高温环境中油套管腐蚀研究进展
Research Progress of Tubing and Casing Corrosion in High Temperature Environment
摘 要
综述了近年来高温环境中油套管材料腐蚀的研究进展，重点关注了二氧化碳腐蚀、硫化氢腐蚀、元素硫腐蚀及氢气腐蚀。对上述四种腐蚀的规律、机理及影响因素进行了归纳、总结，并分析了目前研究中存在的不足。结合现场需求，对未来该领域的研究工作提出了建议。
CO2腐蚀
H2S腐蚀
元素硫腐蚀
氢气腐蚀
high temperature corrosion
CO2 corrosion
H2S corrosion
elemental sulfur corrosion
hydrogen corrosion
Abstract
The research progress of corrosion of tubing and casing materials in high temperature environment in recent years is reviewed, focusing on carbon dioxide corrosion, hydrogen sulfide corrosion, elemental sulfur corrosion and hydrogen corrosion. The corrosion rules, mechanisms and influencing factors of the above four kinds of corrosion are summarized, and the shortcomings of the present research are analyzed. According to the field demand, some suggestions for future research in this field are put forward.
中图分类号 TG172 DOI 10.11973/fsyfh-202308008
所属栏目 专论
基金项目 中国石油天然气服份有限公司重大科技项目（2021DJ5203）
收稿日期 2021/8/19
修改稿日期
网络出版日期
作者单位点击查看
引用该论文: ZHOU Zhiping,ZHAO Aibin,ZHANG Ruquan,LI Mingxing,LIU Wei,YAO Jinxing,ZHONG Xiankang. Research Progress of Tubing and Casing Corrosion in High Temperature Environment[J]. Corrosion & Protection, 2023, 44(8): 40
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参考文献
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【43】WANG J M, ZHU T Y, CHEN K, et al. Effect of dissolved oxygen and hydrogen on the stress corrosion cracking behavior of alloy 600 in high temperature water[J]. Journal of Nuclear Materials, 2021, 543:152603.
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【2】马永生, 蔡勋育, 李国雄. 四川盆地普光大型气藏基本特征及成藏富集规律[J]. 地质学报, 2005, 79(6):858-865.
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【6】GUO Q L, CHEN X M, WANG J A, et al. An improved hydrocarbon generating model of source rocks and its application:a case study of shale oil in situ transformation of the Yanchang Formation in the Ordos Basin[J]. Petroleum Science and Technology, 2021, 39(3):63-87.
【7】王益维, 汪友平, 孟祥龙, 等. 低成熟度页岩油加热改质热解动力学及地层渗透性[J]. 石油与天然气地质, 2019, 40(3):678-684.
【8】王建军, 杨尚谕, 薛承文, 等. 稠油热采井套管柱应变设计方法[J]. 中国石油大学学报(自然科学版), 2017, 41(1):150-155.
【9】何军, 李云龙, 项忠华, 等. 油页岩原位开采井筒结构设计[J]. 科学技术与工程, 2019, 19(20):151-155.
【10】何军, 黄昭, 张清, 等. 低熟页岩油高温开采井筒完整性[J]. 科学技术与工程, 2021, 21(5):1752-1757.
【11】陈尧, 白真权, 林冠发. 普通13Cr钢在高温高压下的抗CO2腐蚀性能[J]. 全面腐蚀控制, 2007, 21(2):11-14.
【12】YIN Z F, FENG Y R, ZHAO W Z, et al. Effect of temperature on CO2 corrosion of carbon steel[J]. Surface and Interface Analysis, 2009, 41(6):517-523.
【13】董晓焕, 姜毅, 付彩利, 等. 温度对Cr13不锈钢CO2腐蚀行为的影响[J]. 腐蚀与防护, 2012, 33(3):196-198.
【14】MUNDHENK N, CARRERO S, KNAUSS K G, et al. Kinetic and thermodynamic analysis of high-temperature CO2 corrosion of carbon steel in simulated geothermal NaCl fluids[J]. Corrosion Science, 2020, 171:108597.
【15】FURUKAWA T, ROUILLARD F. Oxidation and carburizing of FBR structural materials in carbon dioxide[J]. Progress in Nuclear Energy, 2015, 82:136-141.
【16】李瑞涛, 肖博, 刘晓, 等. 低合金耐热钢T23在高温超临界CO2环境中的腐蚀特性研究[J]. 中国腐蚀与防护学报, 2021, 41(3):327-334.
【17】GAO S J, JIN P, BROWN B, et al. Effect of high temperature on the aqueous H2S corrosion of mild steel[J]. Corrosion, 2017, 73(10):1188-1191.
【18】SHI F X, ZHANG L, YANG J W, et al. Polymorphous FeS corrosion products of pipeline steel under highly sour conditions[J]. Corrosion Science, 2016, 102:103-113.
【19】BACKENSTO E B, DREW R D, STAPLEFORD C C. High temperature hydrogen sulfide corrosion[J]. Corrosion, 1956, 12(1):22-32.
【20】SORELL G, HOYT W B. Collection and correlation of high temperature hydrogen sulfide corrosion data-a contribution to the work of NACE task group T-5B-2 on sulfide corrosion at high temperatures and pressures in the petroleum industry from:the M.W.Kellogg Co., New York, N.Y.[J]. Corrosion, 1956, 12(5):33-54.
