Effect of Silane Modified Nano-ZrO2 on Protective Properties of Epoxy Resin Coating on Aluminum Alloy Surface
摘 要
在6061铝合金表面制备了硅烷改性纳米ZrO2环氧树脂涂层,采用电化学测试和腐蚀试验,研究了纳米ZrO2添加量对硅烷改性纳米ZrO2环氧树脂涂层防护性能的影响,并对比了不同转化处理工艺下涂层的物理性能和防护性能。结果表明:当纳米ZrO2添加量为100 mg/L时,硅烷改性纳米ZrO2环氧树脂涂层试样的极化电阻为2 719 Ω·cm2、自腐蚀电流密度为2.528×10-6 A·cm-2;在经不同转化处理工艺处理的涂层中,硅烷改性纳米ZrO2环氧树脂涂层的平均厚度为55 μm,涂层剥离面积比例为5%,附着力达到1级,极化电阻最大,自腐蚀电流密度最小,涂层防护性能最佳。
Abstract
Silane modified nano-ZrO2 epoxy resin coating was prepared on the surface of 6061 aluminum alloy. The effect of nano-ZrO2 addition on the protective properties of silane modified nano-ZrO2 epoxy resin coating was studied by electrochemical test and corrosion test. The physical properties and protective properties of the coating under different conversion treatment processes were compared. The results showed that when the addition amount of nano- ZrO2 was 100 mg/L, the polarization resistance of silane modified nano-ZrO2 epoxy resin coating sample was 2 719 Ω· cm2, and the self-corrosion current density was 2.528×10-6 A·cm-2. Among the coatings treated by different conversion treatment processes, the average thickness of silane modified nano-ZrO2 epoxy resin coating was 55 μm, the peeling area ratio of the coating was 5%, the adhesion reached level 1, the polarization resistance was the largest, the self-corrosion current density was the smallest, and the coating protection performance was the best.
中图分类号 TG174.4 DOI 10.11973/fsyfh-202309013
所属栏目 试验研究
基金项目 河南省科技发展计划项目(1521023102122); 新乡学院科技创新基金(15ZC16)
收稿日期 2021/12/20
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引用该论文: LI Hongling. Effect of Silane Modified Nano-ZrO2 on Protective Properties of Epoxy Resin Coating on Aluminum Alloy Surface[J]. Corrosion & Protection, 2023, 44(9): 83
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参考文献
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【2】ALIBAKHSHI E,GHASEMI E,MAHDAVIAN M,et al. A comparative study on corrosion inhibitive effect of nitrate and phosphate intercalated Zn-Al-layered double hydroxides (LDHs) nanocontainers incorporated into a hybrid silane layer and their effect on cathodic delamination of epoxy topcoat[J]. Corrosion Science,2017,115:159-174.
【3】BERA S,ROUT T K,UDAYABHANU G,et al. Water-based & eco-friendly epoxy-silane hybrid coating for enhanced corrosion protection & adhesion on galvanized steel[J]. Progress in Organic Coatings,2016,101:24-44.
【4】ZOU Y,LI L,TAN B,et al. Silane modified epoxy coatings with low surface tension to achieve self-healing of wide damages[J]. Progress in Organic Coatings,2019,133:357-367.
【5】LI C C,LIANG T T,MA R N,et al. Superhydrophobic surface containing cerium salt and organosilane for corrosion protection of galvanized steel[J]. Journal of Alloys and Compounds,2020,825:153921.
【6】ASHASSI-SORKHABI H,MORADI-ALAVIAN S,JAFARI R,et al. Effect of amino acids and montmorillonite nanoparticles on improving the corrosion protection characteristics of hybrid sol-gel coating applied on AZ91 Mg alloy[J]. Materials Chemistry and Physics,2019,225:298-308.
【7】SELVAM N C S,MANIKANDAN A,KENNEDY L J,et al. Comparative investigation of zirconium oxide (ZrO2) nano and microstructures for structural,optical and photocatalytic properties[J]. Journal of Colloid and Interface Science,2013,389(1):91-98.
【8】ABRARI M,GHANAATSHOAR M,DAVARANI S S H,et al. Synthesis of SnO2 nanoparticles by electrooxidation of tin in quaternary ammonium salt for application in dye-sensitized solar cells[J]. Applied Physics A,2017,123(5):326.
【9】邵亚薇,李瑛,王福会,等. Ti纳米粒子对环氧涂层防护性能的影响[J]. 中国腐蚀与防护学报,2006,26(2):115-119,124.
【10】TIAN H,LI W,ZONG C,et al. Anti-corrosion properties of epoxy coatings modified by nano-SiO2[J]. Journal of the Chinese Society of Corrosion and Protection,2009,5(29):365-370.
【11】丁新更,陈远,吴春春,等. KH570改性SiO2复合耐腐蚀涂层结构及性能[J]. 材料工程,2010,38(12):72-76.
【12】曹楚南,张鉴清. 电化学阻抗谱导论[M]. 北京:科学出版社,2016.
【13】HEGEDUS C R,KAMEL I L. Polymer filler interaction effects on coating properties[J]. Journal of Coatings Technology,1993,65:37-43.
【14】KONG G,LIU L Y,LU J T,et al. Corrosion behavior of lanthanum-based conversion coating modified with citric acid on hot dip galvanized steel in aerated 1M NaCl solution[J]. Corrosion Science,2011,53(4):1621-1626.
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