016; 42(15):17095-17100.
【39】MAUERER A,HENKEL M,WELSCH G H,et al.Effects of different sterilisation methods on antibacterial Cu-TiO2 coatings[J].Surface Engineering,2015,31(10):757-762.
【40】VILLATTE G,MASSARD C,DESCAMPS S,et al.Photoactive TiO2 antibacterial coating on surgical external fixation pins for clinical application[J].International Journal of Nanomedicine,2015,10:3367-3375.
【41】LE M C,LE T H,BUI THI T H,et al.Synthesizing and evaluating the photocatalytic and antibacterial ability of TiO2/SiO2 nanocomposite for silicate coating[J].Frontiers in Chemistry,2021,9:738969.
【42】AHMADI R,ASADPOURCHALLOU N,KALEJI B. In vitro study:Evaluation of mechanical behavior,corrosion resistance,antibacterial properties and biocompatibility of HAp/TiO2/Ag coating on Ti6Al4V/TiO2 substrate[J].Surfaces and Interfaces,2021,24:101072.
【43】MOHAMMAD M R,AHMED D S,MOHAMMED M K A.Synthesis of Ag-doped TiO2 nanoparticles coated with carbon nanotubes by the sol-gel method and their antibacterial activities[J].Journal of Sol-Gel Science and Technology,2019,90(3):498-509.
【44】ZAWADZKA K,KÄDZIOÅA K,FELCZAK A,et al.Surface area or diameter-Which factor really determines the antibacterial activity of silver nanoparticles grown on TiO2 coatings?[J].New Journal of Chemistry,2014,38(7):3275-3281.
【45】宁哲达,王一晴,陈天天,等.磁控溅射沉积银薄膜/涂层的研究进展[J].稀有金属材料与工程,2022,51(12):4773-4782. NING Z D,WANG Y Q,CHEN T T,et al.Research progress of silver films/coatings deposited by magnetron sputtering[J].Rare Metal Materials and Engineering,2022,51(12):4773-4782.
【46】ZAWADZKA K,KISIELEWSKA A,PIWO AN＇G SKI I,et al.Mechanisms of antibacterial activity and stability of silver nanoparticles grown on magnetron sputtered TiO2 coatings[J].Bulletin of Materials Science,2016,39(1):57-68.
【47】SAFFARI M R,MIAB R K.Antibacterial property of PLA textiles coated by nano-TiO2 through eco-friendly low-temperature plasma[J].International Journal of Clothing Science and Technology,2016,28(6):830-840.
【2】CHEN S G, GUO Y J, ZHONG H Q, et al.Synergistic antibacterial mechanism and coating application of copper/titanium dioxide nanoparticles[J].Chemical Engineering Journal,2014,256:238-246.
【3】WANG J Q, LIANG M F, PAN Y, et al.Control of surface composition and microstructure of nano super-hydrophilic TiO2-CuOy coatings through reactive sputtering to improve antibacterial ability,corrosion resistance,and biocompatibility[J].Applied Surface Science,2022,578:151893.
【4】DĚDKOVÁ K,MATĚJOVÁ K,LANG J,et al.Antibacterial activity of kaolinite/nano TiO2 composites in relation to irradiation time[J].Journal of Photochemistry and Photobiology.B,Biology,2014,135:17-22.
【5】刘冷,杜意恩,牛宪军.溶胶-凝胶法制备锐钛矿型TiO2光催化剂及其光催化性能研究[J].四川大学学报(自然科学版),2019,56(3):507-512. LIU L,DU Y E,NIU X J.Synthesis of anatase-type TiO2 photocatalysts by using sol-gel method and their photocatalytic performances[J].Journal of Sichuan University (Natural Science Edition),2019,56(3): 507-512.
【6】DOSTA S,ROBOTTI M,GARCIA-SEGURA S,et al.Influence of atmospheric plasma spraying on the solar photoelectro-catalytic properties of TiO2 coatings[J].Applied Catalysis B:Environmental,2016,189:151-159.
【7】ARMELAO L,BARRECA D,BOTTARO G,et al.Photocatalytic and antibacterial activity of TiO2 and Au/TiO2 nanosystems[J].Nanotechnology,2007,18(37):375709.
【8】MANESS P C,SMOLINSKI S,BLAKE D M,et al.Bactericidal activity of photocatalytic TiO2 reaction:Toward an understanding of its killing mechanism[J].Applied and Environmental Microbiology,1999,65(9):4094-4098.
【9】BLAKE D,MANESS P,HUANG Z,et al.Application of the photocatalytic chemistry of titanium dioxide to disinfection and the killing of cancer cells[J].Separation and Purification Methods,1999,28:1-50.
【10】CERRADA M L,SERRANO C,SÁNCHEZ-CHAVES M,et al.Self-sterilized EVOH-TiO2 nanocomposites:Interface effects on biocidal properties[J].Advanced Functional Materials,2008,18(13):1949-1960.
【11】WANG J M,ZHANG C,YANG Y Q,et al.Poly (vinyl alcohol) (PVA) hydrogel incorporated with Ag/TiO2 for rapid sterilization by photoinspired radical oxygen species and promotion of wound healing[J].Applied Surface Science,2019,494:708-720.
