Electrochemical Impedance Spectroscopy during Exfoliation Corrosion Process of 2B96K Al-Li Alloy
-
摘要: 研究了不同时效状态下的 2B96K铝锂合金在EXCO溶液中剥蚀的电化学阻抗特征.结果表明,腐蚀初期,合金的电化学阻抗谱由一个容抗弧及一个感抗弧组成,一旦发生剥蚀,即变成两个容抗弧.对于欠时效合金,这两个容抗弧出现的时间较长,表明其剥蚀发展较慢.对电化学阻抗谱进行了拟合分析,得到了剥蚀的相关信息,如剥蚀的发展及形貌等.
-
关键词:
- 剥蚀 /
- Al-Li合金 /
- 电化学阻抗谱(EIS)
Abstract: The electrochemical impedance spectroscopy (EIS) during exfoliation corrosion process of 2B96K Al-Li alloy with different aging treatments in EXCO solution was studied.At the beginning of corrosion,the EIS was comprised of a capacitive arc and an inductive loop.Once exfoliation corrosion occurred,two capacitive arcs appeared.The longer appearance time of two capacitive arcs of the under-aged alloy indicated its slower corrosion development.The simulated EIS analysis was done,the information such as developing and feature of exfoliation corrosion was goet. -
-
[1] 尹登峰,郑子樵.铝锂合金研究开发的历史与现状[J].材料导报,2003,17(2):18-20. [2] 邱惠中.铝锂合金的发展概况及其应用[J].宇航材料工艺,1993(4):38-39. [3] Li J F,Zheng Z Q,Tan C Y,et al.Electrochemical impedance spectroscopy during corrosion process of 8090Al-Li alloy in EXCO solution[J].Acta Metallurgica Sinica,2004,17(6):894-897. [4] ASTM G34-79.Exfoliation corrosion susceptibilityin 2×××and 7×××series aluminium alloys (EXCO test )[S]. [5] 苏景新,张昭,曹发和,等.T6态2090 A1-Li合金在 EXCO溶液中的剥蚀行为和剥蚀发展过程中的电化学阻抗谱[J].金属学报,2005,25(7):974-978. [6] LI Jin-feng,CHEN Wen-jing,ZHAO Xu-shan,et al.Corrosion behavior of 2195 and 1420 Al-Li alloys in 35% NaCl solution[J].Ttansactions of Nonferrous Metals Society of China,2006,16(5):1171-1177.
计量
- 文章访问数: 3
- HTML全文浏览量: 0
- PDF下载量: 1