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    LUO Jian-jun, MA Lin, SUN Zhi-guo, TANG Guang-ze. Anti-tarnishing Amorphous Alumina Films on Silver Coins[J]. Corrosion & Protection, 2010, 31(6): 491-493.
    Citation: LUO Jian-jun, MA Lin, SUN Zhi-guo, TANG Guang-ze. Anti-tarnishing Amorphous Alumina Films on Silver Coins[J]. Corrosion & Protection, 2010, 31(6): 491-493.

    Anti-tarnishing Amorphous Alumina Films on Silver Coins

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    • Received Date: September 23, 2009
    • Amorphous alumina films were deposited on silver coin surfaces by reactive magnetron sputtering to improve the anti-tarnishing property of silver.Glance angle X-ray diffraction (GXRD),X-ray photoelectron spectoscopy (XPS) and atomic force microscopy (AFM) were used to analyze the chemical state and surface morphology of alumina films.The corrosion potential of silver coins covered with amorphous alumina was increased,and corrosion current density was decreased in 0.5 mol/L NaCl+10 mmol/L Na2S mixing solution.The accelerated test in H2S vapor showed that the alumina film had excellent anti-tarnishing properties.
    • [1]
      Rice D W,Peterson P,Rigby E B,et al.Atmospheric corrosion of copper and silver[J].Electrochem Soc,1981,128(2):275-284.
      [2]
      Praney J P,Kammlott G W,Graedel T E.The corrosion of silver by atmospheric sulfurous gas[J].Corrosion Science,1985,25(2):133-143.
      [3]
      Kim H.Corrosion process of silver in environments containing 0.1 ppm H2S and 1.2 ppm NO2[J].Materials and Corrosion,2003,54(4):243-250.
      [4]
      Hallett K,Thickett D,McPhail D S,et al.Application of sIMS to silver tarnish at the british museum[J].Applied Surface Science,2003,203/204:792-798.
      [5]
      Dowsett M G,Adriaens A,Soares M,et al.The use of ultra-low-energy dunamic SIMS in the study of the tarnishing of silver[J].Nuclear Instruments & Methods in Physics Research B,2005,239:51-64.
      [6]
      Singh I,Sabita P M,Altekar V A.Silver tarnishing and its prevention-A review[J].Anti-Corrosion,1983,30:4-8.
      [7]
      Souza S de.Smart coating based on polyaniline acrylic blend corrosion protecting of different metals[J].Surface & Coatings Technology,2007,201:7574-7581.
      [8]
      Evesque M,Keddam M,Takenouti H.The formation of self-assembling membrance of hexadencane-thiol of silver to provent the tarnishing[J].Electrochimica Acta,2004,49:2937-2943.
      [9]
      Yang H,Sun Y,Ji J,et al.2-mercaptobenzothiazole monolayers on zinc and silver surface for anticorrosion[J].Corrosion Science,2008,50:3160-3167.
      [10]
      Frey T,Kgel M.Tarnish protection of silver jewels by plasmapolymer coatings[J].Surface & Coatings Technology,2003,173/174:902-904.
      [11]
      Farre Quattropani L,Groening P,Ramseyer D,et al.The protection of metallic archaeological objects using plasma polyer coatings[J].Surface & Coatings Technology,2000,125:377-382.

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