【12】黄素涌,李凯夫.溶胶-凝胶法制备杉木/TiO2复合材料及其抗菌性的研究[J].林产工业,2010,37(5):21-23. HUANG S Y,LI K F.China fir/TiO2 composite prepared by using sol-gel method and its antibacterial property[J].China Forest Products Industry,2010,37(5):21-23.
【13】李灵珍,杨艳玲,李星,等.UV-TiO2技术在二次供水中的消毒效能研究[J].水处理技术,2017,43(12):83-88. LI L Z,YANG Y L,LI X,et al.Research on disinfection efficacy of secondary supply water by UV/TiO2 technique[J].Technology of Water Treatment,2017,43(12):83-88.
【14】郑学斌,季珩,黄静琪,等.等离子喷涂抗菌羟基磷灰石涂层研究[J].无机材料学报,2006,21(3):764-768. ZHENG X B,JI H,HUANG J Q,et al.Plasma sprayed antibacterial HA coatings[J].Journal of Inorganic Materials,2006,21(3):764-768.
【15】王宇华,朱梓园,张富强,等.单质银应用于等离子喷涂抗菌涂层的研究[J].上海口腔医学,2009,18(3):317-319. WANG Y H,ZHU Z Y,ZHANG F Q,et al.The antibacterial activity of plasma sprayed silver-containing hydroxyapatite coatings[J].Shanghai Journal of Stomatology,2009,18(3):317-319.
【16】GAO J J,LI C X,ZHOU J F,et al.Plasma sprayed alumina-nanosilver antibacterial coatings[J].RSC Advances,2015,5(26):20357-20364.
【17】时代,杨合,薛向欣.Zn、Co单掺杂及Co-Zn共掺杂TiO2纳米材料协同抗菌效应的研究[J].功能材料,2019,50(10):10133-10139. SHI D,YANG H,XUE X X.Synergistic antibacterial effect of Zn,Co doped and Co/Zn co-doped titania nano-materials[J].Journal of Functional Materials,2019,50(10):10133-10139.
【18】赵晓兵,刘高鹏.等离子喷涂TiO2-CeO2复合涂层的结构及抗菌性能研究[J].常州大学学报(自然科学版),2015,27(1): 26-31. ZHAO X B,LIU G P.Research on microstructure and antibacterial property of TiO2-CeO2 plasma-sprayed composite coatings[J].Journal of Changzhou University (Natural Science Edition),2015,27(1): 26-31.
【19】路怀峰,陆健,宋小霞,等.抗菌元素对纳米TiO2涂层结构和性能的影响[J].表面技术,2018,47(9):65-73. LU H F,LU J,SONG X X,et al.Influence of antibacterial elements on the structure and properties of nanostructured TiO2 coatings[J].Surface Technology,2018,47(9):65-73.
【20】SAFFARI M R,MIAB R K.Antibacterial property of PLA textiles coated by nano-TiO2 through eco-friendly low-temperature plasma[J].International Journal of Clothing Science and Technology,2016,28(6):830-840.
【21】UHM S H,LEE S B,SONG D H,et al.Fabrication of bioactive,antibacterial TiO2 nanotube surfaces,coated with magnetron sputtered Ag nanostructures for dental applications[J].Journal of Nanoscience and Nanotechnology,2014,14(10):7847-7854.
【22】LI B E, LIU X Y, MENG F H, et al. Preparation and antibacterial properties of plasma sprayed nano-titania/silver coatings[J]. Materials Chemistry and Physics, 2009, 118(1): 99-104.
【23】ZHAI M J,LIU Y,HUANG J,et al.Fabrication of TiO2-SrCO3 composite coatings by suspension plasma spraying:Microstructure and enhanced visible light photocatalytic performances[J].Journal of Thermal Spray Technology,2020,29(5):1172-1182.
【24】YIN L L,FU Z X,LI Y,et al.Enhanced antibacterial properties of biocompatible titanium via electrochemically deposited Ag/TiO2 nanotubes and chitosan-gelatin-Ag-ZnO complex coating[J].RSC Advances,2019,9(8):4521-4529.
【25】NADIMI M,DEHGHANIAN C.Incorporation of ZnO-ZrO2 nanoparticles into TiO2 coatings obtained by PEO on Ti-6Al-4V substrate and evaluation of its corrosion behavior,microstructural and antibacterial effects exposed to SBF solution[J].Ceramics International,2021,47(23):33413-33425.
【26】LIU S,ZHANG Z M,ZHANG J Q,et al.Construction of a TiO2/Cu2O multifunctional coating on Ti-Cu alloy and its influence on the cell compatibility and antibacterial properties[J].Surface and Coatings Technology,2021,421:127438.
【27】ZHANG Z Q,ZHANG Y,ZHANG S Q,et al.Synthesis of rare earth doped MOF base coating on TiO2 nanotubes arrays by electrochemical method using as antibacterial implant material[J].Inorganic Chemistry Communications,2021,127:108484.