【21】SILVA C C, MACHADO J P S E, SOBRAL-SANTIAGO A V C, et al. High-temperature hydrogen sulfide corrosion on the heat-affected zone of the AISI 444 stainless steel caused by Venezuelan heavy petroleum[J]. Journal of Petroleum Science and Engineering, 2007, 59(3/4):219-225.
【22】MEDVEDEVA M L. Specifics of high-temperature corrosion processes during oil recovery[J]. Chemical and Petroleum Engineering, 2000, 36(11/12):749-754.
【23】谭惠钟, 陈继志, 王嘉敏. 5种常用耐热钢的耐高温二氧化硫气体腐蚀性能研究[J]. 钢铁研究学报, 2011, 23(S2):329-332.
【24】FARBER M, EHRENBERG D M. High-temperature corrosion rates of several metals with hydrogen sulfide and sulfur dioxide[J]. Journal of the Electrochemical Society, 1952, 99(10):427.
【25】邓彤, 柯家骏, 陈家镛. 元素硫的歧化反应动力学研究[J]. 化工学报, 1984, 35(4):328-334.
【26】付德奎, 郭肖, 杜志敏, 等. 高含硫裂缝性气藏储层伤害数学模型[J]. 石油学报, 2010, 31(3):463-466.
【27】杨仲熙, 刘志德, 谷坛, 等. 高含硫气田电化学腐蚀现场试验研究[J]. 石油与天然气化工, 2006, 35(3):222-223, 166.
【28】MALDONADO-ZAGAL S B, BODEN P J. Hydrolysis of elemental sulphur in water and its effect on the corrosion of mild steel[J]. British Corrosion Journal, 1982, 17(3):116-120.
【29】ZHU S D, MA H X, LI J L, et al. Effect of elemental sulfur on corrosion behavior of super 13Cr martensitic stainless steel[J]. Applied Mechanics and Materials, 2014, 556/557/558/559/560/561/562:162-165.
【30】张昀. 高酸高硫原油腐蚀性研究[J]. 石油化工腐蚀与防护, 2004, 21(6):9-13.
【31】段永锋, 李朝法, 于凤昌, 等. 高硫原油在高温下的腐蚀性能及选材研究[J]. 压力容器, 2012, 29(7):14-19.
【32】SUN H A, WU X Q, HAN E H. Effects of temperature on the protective property, structure and composition of the oxide film on alloy 625[J]. Corrosion Science, 2009, 51(11):2565-2572.
【33】SUN H A, WU X Q, HAN E H. Effects of temperature on the oxide film properties of 304 stainless steel in high temperature lithium borate buffer solution[J]. Corrosion Science, 2009, 51(12):2840-2847.
【34】CHANG L T, MUKAHIWA K, DUFF J, et al. The effect of low temperature heat treatment on stress corrosion crack initiation in machined 316L stainless steel in high-temperature hydrogenated water[J]. Scripta Materialia, 2021, 195:113742.
【35】张民强, 黄丽琴, 刘光明, 等. S30432在不同煤灰/烟气环境中的高温腐蚀行为研究[J]. 表面技术, 2018, 47(8):251-256.
【36】ZENG Z, NATESAN K, CAI Z, et al. Effect of coal ash on the performance of alloys in simulated oxy-fuel environments[J]. Fuel, 2014, 117:133-145.
【37】HUSSAIN T, SYED A U, SIMMS N J. Trends in fireside corrosion damage to superheaters in air and oxy-firing of coal/biomass[J]. Fuel, 2013, 113:787-797.
【38】杨波, 李茂东, 刘光明, 等. 超音速喷涂Inconel625/NiCr合金涂层的热腐蚀行为[J]. 中国腐蚀与防护学报, 2016, 36(5):483-488.
【39】王健, 黄亚继, 邹磊, 等. 气固相硫协同作用下水冷壁的高温腐蚀特性[J]. 化工进展, 2018, 37(2):452-458.
【40】STEIN-BRZOZOWSKA G, NORLING R, VIKLUND P, et al. Fireside corrosion during oxyfuel combustion considering various SO2 contents[J]. Energy Procedia, 2014, 51:135-147.
【41】BIRKS N, MEIER G H, PETTIT F S. Introduction to the High Temperature Oxidation of Metals[M]. Cambridge, UK:Cambridge University Press, 2006.
【42】LUTHRA K L. Low temperature hot corrosion of cobalt-base alloys:parti.morphology of the reaction product[J]. Metallurgical Transactions A, 1982, 13(10):1843-1852.
【43】WANG J M, ZHU T Y, CHEN K, et al. Effect of dissolved oxygen and hydrogen on the stress corrosion cracking behavior of alloy 600 in high temperature water[J]. Journal of Nuclear Materials, 2021, 543:152603.
【44】刘强, 惠松骁, 汪鹏勃, 等. 油气开采用钛合金石油管材料耐腐蚀性能研究[J]. 稀有金属材料与工程, 2020, 49(4):1427-1436.
【45】董超芳, 徐璟, 李晓刚, 等. 用高温显微镜原位观察钢中氢腐蚀裂纹愈合过程[J]. 中国腐蚀与防护学报, 2003, 23(3):179-182.
【46】XU J A, WANG Z H, SHOJI T. Effects of hydrogen on corrosion of pure Ni in high temperature water[J]. Corrosion Science, 2017, 122:123-129.
【47】ENSOR B, LUCENTE A M, FREDERICK M J, et al. The role of hydrogen in zirconium alloy corrosion[J]. Journal of Nuclear Materials, 2017, 496:301-312.
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