Citation: | LIU Qiang, CHENG Xin, YOU Bo. Preparation of Phytic Acid and Silane Modified Graphene Oxide Polyaspartic Acid Ester Composite Coating and Its Anti-Corrosion Mechanism[J]. Corrosion & Protection, 2025, 46(5): 15-23. DOI: 10.11973/fsyfh240383 |
Phytic acid and silane modified graphene oxide (PSGO) nanomaterials were added into a high solid content polyaspartic acid ester (PAE) coating system to prepare environmentally friendly high solid content PSGO/PAE composite coatings. Salt-spray corrosion test, electrochemical test and field application test were carried out to study the anti-corrosion performance of the PSGO/PAE composite coating, and the anti-corrosion mechanism of the coating was preliminarily investigated. The results show that the addition of PSGO could significantly improve the corrosion resistance of the PAE coating. After soaking for 28 days, the |Z|0.01 Hz of the composite coating still reached 1.35× 1010 Ω·cm2. The PSGO/PAE composite coating with 0.5% (mass fraction) PSGO had excellent anti-corrosion performance in the atmospheric environment of the South China Sea. The synergistic effect of phytic acid's passivation protection on metal materials and graphene oxide nanosheets' barrier shielding enable the PSGO/PAE composite coating to provide dual protection for metal substrates. And the coating is expected to be applied to marine heavy anti-corrosion and other fields.
[1] |
GEORGAKILAS V, OTYEPKA M, BOURLINOS A B, et al. Functionalization of graphene: covalent and non-covalent approaches, derivatives and applications[J]. Chemical Reviews, 2012, 112(11): 6156-6214.
|
[2] |
JAVIDPARVAR A A, NADERI R, RAMEZANZADEH B. Epoxy-polyamide nanocomposite coating with graphene oxide as cerium nanocontainer generating effective dual active/barrier corrosion protection[J]. Composites Part B: Engineering, 2019, 172: 363-375.
|
[3] |
ZHOU X N, HUANG H W, ZHU R, et al. Facile modification of graphene oxide with Lysine for improving anti-corrosion performances of water-borne epoxy coatings[J]. Progress in Organic Coatings, 2019, 136: 105200.
|
[4] |
ASALDOUST S, RAMEZANZADEH B. Synthesis and characterization of a high-quality nanocontainer based on benzimidazole-zinc phosphate (ZP-BIM) tailored graphene oxides; a facile approach to fabricating a smart self-healing anti-corrosion system[J]. Journal of Colloid and Interface Science, 2020, 564: 230-244.
|
[5] |
MOTAMEDI M, RAMEZANZADEH M, RAMEZANZADEH B, et al. Enhancement of the active/passive anti-corrosion properties of epoxy coating via inclusion of histamine/zinc modified/reduced graphene oxide nanosheets[J]. Applied Surface Science, 2019, 488: 77-91.
|
[6] |
JAVIDPARVAR A A, NADERI R, RAMEZANZADEH B. L-cysteine reduced/functionalized graphene oxide application as a smart/control release nanocarrier of sustainable cerium ions for epoxy coating anti-corrosion properties improvement[J]. Journal of Hazardous Materials, 2020, 389: 122135.
|
[7] |
HAO Y S, SANI L A, GE T J, et al. Phytic acid doped polyaniline containing epoxy coatings for corrosion protection of Q235 carbon steel[J]. Applied Surface Science, 2017, 419: 826-837.
|
[8] |
ZHAO Y J, ZHAO S Y, GUO H C, et al. Facile synthesis of phytic acid@attapulgite nanospheres for enhanced anti-corrosion performances of coatings[J]. Progress in Organic Coatings, 2018, 117: 47-55.
|
[9] |
XING W T, YOU B, WU L M. Chemical and anticorrosion characterization of polysilsesquioxane coatings catalyzed by different acids[J]. Journal of Coatings Technology and Research, 2008, 5(1): 65-72.
|
[10] |
LIU Q, ZENG Q, LEI Y, et al. Nacre-inspired fabrication of robust and flexible photothermal protective films using a coordination-crosslinking self-assembly strategy[J]. Progress in Organic Coatings, 2024, 186: 108014.
|
[11] |
LIANG J F, WU X W, LING Y H, et al. Trilaminar structure hydrophobic graphene oxide decorated organosilane composite coatings for corrosion protection[J]. Surface and Coatings Technology, 2018, 339: 65-77.
|
[12] |
JIANG F W, ZHAO W J, WU Y M, et al. Anti-corrosion behaviors of epoxy composite coatings enhanced via graphene oxide with different aspect ratios[J]. Progress in Organic Coatings, 2019, 127: 70-79.
|
[13] |
POURHASHEM S, VAEZI M R, RASHIDI A. Investigating the effect of SiO2-graphene oxide hybrid as inorganic nanofiller on corrosion protection properties of epoxy coatings[J]. Surface and Coatings Technology, 2017, 311: 282-294.
|
[14] |
HINDERLITER B R, CROLL S G, TALLMAN D E, et al. Interpretation of EIS data from accelerated exposure of coated metals based on modeling of coating physical properties[J]. Electrochimica Acta, 2006, 51(21): 4505-4515.
|
[15] |
CONRADI M, KOCIJAN A, KEK-MERL D, et al. Mechanical and anticorrosion properties of nanosilica-filled epoxy-resin composite coatings[J]. Applied Surface Science, 2014, 292: 432-437.
|
[16] |
QIU S H, LI W, ZHENG W R, et al. Synergistic effect of polypyrrole-intercalated graphene for enhanced corrosion protection of aqueous coating in 3.5% NaCl solution[J]. ACS Applied Materials & Interfaces, 2017, 9(39): 34294-34304.
|
[17] |
CANO E, LAFUENTE D, BASTIDAS D M. Use of EIS for the evaluation of the protective properties of coatings for metallic cultural heritage: a review[J]. Journal of Solid State Electrochemistry, 2010, 14(3): 381-391.
|