【28】YIN L L,FU Z X,LI Y,et al.Enhanced antibacterial properties of biocompatible titanium via electrochemically deposited Ag/TiO2 nanotubes and chitosan-gelatin-Ag-ZnO complex coating[J].RSC Advances,2019,9(8):4521-4529.
【29】QIAO H X,SONG G Q,HUANG Y,et al.Si,Sr,Ag co-doped hydroxyapatite/TiO2 coating:Enhancement of its antibacterial activity and osteoinductivity[J].RSC Advances,2019,9(24):13348-13364.
【30】KHARITONOV D S,KASACH A A,SERGIEVICH D S,et al.Ultrasonic-assisted electrodeposition of Cu-Sn-TiO2 nanocomposite coatings with enhanced antibacterial activity[J].Ultrasonics Sonochemistry,2021,75:105593.
【31】YAN Y J,ZHANG X J,HUANG Y,et al.Antibacterial and bioactivity of silver substituted hydroxyapatite/TiO2 nanotube composite coatings on titanium[J].Applied Surface Science,2014,314:348-357.
【32】KHARITONOV D S,KASACH A A,SERGIEVICH D S,et al.Ultrasonic-assisted electrodeposition of Cu-Sn-TiO2 nanocomposite coatings with enhanced antibacterial activity[J].Ultrasonics Sonochemistry,2021,75:105593.
【33】WU H B, ZHANG X Y, GENG Z H, et al. Preparation, antibacterial effects and corrosion resistant of porous Cu-TiO2 coatings[J]. Applied Surface Science, 2014, 308: 43-49.
【34】ZHOU J H,LI B,HAN Y.F-doped TiO2 microporous coating on titanium with enhanced antibacterial and osteogenic activities[J].Scientific Reports,2018,8(1):17858.
【35】YAO X H, ZHANG X Y, WU H B, et al. Microstructure and antibacterial properties of Cu-doped TiO2 coating on titanium by micro-arc oxidation[J]. Applied Surface Science, 2014, 292: 944-947.
【36】KANG B B,LAN D M,YAO C,et al.Evaluation of antibacterial property and biocompatibility of Cu doped TiO2 coated implant prepared by micro-arc oxidation[J].Frontiers in Bioengineering and Biotechnology,2022,10:941109.
【37】ZHU W, ZHANG Z X, GU B B, et al. Biological activity and antibacterial property of nano-structured TiO2 coating incorporated with Cu prepared by micro-arc oxidation[J].Journal of Materials Science & Technology, 2013, 29(3): 237-244.
【38】ZHANG X, WANG H, LI J, et al. Corrosion behavior of Zn-incorporated antibacterial TiO2 porous coating on titanium[J]. Ceramics International 2016; 42(15):17095-17100.
【39】MAUERER A,HENKEL M,WELSCH G H,et al.Effects of different sterilisation methods on antibacterial Cu-TiO2 coatings[J].Surface Engineering,2015,31(10):757-762.
【40】VILLATTE G,MASSARD C,DESCAMPS S,et al.Photoactive TiO2 antibacterial coating on surgical external fixation pins for clinical application[J].International Journal of Nanomedicine,2015,10:3367-3375.
【41】LE M C,LE T H,BUI THI T H,et al.Synthesizing and evaluating the photocatalytic and antibacterial ability of TiO2/SiO2 nanocomposite for silicate coating[J].Frontiers in Chemistry,2021,9:738969.
【42】AHMADI R,ASADPOURCHALLOU N,KALEJI B. In vitro study:Evaluation of mechanical behavior,corrosion resistance,antibacterial properties and biocompatibility of HAp/TiO2/Ag coating on Ti6Al4V/TiO2 substrate[J].Surfaces and Interfaces,2021,24:101072.
【43】MOHAMMAD M R,AHMED D S,MOHAMMED M K A.Synthesis of Ag-doped TiO2 nanoparticles coated with carbon nanotubes by the sol-gel method and their antibacterial activities[J].Journal of Sol-Gel Science and Technology,2019,90(3):498-509.
【44】ZAWADZKA K,KÄDZIOÅA K,FELCZAK A,et al.Surface area or diameter-Which factor really determines the antibacterial activity of silver nanoparticles grown on TiO2 coatings?[J].New Journal of Chemistry,2014,38(7):3275-3281.
【45】宁哲达,王一晴,陈天天,等.磁控溅射沉积银薄膜/涂层的研究进展[J].稀有金属材料与工程,2022,51(12):4773-4782. NING Z D,WANG Y Q,CHEN T T,et al.Research progress of silver films/coatings deposited by magnetron sputtering[J].Rare Metal Materials and Engineering,2022,51(12):4773-4782.
【46】ZAWADZKA K,KISIELEWSKA A,PIWO AN＇G SKI I,et al.Mechanisms of antibacterial activity and stability of silver nanoparticles grown on magnetron sputtered TiO2 coatings[J].Bulletin of Materials Science,2016,39(1):57-68.
【47】SAFFARI M R,MIAB R K.Antibacterial property of PLA textiles coated by nano-TiO2 through eco-friendly low-temperature plasma[J].International Journal of Clothing Science and Technology,2016,28(6):830-840.
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