Comparison on Determination of Total Carbon in Soil and Sediment by Elemental Analyzer and Combustion- Infrared Absorption Spectrometry
摘 要
燃烧-红外吸收光谱法是土壤和沉积物中总碳含量测定的标准方法,为探究元素分析仪发展为土壤、沉积物中总碳含量标准方法的可行性,进行了题示项目研究。选取5种具有代表性的土壤、沉积物标准物质,分别采用燃烧-红外吸收光谱法和元素分析仪进行测定。结果表明:燃烧-红外吸收光谱法测定值的相对标准偏差(RSD,n=6)为1.2%~2.7%,相对误差为-2.9%~0.63%;元素分析仪测定值的RSD(n=6)为0.24%~2.7%,相对误差为-3.3%~0.84%;两种方法t检验结果均满足|t|<t0.05,P>0.05,表明两种方法无显著性差异。基于元素分析仪简便、快速、适用于大批量样品测定及具有较高的准确度和精密度,因此可考虑将其发展为土壤和沉积物等地质样品中总碳含量测定的标准方法。
Abstract
Combustion-infrared absorption spectrometry is a standard method for the determination of total carbon in soil and sediment. In order to explore the feasibility of developing the elemental analyzer into a standard method for the determination of total carbon in soil and sediment, the research mentioned by this article was carried out. Five representative soil and sediment reference materials were selected and determined by combustion-infrared absorption spectrometry and elemental analyzer. It was shown that RSDs (n=6) of the determined values obtained by combustion-infrared absorption spectrometry were in the range of 1.2%-2.7%, with relative errors ranged from -2.9% to 0.63%, and RSDs (n=6) of the determined values obtained by elemental analyzer were in the range of 0.24%-2.7%, with relative errors ranged from -3.3% to 0.84%. The results of t test for the two methods were satisfied |t|<t(0.05) and P>0.05, indicating that there was no significant difference between the two methods. Based on these facts that the elemental analyzer was simple, rapid, and suitable for the determination of large quantities of samples, which had high accuracy and precision, so it could be considered as a standard method for the determination of total carbon in geological samples such as soil and sediment.
中图分类号 O657.3 S151.9 DOI 10.11973/lhjy-hx202307005
所属栏目 工作简报
基金项目 国家重点研发计划课题(2021YFC2903004);中国地质科学院基本科研业务费项目(CSJ202013)
收稿日期 2021/12/16
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备注陈宗定,硕士研究生,主要从事实验测试标准化相关工作,ding_5424@126.com
引用该论文: CHEN Zongding,XU Chunxue,LIU Guilei,WANG Lan,SUN Huizhong,AN Ziyi. Comparison on Determination of Total Carbon in Soil and Sediment by Elemental Analyzer and Combustion- Infrared Absorption Spectrometry[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2023, 59(7): 771~775
陈宗定,许春雪,刘贵磊,王岚,孙慧中,安子怡. 元素分析仪和燃烧-红外吸收光谱法测定土壤和沉积物中总碳含量的比对[J]. 理化检验-化学分册, 2023, 59(7): 771~775
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参考文献
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【3】CHEN L C, WANG H A, YU X, et al. Recovery time of soil carbon pools of conversional Chinese fir plantations from broadleaved forests in subtropical regions, China[J]. Science of the Total Environment, 2017,587/588:296-304.
【4】PHO K H, SARSHAD M, ALIZADEH P, et al. Soil carbon pool changes following semi-arid lands planting programs[J]. Catena, 2020,191:104563.
【5】ADENUGA O S, AJIBOYE G A, SHADE J, et al. Siol carbon[M]. Swizerland:Springer International Publishing, 2014:27-28.
【6】陈宗定,许春雪,安子怡,等.土壤碳赋存形态及分析方法研究进展[J].岩矿测试, 2019,38(2):233-244.
【7】王巧环,任玉芬,孟龄,等.元素分析仪同时测定土壤中全氮和有机碳[J].分析试验室, 2013,32(10):41-45.
【8】李志鹏,潘根兴,李恋卿,等.水稻土和湿地土壤有机碳测定的CNS元素分析仪法与湿消化容量法之比较[J].土壤, 2008,40(4):580-585.
【9】LOMBARD B, LECLERCQ A. Validation of innovative food microbiological methods according to the EN ISO 16140 standard[J]. Food Analytical Methods, 2011,4(2):163-172.
【10】蒙益林,汪磊,孙涛,等.高频燃烧-红外吸收法测定钴基钎料中碳和硫[J].冶金分析, 2015,35(8):39-44.
【11】邓军华,王一凌,亢德华,等.高频燃烧红外吸收法测定磷铁中碳和硫[J].冶金分析, 2017,37(3):83-87.
【12】袁润蕾.HCS878A型高频红外碳硫分析仪测定地质样品中碳、硫[J].化学工程师, 2019,33(9):31-33.
【13】赵星,宋江伟,史旭峰.燃烧-高频红外碳硫分析法测定土壤中全碳量[J].云南地质, 2018,37(2):243-246.
【14】申健,翟嘉琪,覃涛,等.煤炭元素分析仪性能试验研究[J].煤炭加工与综合利用, 2019(1):69-71.
【15】罗浩.LECO CHN628元素分析仪测定煤中碳氢氮的研究[J].能源与环境, 2019(2):13-15.
【16】孙辞,崔杰华,林桂凤,等.元素分析仪测定低含碳量土壤样品方法的改进[J].辽宁大学学报(自然科学版), 2017,44(4):337-341.
【17】WRIGHT A F, BAILEY J S. Organic carbon, total carbon, and total nitrogen determinations in soils of variable calcium carbonate contents using a Leco CN-2000 dry combustion analyzer[J]. Communications in Soil Science and Plant Analysis, 2001,32(19/20):3243-3258.
【18】高翠萍,李岩,刘美英,等.Vario MACRO cube元素分析仪测定土壤碳氮方法研究[J].北方农业学报, 2017,45(1):76-79.
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